Skip to main content
Erschienen in: Journal of Polymer Research 1/2008

01.02.2008

Correlations between composition and crystallinity of LDPE/HDPE blends

verfasst von: Marilda Munaro, Leni Akcelrud

Erschienen in: Journal of Polymer Research | Ausgabe 1/2008

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

DMTA, DSC, WAXS and density were used to quantify the crystallinity and crystallite dimensions of specific grades of LDPE/HDPE blends. In virtue of the close agreement of the results obtained with the three techniques, an average degree of crystallinity was calculated, allowing the establishment of quantitative relationships between composition and crystallinity, and shifting of the α-relaxation. Dimensions along the 110 and 200 planes were also correlated with shifting of the α-transition.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Nalwa HS (1999) Handbook of low and high dielectric constant materials and their applications—materials and processing, v.1. Academic, San Diego Nalwa HS (1999) Handbook of low and high dielectric constant materials and their applications—materials and processing, v.1. Academic, San Diego
2.
Zurück zum Zitat Bartnikas R, Eichhorn RM (1983) Engineering dielectrics v. IIA. ASTM Publications, Philadelphia Bartnikas R, Eichhorn RM (1983) Engineering dielectrics v. IIA. ASTM Publications, Philadelphia
3.
Zurück zum Zitat Wu T, Li Y, Wu G (2005) Crystalline structure and phase structure of mLLDPE/LDPE blends. Polymer 46:3472CrossRef Wu T, Li Y, Wu G (2005) Crystalline structure and phase structure of mLLDPE/LDPE blends. Polymer 46:3472CrossRef
4.
Zurück zum Zitat Liu CY, Wang J, He J (2002) Rheological and thermal properties of m-LLDPE blends with m-HDPE and LDPE. Polymer 43:3811CrossRef Liu CY, Wang J, He J (2002) Rheological and thermal properties of m-LLDPE blends with m-HDPE and LDPE. Polymer 43:3811CrossRef
5.
Zurück zum Zitat Coutry S, Spells SJ (2002) The effect of short chain branching on local chain organisation in isotopically labelled blends of polyethylene. Polymer 43:4957CrossRef Coutry S, Spells SJ (2002) The effect of short chain branching on local chain organisation in isotopically labelled blends of polyethylene. Polymer 43:4957CrossRef
6.
Zurück zum Zitat Matsuba G, Shimizu K, Wang H, Wang Z, Han CC (2003) Kinetics of phase separation and crystallization in poly (ethylene-ran-hexene) and poly (ethylene-ran-octene). Polymer 44:7459CrossRef Matsuba G, Shimizu K, Wang H, Wang Z, Han CC (2003) Kinetics of phase separation and crystallization in poly (ethylene-ran-hexene) and poly (ethylene-ran-octene). Polymer 44:7459CrossRef
7.
Zurück zum Zitat Wignall GD, Alamo RG, Londono JD, Mandelkern L, Kim MH, Lin JS, Brown GM (2000) Morphology of blends of linear and short-chain branched polyethylenes in the solid state by small-angle neutron and X-ray scattering, differential scanning calorimetry, and transmission electron microscopy. Macromolecule 33:551CrossRef Wignall GD, Alamo RG, Londono JD, Mandelkern L, Kim MH, Lin JS, Brown GM (2000) Morphology of blends of linear and short-chain branched polyethylenes in the solid state by small-angle neutron and X-ray scattering, differential scanning calorimetry, and transmission electron microscopy. Macromolecule 33:551CrossRef
8.
Zurück zum Zitat Fu Q, Men Y, Strobl G (2003) Understanding of the tensile deformation in HDPE/LDPE blends based on their crystal structure and phase morphology. Polymer 44:1927CrossRef Fu Q, Men Y, Strobl G (2003) Understanding of the tensile deformation in HDPE/LDPE blends based on their crystal structure and phase morphology. Polymer 44:1927CrossRef
9.
Zurück zum Zitat Abu-Sharkh BF, Giri AM, Hussein IA (2004) Influence of branch content on the microstructure of blends of linear and octene-branched polyethylene: a MD simulation study. European Polymer J 40:1177CrossRef Abu-Sharkh BF, Giri AM, Hussein IA (2004) Influence of branch content on the microstructure of blends of linear and octene-branched polyethylene: a MD simulation study. European Polymer J 40:1177CrossRef
10.
Zurück zum Zitat Fan ZGJ, Williams MC, Choi P (2002) A molecular dynamics study of the effects of branching characteristics of LDPE on its miscibility with HDPE. Polymer 43:1497CrossRef Fan ZGJ, Williams MC, Choi P (2002) A molecular dynamics study of the effects of branching characteristics of LDPE on its miscibility with HDPE. Polymer 43:1497CrossRef
11.
Zurück zum Zitat Arnal ML, Sanchez JJ, Müler AJ (2001) Miscibility of linear and branched polyethylene blends by thermal fractionation: use of the successive self-nucleation and annealing (SSA) technique. Polymer 42:6877CrossRef Arnal ML, Sanchez JJ, Müler AJ (2001) Miscibility of linear and branched polyethylene blends by thermal fractionation: use of the successive self-nucleation and annealing (SSA) technique. Polymer 42:6877CrossRef
12.
Zurück zum Zitat Minick J, Moet A, Baer E (1995) Morphology of HDPE/LDPE blends with different thermal histories. Polymer 36:1923CrossRef Minick J, Moet A, Baer E (1995) Morphology of HDPE/LDPE blends with different thermal histories. Polymer 36:1923CrossRef
13.
Zurück zum Zitat Maaty MIA (2002) A counter-intuitive asymmetric habit of spherulites in polyethylene blends. Polymer 43:5639CrossRef Maaty MIA (2002) A counter-intuitive asymmetric habit of spherulites in polyethylene blends. Polymer 43:5639CrossRef
14.
Zurück zum Zitat Li C, Zhao J, Zhao D, Fan Q (2004) Linear low-density polyethylene/poly(ethylene-ran-butene) elastomer blends: miscibility and crystallization behavior. J Polym Res 11:323CrossRef Li C, Zhao J, Zhao D, Fan Q (2004) Linear low-density polyethylene/poly(ethylene-ran-butene) elastomer blends: miscibility and crystallization behavior. J Polym Res 11:323CrossRef
15.
Zurück zum Zitat Quental AC, Felisberti MI (2005) Phase behavior of blends of linear low density polyethylene and poly(ethene-propene-l-butene). European Polymer J 41:894CrossRef Quental AC, Felisberti MI (2005) Phase behavior of blends of linear low density polyethylene and poly(ethene-propene-l-butene). European Polymer J 41:894CrossRef
16.
Zurück zum Zitat Alberola N, Cavaille JY, Perez J (1990) Mechanical spectrometry of alpha-relaxations of high-density polyethylene. J Polym Sci B Polym Phys 28:569CrossRef Alberola N, Cavaille JY, Perez J (1990) Mechanical spectrometry of alpha-relaxations of high-density polyethylene. J Polym Sci B Polym Phys 28:569CrossRef
17.
Zurück zum Zitat Popli R, Glotin M, Manderlkern L (1984) Dynamic mechanical studies of alpha-relaxations and beta-relaxations of polyethylenes. J Polym Sci Polym Phys Ed 22:407CrossRef Popli R, Glotin M, Manderlkern L (1984) Dynamic mechanical studies of alpha-relaxations and beta-relaxations of polyethylenes. J Polym Sci Polym Phys Ed 22:407CrossRef
18.
Zurück zum Zitat Boyd RH (1985) Relaxation processes in crystalline polymers—molecular interpretation—a review. Polymer 26:1123CrossRef Boyd RH (1985) Relaxation processes in crystalline polymers—molecular interpretation—a review. Polymer 26:1123CrossRef
19.
Zurück zum Zitat Sirotkin RO, Brooks NW (2001) The dynamic mechanical relaxation behaviour of polyethylene copolymers cast from solution. Polymer 42:9801CrossRef Sirotkin RO, Brooks NW (2001) The dynamic mechanical relaxation behaviour of polyethylene copolymers cast from solution. Polymer 42:9801CrossRef
21.
Zurück zum Zitat Schatzki TF (1962) Statistical computation of distribution functions of dimensions of macromolecules. J Polym Sci 57:337CrossRef Schatzki TF (1962) Statistical computation of distribution functions of dimensions of macromolecules. J Polym Sci 57:337CrossRef
22.
Zurück zum Zitat Boyer RF (1963) The relation of transition temperatures to chemical structure in high polymers. Rubber Chem Technol 34:01303 Boyer RF (1963) The relation of transition temperatures to chemical structure in high polymers. Rubber Chem Technol 34:01303
23.
Zurück zum Zitat Nitta K-h, Tanaka A (2001) Dynamic mechanical properties of metallocene catalyzed linear polyethylenes. Polymer 42:1219CrossRef Nitta K-h, Tanaka A (2001) Dynamic mechanical properties of metallocene catalyzed linear polyethylenes. Polymer 42:1219CrossRef
24.
Zurück zum Zitat Stachurski ZH, Ward IM (1969) Mechanical relaxations in polyethylene. Macromol Sci B3 3:445CrossRef Stachurski ZH, Ward IM (1969) Mechanical relaxations in polyethylene. Macromol Sci B3 3:445CrossRef
25.
Zurück zum Zitat Stachurski ZH, Ward IM (1968) Anisotropy of viscoelastic transitions in oriented polyethylenes. J Polym Sci 6:1817 Stachurski ZH, Ward IM (1968) Anisotropy of viscoelastic transitions in oriented polyethylenes. J Polym Sci 6:1817
26.
Zurück zum Zitat Gulmine JV, Akcelrud L (2006) Correlations between structure and accelerated artificial ageing of XLPE. Eur Polym J 42:553CrossRef Gulmine JV, Akcelrud L (2006) Correlations between structure and accelerated artificial ageing of XLPE. Eur Polym J 42:553CrossRef
27.
Zurück zum Zitat Kline D, Sauer JA, Woodward AE (1956) Effect of branching on dynamic mechanical properties of polyethylene. J Polym Science 22:455CrossRef Kline D, Sauer JA, Woodward AE (1956) Effect of branching on dynamic mechanical properties of polyethylene. J Polym Science 22:455CrossRef
28.
Zurück zum Zitat Al-Hussein M, Davies G, Ward IM (2000) Mechanical properties of oriented low-density polyethylene with an oriented lamellar-stack morphology. J Polym Sci B 38:755CrossRef Al-Hussein M, Davies G, Ward IM (2000) Mechanical properties of oriented low-density polyethylene with an oriented lamellar-stack morphology. J Polym Sci B 38:755CrossRef
29.
Zurück zum Zitat Matthews R, Ward IM, Capoccio GJ (1999) Macromol Science Phys B 38(1 and 2):123CrossRef Matthews R, Ward IM, Capoccio GJ (1999) Macromol Science Phys B 38(1 and 2):123CrossRef
30.
Zurück zum Zitat Boyd RH (1985) Relaxation processes in crystalline polymers—experimental behavior—a review. Polymer 26:323CrossRef Boyd RH (1985) Relaxation processes in crystalline polymers—experimental behavior—a review. Polymer 26:323CrossRef
31.
Zurück zum Zitat ASTM International (2001) Standard test method for plastics: dynamic mechanical properties in tension. ASTM D5626. Printed in Easton ASTM International (2001) Standard test method for plastics: dynamic mechanical properties in tension. ASTM D5626. Printed in Easton
32.
Zurück zum Zitat ASTM International (1998) Standard test methods for density and specific gravity (relative density) of plastics by displacement, ASTM D792. Printed in Easton ASTM International (1998) Standard test methods for density and specific gravity (relative density) of plastics by displacement, ASTM D792. Printed in Easton
33.
Zurück zum Zitat Elias H-G (1983) Macromolecules 1 structure and properties, 2nd edn. Plenum, New York Elias H-G (1983) Macromolecules 1 structure and properties, 2nd edn. Plenum, New York
34.
Zurück zum Zitat Wunderlich B (1980) Macromolecular physics. 3v. Academic, New York Wunderlich B (1980) Macromolecular physics. 3v. Academic, New York
35.
Zurück zum Zitat Perepechko II (1981) An introduction to polymer physics. Mir Publishers, Moscow Perepechko II (1981) An introduction to polymer physics. Mir Publishers, Moscow
36.
Zurück zum Zitat Young RS, Lovell PA (1991) Introduction of polymers, 2nd edn. Chapman & Hall, New York Young RS, Lovell PA (1991) Introduction of polymers, 2nd edn. Chapman & Hall, New York
37.
Zurück zum Zitat Wang Z-G, Hsiao BS, Lopez J, Armistead JP (1999) Crystal structure changes during isothermal crystallization, cooling and heating of linear polyethylene. J Polym Res 6:167CrossRef Wang Z-G, Hsiao BS, Lopez J, Armistead JP (1999) Crystal structure changes during isothermal crystallization, cooling and heating of linear polyethylene. J Polym Res 6:167CrossRef
38.
Zurück zum Zitat Stadler FJ, Kaschta J, Münstedt H (2005) Dynamic-mechanical behavior of polyethylenes and ethene-/alpha-olefin-co-polymers. Part I. alpha'-relaxation. Polymer 46:10311CrossRef Stadler FJ, Kaschta J, Münstedt H (2005) Dynamic-mechanical behavior of polyethylenes and ethene-/alpha-olefin-co-polymers. Part I. alpha'-relaxation. Polymer 46:10311CrossRef
39.
Zurück zum Zitat Kolesov IS, Androsh R, Radusch H-J (2005) Effect of crystal morphology and crystallinity on the mechanical alpha- and beta-relaxation processes of short-chain branched polyethylene. Macromolecules 38:445CrossRef Kolesov IS, Androsh R, Radusch H-J (2005) Effect of crystal morphology and crystallinity on the mechanical alpha- and beta-relaxation processes of short-chain branched polyethylene. Macromolecules 38:445CrossRef
Metadaten
Titel
Correlations between composition and crystallinity of LDPE/HDPE blends
verfasst von
Marilda Munaro
Leni Akcelrud
Publikationsdatum
01.02.2008
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 1/2008
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-007-9146-2

Weitere Artikel der Ausgabe 1/2008

Journal of Polymer Research 1/2008 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.