Skip to main content
Erschienen in: Physics of Metals and Metallography 12/2023

01.12.2023 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Determination of the Boundaries of the Metastable ω-Phase Region in Titanium and Zirconium Alloys

verfasst von: A. V. Dobromyslov

Erschienen in: Physics of Metals and Metallography | Ausgabe 12/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract—

The concentration boundary of the formation of the ω-phase in binary titanium alloys with d-metals of 4−11 groups of 4−6 periods were studied by X-ray diffraction analysis. It is established that the ω-phase is formed in all the alloys studied, with the exception of Ti−Zr alloys. It is shown that the minimum concentration limit of the formation of the ω-phase is determined by the position of the curve of the finish of the martensitic β → \(\alpha {\kern 1pt} '\)(\(\alpha {\kern 1pt} ''\)) transformation (Mf). For most of the studied titanium alloys, concentrations were determined at which the Ms and Mf points correspond to a temperature of 20°C. The conditions for the formation of the ω-phase in titanium alloys were compared with the conditions for its formation in zirconium alloys.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Nosova, G.I., Phase Transformations in Titanium Alloys (Metallurgiya, Moscow, 1968) [in Russian]. Nosova, G.I., Phase Transformations in Titanium Alloys (Metallurgiya, Moscow, 1968) [in Russian].
2.
Zurück zum Zitat U. Zwicker, Titan und Titanlegierungen (Springer-Verlag, Berlin, 1974).CrossRef U. Zwicker, Titan und Titanlegierungen (Springer-Verlag, Berlin, 1974).CrossRef
3.
Zurück zum Zitat E. W. Collings, The Physical Metallurgy of Titanium Alloys, ASM Series in Metal Processing, Vol. 3 (American Society for Metals, Metals Park, Ohio, 1984). E. W. Collings, The Physical Metallurgy of Titanium Alloys, ASM Series in Metal Processing, Vol. 3 (American Society for Metals, Metals Park, Ohio, 1984).
4.
5.
Zurück zum Zitat A. A. Il’in, Mechanism and Kinetics of Phase and Structural Transformations in Titanium Alloys (Nauka, Moscow, 1994) [in Russian]. A. A. Il’in, Mechanism and Kinetics of Phase and Structural Transformations in Titanium Alloys (Nauka, Moscow, 1994) [in Russian].
7.
Zurück zum Zitat A. V. Dobromyslov and N. I. Taluts, Structure of Zirconium and Its Alloys (Ural. Otd. Ross. Akad. Nauk, Ekaterinburg, 1997) [in Russian]. A. V. Dobromyslov and N. I. Taluts, Structure of Zirconium and Its Alloys (Ural. Otd. Ross. Akad. Nauk, Ekaterinburg, 1997) [in Russian].
8.
Zurück zum Zitat A. V. Dobromyslov, “General regularities of formation of the omega-phase in binary titanium-base alloys with metals of IV–VIII, I groups of the periodic table,” in Proc. 12th World Conf. on Titanium (Beijing, 2012), Vol. 1, pp. 410–414. https://doi.org/10.2478/v10077-008-0004-7 A. V. Dobromyslov, “General regularities of formation of the omega-phase in binary titanium-base alloys with metals of IV–VIII, I groups of the periodic table,” in Proc. 12th World Conf. on Titanium (Beijing, 2012), Vol. 1, pp. 410–414. https://​doi.​org/​10.​2478/​v10077-008-0004-7
9.
Zurück zum Zitat Yu. A. Bagaryatskii, T. V. Tagunova, and G. I. Nosova, “Metastable phases in titnaium alloys with transition elements,” in Problems of Metal Science and Metal Physics (Metallurgizdat, Moscow, 1958), pp. 210–234 [in Russian]. Yu. A. Bagaryatskii, T. V. Tagunova, and G. I. Nosova, “Metastable phases in titnaium alloys with transition elements,” in Problems of Metal Science and Metal Physics (Metallurgizdat, Moscow, 1958), pp. 210–234 [in Russian].
12.
Zurück zum Zitat C. A. Luke, R. Taggart, and D. H. Polonis, “The metastable constitution of quenched titanium and zirconium-base binary alloys,” Trans. ASM 57, 142–149 (1964). C. A. Luke, R. Taggart, and D. H. Polonis, “The metastable constitution of quenched titanium and zirconium-base binary alloys,” Trans. ASM 57, 142–149 (1964).
13.
Zurück zum Zitat “General regularities in the stabilization of solid solution in titanium alloys,” Dokl. Akad. Nauk SSSR 138, 359–360 (1961). “General regularities in the stabilization of solid solution in titanium alloys,” Dokl. Akad. Nauk SSSR 138, 359–360 (1961).
15.
Zurück zum Zitat Yu. A. Bagaryatskii, G. I. Nosova, and T. Tagunova, “The crystallographic structure and nature of the ω‑phase in titanium alloys with chromium,” Dokl. Akad. Nauk SSSR 105, 1225–1228 (1955). Yu. A. Bagaryatskii, G. I. Nosova, and T. Tagunova, “The crystallographic structure and nature of the ω‑phase in titanium alloys with chromium,” Dokl. Akad. Nauk SSSR 105, 1225–1228 (1955).
18.
Zurück zum Zitat S. G. Fedotov, “Metastable phases in titanium alloys: Mechanism and kinetics of their formation,” in Studies of Metals in Liquid and Solid States (Nauka, Moscow, 1964), pp. 207–238 [in Russian]. S. G. Fedotov, “Metastable phases in titanium alloys: Mechanism and kinetics of their formation,” in Studies of Metals in Liquid and Solid States (Nauka, Moscow, 1964), pp. 207–238 [in Russian].
21.
Zurück zum Zitat B. S. Hickman, “Omega phase precipitation in alloys of titanium with transition metals,” Trans. AIME 245, 1329–1336 (1969). B. S. Hickman, “Omega phase precipitation in alloys of titanium with transition metals,” Trans. AIME 245, 1329–1336 (1969).
25.
Zurück zum Zitat N. V. Ageev, L. N. Guseva, and L. K. Dolinskaya, “Metastable phases in quenched titanium−molybdenum and titanium−vanadium alloys and the effect of small oxygen admixtures on them,” Izv. Vyssh. Uchebn. Zaved., Met., No. 4, 151–156 (1975). N. V. Ageev, L. N. Guseva, and L. K. Dolinskaya, “Metastable phases in quenched titanium−molybdenum and titanium−vanadium alloys and the effect of small oxygen admixtures on them,” Izv. Vyssh. Uchebn. Zaved., Met., No. 4, 151–156 (1975).
30.
Zurück zum Zitat J. W. Barton, G. R. Purdy, R. Taggart, J. Gordon, and J. G. Parr, “Structure and properties of titanium-reach Ti−Ni alloys,” Trans. AIME 218, 844–849 (1960). J. W. Barton, G. R. Purdy, R. Taggart, J. Gordon, and J. G. Parr, “Structure and properties of titanium-reach Ti−Ni alloys,” Trans. AIME 218, 844–849 (1960).
37.
Zurück zum Zitat Yu. A. Bagaryatskii and G. I. Nosova, “The β−ω transformation in Titanium alloys during quenching: A singular kind of martensitic transformation,” Fiz. Met. Metalloved. 13, 415–415 (1962). Yu. A. Bagaryatskii and G. I. Nosova, “The β−ω transformation in Titanium alloys during quenching: A singular kind of martensitic transformation,” Fiz. Met. Metalloved. 13, 415–415 (1962).
50.
Zurück zum Zitat P. D. Frost, W. M. Parris, L. L. Hirsh, J. R. Diog, and C. M. Schwartz, “Isothermal transformation of titanium−chromium alloys,” Trans. Am. Soc. Met. 46, 231–256 (1954). P. D. Frost, W. M. Parris, L. L. Hirsh, J. R. Diog, and C. M. Schwartz, “Isothermal transformation of titanium−chromium alloys,” Trans. Am. Soc. Met. 46, 231–256 (1954).
54.
Zurück zum Zitat D. L. Douglas, “Metallurgy of zirconium,” At. Energy Rev. Suppl. 1971, 1–470 (1971). D. L. Douglas, “Metallurgy of zirconium,” At. Energy Rev. Suppl. 1971, 1–470 (1971).
55.
Zurück zum Zitat A. V. Dobromyslov, N. I. Taluts, and N. V. Kazantseva, “The structure of quenched Zr—V alloys,” Phys. Met. Metallogr. 74, 231–235 (1992). A. V. Dobromyslov, N. I. Taluts, and N. V. Kazantseva, “The structure of quenched Zr—V alloys,” Phys. Met. Metallogr. 74, 231–235 (1992).
64.
Zurück zum Zitat A. V. Dobromyslov and N. I. Taluts, “Electron microscopy investigation of the structure of alloys of the Zr−Mo system,” Phys. Met. Metallogr. 70 (6), 68–76 (1990). A. V. Dobromyslov and N. I. Taluts, “Electron microscopy investigation of the structure of alloys of the Zr−Mo system,” Phys. Met. Metallogr. 70 (6), 68–76 (1990).
65.
Zurück zum Zitat A. V. Dobromyslov and N. I. Taluts, “Formation of α″‑phase in zirconium−molybdenum system,” Phys. Met. Metallogr. 76, 514–519 (1993). A. V. Dobromyslov and N. I. Taluts, “Formation of α″‑phase in zirconium−molybdenum system,” Phys. Met. Metallogr. 76, 514–519 (1993).
69.
Zurück zum Zitat A. V. Dobromyslov and N. I. Taluts, “Structure of the quenched Zr−Rh alloys,” Phys. Met. Metallogr. 83, 619–625 (1997). A. V. Dobromyslov and N. I. Taluts, “Structure of the quenched Zr−Rh alloys,” Phys. Met. Metallogr. 83, 619–625 (1997).
72.
Zurück zum Zitat A. V. Dobromyslov, N. I. Taluts, and A. P. Egorov, “Formation of the orthorhombic α phase in alloys of the Zr−Ta system,” Phys. Met. Metallogr. 82, 85–88 (1996). A. V. Dobromyslov, N. I. Taluts, and A. P. Egorov, “Formation of the orthorhombic α phase in alloys of the Zr−Ta system,” Phys. Met. Metallogr. 82, 85–88 (1996).
76.
Zurück zum Zitat N. I. Taluts and A. V. Dobromyslov, “Structure of quenched Zr−Pt alloys,” Phys. Met. Metallogr. 95, 50–57 (2003). N. I. Taluts and A. V. Dobromyslov, “Structure of quenched Zr−Pt alloys,” Phys. Met. Metallogr. 95, 50–57 (2003).
77.
Zurück zum Zitat N. I. Taluts, “Regularities of structural and phase transformations in zirconium and its alloys with transition metals of IV−VIII groups of the periodic table of elements,” Doctoral Dissertation in Physics and Mathematics (Mikheev Inst. of Metal Physics, Ural Branch, Russ. Acad. Sci., Ekaterinburg, 2006) [in Russian]. N. I. Taluts, “Regularities of structural and phase transformations in zirconium and its alloys with transition metals of IV−VIII groups of the periodic table of elements,” Doctoral Dissertation in Physics and Mathematics (Mikheev Inst. of Metal Physics, Ural Branch, Russ. Acad. Sci., Ekaterinburg, 2006) [in Russian].
79.
Zurück zum Zitat V. N. Gridnev, V. I. Trefilov, and V. N. Minakov, “Martensitic transformations in the system titanium−zirconium,” Sov. Phys. Dokl 5, 1094–1096 (1960). V. N. Gridnev, V. I. Trefilov, and V. N. Minakov, “Martensitic transformations in the system titanium−zirconium,” Sov. Phys. Dokl 5, 1094–1096 (1960).
Metadaten
Titel
Determination of the Boundaries of the Metastable ω-Phase Region in Titanium and Zirconium Alloys
verfasst von
A. V. Dobromyslov
Publikationsdatum
01.12.2023
Verlag
Pleiades Publishing
Erschienen in
Physics of Metals and Metallography / Ausgabe 12/2023
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X23700163

Weitere Artikel der Ausgabe 12/2023

Physics of Metals and Metallography 12/2023 Zur Ausgabe

STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Thermophysical Properties of Metals in Quasi-Two-Phase Model