nach oben

Journal of Nanoparticle Research

Erschienen in:

01.02.2012 | Research Paper

Controlled synthesis and magnetic properties of nickel phosphide and bimetallic iron–nickel phosphide nanorods

verfasst von: Bhupendra Singh, Chia-Ling Ho, Yuan-Chieh Tseng, Chieh-Tsung Lo

Erschienen in: Journal of Nanoparticle Research | Ausgabe 2/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Nickel phosphide (Ni₂P) and bimetallic iron–nickel phosphides [(Fe_xNi_y)₂P] nanorods were fabricated by a seeded growth strategy. This strategy utilized pre-synthesized Fe₃O₄ nanoparticles as seeds and the thermal decomposition of metal precursors by multiple injections in a solution containing trioctylphosphine and didodecyldimethylammonium bromide (DDAB). The nanorods were characterized by transmission electron microscopy, X-ray diffraction, and magnetic measurements were carried out using superconducting quantum interference device (SQUID). The rod length was tunable, ranging from 10 to 110 nm depending on the number of injections, whereas the diameter of the rods was nearly 6 nm. It was found that the rod size increased with the number of injections under the constant total injection concentration and reaction time. In addition, the effect of the DDAB quantity used as a co-surfactant was studied, which showed that an optimum quantity was required to achieve uniform nanorods. Magnetic characterizations were performed over the two kinds of nanorods to identify their respective magnetic phases. The results demonstrated that the Ni₂P nanorods were defined as a Curie–Weiss paramagnet, whereas the (Fe_xNi_y)₂P nanorods exhibited superparamagnetic characteristics.

Vorheriger Artikel Biotinylated chitosan-based SPIONs with potential in blood-contacting applications

Nächster Artikel Solvothermal preparation of nano-β-HgS from a precursor, bis(dibenzyldithiocarbamato)mercury(II)

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Bai J, Takahoshi H, Ito H, Saito H, Wei F, Yang Z, Ishio S (2004) Coercivity map of perpendicular patterned CoCrPt medium investigated by using MFM. Phys Status Solidi A 201:1662–1665CrossRef

Bieger T (1997) Fabrication, metallographic and tribologic investigations of LIGA-microstructures made of nickel phosphorous alloys. Microsyst Technol 3:155–163CrossRef

Boyanov S, Bernardi J, Gillot F, Dupont L, Womes M, Tarascon JM, Monconduit L, Doublet ML (2006) FeP: another attractive anode for the Li-ion battery enlisting a reversible two-step insertion/conversion process. Chem Mater 18:3531–3538CrossRef

Brock SL, Perera SC, Stamm L (2004) Chemical routes for production of transition-metal phosphides on the nanoscale: implications for advanced magnetic and catalytic materials. Chem Eur J 10:3364–3371CrossRef

Cattaruzza F, Fiorani D, Flamini A, Imperatori P, Scavia G, Suber L, Testa AM, Mezzi A, Ausanio G, Plunkett WR (2005) Magnetite nanoparticles anchored to crystalline silicon surfaces. Chem Mater 17:3311–3316CrossRef

Chubykalo-Fesenko OA, Chantrell RW (2004) Numerical evaluation of energy barriers and magnetic relaxation in interacting nanostructured magnetic systems. Phys B 343:189–194CrossRef

Fujii S, Ishida S, Asano S (1988) Electronic structures and magnetic properties of Fe₂P, Co₂P and CoMnP. J Phys F 18:971–980CrossRef

Gregg KA, Perera SC, Laws G, Shinozaki S, Brock SL (2006) Controlled synthesis of MnP nanorods: effect of shape anisotropy on magnetization. Chem Mater 18:879–886CrossRef

Guan J, Wang Y, Qin M, Yang Y, Li X, Wang A (2009) Synthesis of transition-metal phosphides from oxidic precursors by reduction in hydrogen plasma. J Solid State Chem 182:1550–1555CrossRef

Hou HW, Yang Q, Tan CR, Ji GB, Xie Y (2004) One-pot solution-phase synthesis of paramagnetic Co₂P nanorods. Chem Lett 33:1272–1273CrossRef

Kelly AT, Rusakova I, Ould-Ely T, Hofmann C, Luttge A, Whitmire KH (2007) Iron phosphide nanostructures produced from a single-source organometallic precursor: nanorods, bundles, crosses, and spherulites. Nano Lett 7:2920–2925CrossRef

Lee KB, Park S, Mirkin CA (2004) Multicomponent magnetic nanorods for biomolecular separations. Angew Chem Int Ed 116:3110–3112CrossRef

Liu JW, Chen XY, Shao MW, An CH, Yu WC, Qian YT (2003) Surfactant-aided solvothermal synthesis of dinickel phosphide nanocrystallites using red phosphorus as starting materials. J Cryst Growth 252:297–301CrossRef

Liu C, Chung SH, Jin Q, Sutton A, Yan F, Hoffmann A, Kay BK, Bader SD, Makowski L, Chen L (2006) Magnetic viruses via nano-capsid templates. J Magn Magn Mater 302:47–51CrossRef

Lo CT, Kuo PY (2010) Synthesis and magnetic properties of iron phosphide nanorods. J Phys Chem C 114:4808–4815CrossRef

Lukehart CM, Milne SB, Stock SR (1998) Formation of crystalline nanoclusters of Fe₂P, RuP, Co₂P, Rh₂P, Ni₂P, Pd₅P₂, or PtP₂ in a silica xerogel matrix from single-source molecular precursors. Chem Mater 10:903–908CrossRef

Motojima S, Katsuhiko H, Takahashi Y, Sugiyama K (1979) Chemical vapor deposition of nickel phosphide Ni₂P. J Less Common Met 64:101–106CrossRef

Motojima S, Wakamatsu T, Sugiyama K (1981) Corrosion stability of vapor-deposited transition metal phosphides at high temperature. J Less Common Met 82:379–383CrossRef

Muthuswamy E, Kharel PR, Lawes G, Brock SL (2009) Control of phase in phosphide nanoparticles produced by metal nanoparticle transformation: Fe₂P and FeP. ACS Nano 3:2383–2393CrossRef

Oyama ST (2003) Novel catalysts for advanced hydroprocessing: transition metal phosphides. J Catal 216:343–352CrossRef

Park SJ, Kim S, Lee S, Khim ZG, Char K, Hyeon T (2000) Synthesis and magnetic studies of uniform iron nanorods and nanospheres. J Am Chem Soc 122:8581–8582CrossRef

Park J, Koo B, Hwang Y, Bae C, An K, Park JG, Park HM, Hyeon T (2004) Novel synthesis of magnetic Fe₂P nanorods from thermal decomposition of continuously delivered precursors using a syringe pump. Angew Chem Int Ed 43:282–2285

Park J, Koo B, Hwang Y, Bae C, An K, Park JG, Park HM, Hyeon T (2005) Generalized synthesis of metal phosphide nanorods via thermal decomposition of continuously delivered metal–phosphine complexes using a syringe pump. J Am Chem Soc 127:8433–8440CrossRef

Peng X, Wickham J, Alivisatos AP (1998) Kinetics of II–VI and III–V colloidal semiconductor nanocrystal growth: “focusing” of size distributions. J Am Chem Soc 120:5343–5344CrossRef

Qian XF, Zhang XM, Wang C, Wang WZ, Qian YT (1998) A new way to prepare nanocrystalline dinickel phosphide. Mater Res Bull 33:669–672CrossRef

Qian C, Kim F, Ma L, Tsui F, Yang P, Liu J (2004) Solution-phase synthesis of single-crystalline iron phosphide nanorods/nanowires. J Am Chem Soc 126:1195–1198CrossRef

Sawhill SJ, Phillips DC, Bussell ME (2003) Thiophene hydrodesulfurization over supported nickel phosphide catalysts. J Catal 215:208–219CrossRef

Senevirathne K, Burns AW, Bussell ME, Brock SL (2007) Synthesis and characterization of discrete nickel phosphide nanoparticles: effect of surface ligation chemistry on catalytic hydrodesulfurization of thiophene. Adv Funct Mater 17:3933–3939CrossRef

Sredniawa B, Duraj R, Pacyna A, Bombik A, Zach R, Bacmann M, Fruchart D, Niziol S, Fornal P, Stanek J (2000) Magnetoelastic phase transitions and critical behaviour of (Fe_1−xNi_x)₂P system. Acta Phys Pol A 97:921–926

van Schnering HG, Honle W (1994) Encyclopedia of inorganic chemistry, vol 6. Wiley, Chichester 3106

Wang R, Smith KJ (2010) The effect of preparation conditions on the properties of high-surface area Ni₂P catalysts. App Catal A 380:149–164CrossRef

Wang X, Clark P, Oyama ST (2002) Synthesis, characterization, and hydrotreating activity of several iron group transition metal phosphides. J Catal 208:321–331CrossRef

Wang A, Qin M, Guan J, Wang L, Guo H, Li X, Wang Y, Prins R, Hu Y (2008) The synthesis of metal phosphides: reduction of oxide precursors in a hydrogen plasma. Angew Chem Int Ed 47:6052–6054

Wang JL, Yang Q, Zhang ZD, Sun SH (2010a) Phase-controlled synthesis of transition-metal phosphide nanowires by Ullmann-type reactions. Chem Eur J 16:7916–7924CrossRef

Wang JL, Yang Q, Zhou J, Sun KW, Zhang ZD, Feng XM, Li TW (2010b) Magnetic Fe₂P nanowires and Fe₂P@C core@shell nanocables. Nano Res 3:211–221CrossRef

Xie SH, Qiao MH, Zhou WZ, Luo G, He HY, Fan KN, Zhao TJ, Yuan WK (2005) Controlled synthesis, characterization, and crystallization of Ni–P nanospheres. J Phys Chem B 109:24361–24368CrossRef

Yoon KY, Jang Y, Park J, Hwang Y, Koo B, Park JG, Hyeon T (2008) Synthesis of uniform-sized bimetallic iron-nickel phosphide nanorods. J Solid State Chem 181:1609–1613CrossRef

Yunle G, Fan G, Qian Y, Huagui Z, Ziping Y (2002) A solvothermal synthesis of ultra-fine iron phosphide. Mater Res Bull 37:1101–1105CrossRef

Zach R, Tobola J, Sredniawa B, Kaprzyk S, Casado C, Bacmann M, Fruchart D (2004) Magneto-elastic properties and electronic structure analysis of the (Fe_1−xNi_x)₂P system. J Alloy Compd 383:322–327CrossRef

Zhang XF, Zhang QM, Zhao AQ, Guan J, He DM, Hu HQ, Liang CH (2010) Naphthalene hydrogenation over silica supported nickel phosphide in the absence and presence of n-containing compounds. Energy Fuels 24:3796–3803CrossRef

Titel: Controlled synthesis and magnetic properties of nickel phosphide and bimetallic iron–nickel phosphide nanorods
verfasst von: Bhupendra Singh
Chia-Ling Ho
Yuan-Chieh Tseng
Chieh-Tsung Lo
Publikationsdatum: 01.02.2012
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 2/2012
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-011-0706-3

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 2/2012

Microwave-induced solid-state synthesis of TiO2(B) nanobelts with enhanced lithium-storage properties

Solution templating of Au and Ag nanoparticles by linear poly[2-(diethylamino)ethyl methacrylate]

Novel NdCo5 nanoflakes and nanoparticles produced by surfactant-assisted high-energy ball milling

Polymer-supported metals and metal oxide nanoparticles: synthesis, characterization, and applications

Immobilization of platinum nanoparticles on 3,4-diaminobenzoyl-functionalized multi-walled carbon nanotube and its electrocatalytic activity

In situ purity enhancement/surface modification of single-walled carbon nanotubes synthesized by induction thermal plasma

Premium Partner

Marktübersichten