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Journal of Materials Science
Erschienen in: Journal of Materials Science 17/2016

03.06.2016 | Original Paper

Convenient synthesis of nanocrystalline powders of phase-pure manganese nitride η-Mn3N2

verfasst von: Mariusz Drygaś, Mirosław M. Bućko, Michał Musiał, Jerzy F. Janik

Erschienen in: Journal of Materials Science | Ausgabe 17/2016

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Abstract

Manganese bis(trimethylsilyl)amide Mn[N(Si(CH3)3)2]2 was used as a convenient material precursor to prepare pure manganese nitride nanopowders with reaction-controlled average crystallite sizes. The precursor was first reacted with liquid ammonia under reflux conditions and the resulting by-product was pyrolyzed under an ammonia flow at temperatures in the range 150–900 °C. The powder products were characterized mainly by powder X-ray diffraction (XRD) diffraction, SEM/EDX examinations, and FT-IR and micro-Raman spectroscopies. In all cases, a pure phase of nanocrystalline η-Mn3N2 was detected by XRD as the exclusive manganese nitride product. The compound’s nanopowders were extremely reactive toward air. Upon oxidation, they formed either MnO for a relatively better crystallized nitride from higher synthesis temperatures or Mn3O4 after self-ignition of a poorly crystalline nitride from a lower synthesis temperature.
Vorheriger Artikel Control of octahedral rotations via octahedral connectivity in an epitaxially strained [1 u.c.//4 u.c.] LaNiO3/LaGaO3 superlattice
Nächster Artikel Soft synthesis of potassium co-doped Al–ZnO nanocomposites: a comprehensive study on their visible-light driven photocatalytic activity on dye degradation

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Metadaten
Titel
Convenient synthesis of nanocrystalline powders of phase-pure manganese nitride η-Mn3N2
verfasst von
Mariusz Drygaś
Mirosław M. Bućko
Michał Musiał
Jerzy F. Janik
Publikationsdatum
03.06.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 17/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0094-2

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