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Journal of Sol-Gel Science and Technology

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13.11.2018 | Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Sol-gel-derived perovskite-based sorbents for high-temperature air separation

verfasst von: Ainun Sailah Sihar, Nur Hashimah Alias, Munawar Zaman Shahruddin, Syed Shatir Asghrar Syed Hassan, Nik Raihan Nik Him, Nur Hidayati Othman

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2019

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Abstract

In this work, partial substitution or doping of SrCo_0.8Fe_0.2O_3-δ (SCF), which leads to the formation of La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) and La_0.6Sr_0.4Co_0.2Ni_0.8O_3-δ (LSCNi) were carried out using Pechini sol–gel technique. The perovskite oxides sol was then calcined at 850 °C for 4 h and their crystallinity, morphology and oxygen sorption/desorption behaviour were systematically compared. It was found that the synthesised perovskite oxides exhibit single-phase cubic perovskites. The O₂-TPD analysis indicates that LSCNi adsorbed the largest amount of oxygen and SCF only performed better at higher operating temperature. From the fixed bed test, LSCF and LSCNi are found to have high potential to be used as O₂ sorbent for high-temperature air separation because they required shorter time to achieve the breakthrough curve.

Vorheriger Artikel Structural characterization and antibacterial activity of hydroxyapatite synthesized via sol-gel method using glutinous rice as a template

Nächster Artikel Mesoporous silica modified luminescent Gd2O3:Eu nanoparticles: physicochemical and luminescence properties

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Titel: Sol-gel-derived perovskite-based sorbents for high-temperature air separation
verfasst von: Ainun Sailah Sihar
Nur Hashimah Alias
Munawar Zaman Shahruddin
Syed Shatir Asghrar Syed Hassan
Nik Raihan Nik Him
Nur Hidayati Othman
Publikationsdatum: 13.11.2018
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 3/2019
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-018-4865-x

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