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2020 | OriginalPaper | Buchkapitel

Development of a Physiochemical Model Combined with an Engineering Model for Predicting Solvent Extraction Performances Within the Context of Lithium-Ion Battery Recycling

verfasst von : Alexandre Chagnes

Erschienen in: Rare Metal Technology 2020

Verlag: Springer International Publishing

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Abstract

Solvent extraction is a mature technology that is used in many industrial applications for the extraction and/or purification of metals contained in aqueous solutions. Such a technology could be advantageously utilized to produce high-grade salts of lithium, cobalt, nickel, and manganese from mine or lithium-ion battery recycling. However, nickel–cobalt–manganese separation is not easy by means of commercial extractants. Such a separation could be achieved providing that process operation would be always optimized. Modelling tools could help achieve this goal. This paper presents the development of a global model implementing a physicochemical model and an engineering model, which can predict the influence of pH, flowrates, and mixers-settlers arrangement on the performances of liquid–liquid extraction.

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Literatur
1.
Zurück zum Zitat Chagnes A (2015) Lithium battery technologies: electrolytes. In: Chagnes A, Swiatowska J (eds) Lithium process chemistry: resources, extractions, batteries and recycling, 1st edn. Elsevier, Amsterdam, pp 167–189CrossRef Chagnes A (2015) Lithium battery technologies: electrolytes. In: Chagnes A, Swiatowska J (eds) Lithium process chemistry: resources, extractions, batteries and recycling, 1st edn. Elsevier, Amsterdam, pp 167–189CrossRef
2.
Zurück zum Zitat Chagnes, A. (2012) La technologie lithium-ion. La Revue 3EI 69:69–74 Chagnes, A. (2012) La technologie lithium-ion. La Revue 3EI 69:69–74
3.
Zurück zum Zitat Chagnes A, Swiatowska J (eds) (2015) Lithium process chemistry: resources, extractions, batteries and recycling. Elsevier, Amsterdam Chagnes A, Swiatowska J (eds) (2015) Lithium process chemistry: resources, extractions, batteries and recycling. Elsevier, Amsterdam
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Zurück zum Zitat Pillot C (2018) The rechargeable battery market and main trends 2017–2025. Paper presented at R&D stream lithium-ion development & commercialization delivering higher performance at lower cost, Fort Lauderdale, Florida (USA), 28–29 March 2018 Pillot C (2018) The rechargeable battery market and main trends 2017–2025. Paper presented at R&D stream lithium-ion development & commercialization delivering higher performance at lower cost, Fort Lauderdale, Florida (USA), 28–29 March 2018
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Zurück zum Zitat Chagnes A, Cote G (2010) Séparation du Cobalt et du Nickel à l’aide du Cyanex® 272 par extraction liquide-liquide. L’Actualité Chimique 346:29–347 Chagnes A, Cote G (2010) Séparation du Cobalt et du Nickel à l’aide du Cyanex® 272 par extraction liquide-liquide. L’Actualité Chimique 346:29–347
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Zurück zum Zitat Omelchuk K, Szczepański P, Shrotre A, Haddad M, Chagnes A (2017) Effects of structural changes of new organophosphorus cationic exchangers on solvent extraction of cobalt, nickel and manganese from acidic chloride media. RSC Adv 7:5660–5668CrossRef Omelchuk K, Szczepański P, Shrotre A, Haddad M, Chagnes A (2017) Effects of structural changes of new organophosphorus cationic exchangers on solvent extraction of cobalt, nickel and manganese from acidic chloride media. RSC Adv 7:5660–5668CrossRef
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Zurück zum Zitat Omelchuk K, Chagnes A (2018) New cationic exchangers for the recovery of cobalt(II), nickel(II) and manganese(II) from acidic chloride solutions: modelling of extraction curves. Hydrometallurgy 180:96–103CrossRef Omelchuk K, Chagnes A (2018) New cationic exchangers for the recovery of cobalt(II), nickel(II) and manganese(II) from acidic chloride solutions: modelling of extraction curves. Hydrometallurgy 180:96–103CrossRef
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Zurück zum Zitat Omelchuk K, Stambouli M, Chagnes A (2018) Investigation of aggregation and acid dissociation of new cationic exchangers for liquid–liquid extraction. J Mol Liq J Mol Liq 262:111–118CrossRef Omelchuk K, Stambouli M, Chagnes A (2018) Investigation of aggregation and acid dissociation of new cationic exchangers for liquid–liquid extraction. J Mol Liq J Mol Liq 262:111–118CrossRef
9.
Zurück zum Zitat Chagnes, A. (2019) Simulation of solvent extraction flowsheets by a global model combining physicochemical and engineering approaches—application to cobalt(II) extraction by D2EHPA, accepted in solvent extraction and ion exchange (in Press) Chagnes, A. (2019) Simulation of solvent extraction flowsheets by a global model combining physicochemical and engineering approaches—application to cobalt(II) extraction by D2EHPA, accepted in solvent extraction and ion exchange (in Press)
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Zurück zum Zitat Collet S, Chagnes A, Courtaud B, Thiry J, Cote G (2009) Solvent extraction of uranium from acidic sulfate media by Alamine®336: computer simulation and optimization of the flowsheets. J Chem Technol Biotechnol 84:1331–1337CrossRef Collet S, Chagnes A, Courtaud B, Thiry J, Cote G (2009) Solvent extraction of uranium from acidic sulfate media by Alamine®336: computer simulation and optimization of the flowsheets. J Chem Technol Biotechnol 84:1331–1337CrossRef
Metadaten
Titel
Development of a Physiochemical Model Combined with an Engineering Model for Predicting Solvent Extraction Performances Within the Context of Lithium-Ion Battery Recycling
verfasst von
Alexandre Chagnes
Copyright-Jahr
2020
DOI
https://doi.org/10.1007/978-3-030-36758-9_1

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