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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2017

08.09.2016 | Original Paper: Characterization methods of sol-gel and hybrid materials

Development of an ecofriendly silane sol-gel coating with zinc acetylacetonate corrosion inhibitor for active protection of mild steel in sodium chloride solution

verfasst von: Marzieh Taheri, Reza Naderi, Mohsen Saremi, Mohammad Mahdavian

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2017

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Abstract

This work intends to develop an ecofriendly silane sol-gel coating with zinc acetylacetonate for active protection of mild steel. This water-based silane coating was composed of γ-glycidoxypropyltrimethoxysilane, tetraethoxysilane and methyltriethoxysilane. The optimum inhibitor concentration was determined using electrochemical impedance spectroscopy. The electrochemical impedance spectroscopy data indicated no effect of zinc acetylacetonate on the coating barrier properties, which was confirmed by field emission scanning electron microscope (field emission scanning electron microscope), energy dispersive X-ray spectroscopy and fourier transform infrared spectroscopy surface analysis. From the charge transfer resistance, the superiority of inhibitor-doped films was associated with the function of zinc acetylacetonate at the interface. The electrochemical measurements showed an increase in the corrosion resistance of bare metal in sodium chloride solution with zinc acetylacetonate. From the results of field emission scanning electron microscope, energy dispersive X-ray spectroscopy, and atomic-force microscopy surface analysis, the corrosion control was suggested to be attributed to formation of a protective layer on the surface with contribution of zinc acetylacetonate.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-016-4180-3/MediaObjects/10971_2016_4180_Figa_HTML.gif
Vorheriger Artikel Controlled surface modification of gold nanostructures with functionalized silicon polymers
Nächster Artikel Best compromise for photocatalytic activity and hydrophilicity: N-doped TiO2 films under UV light

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Literatur
1.
Juan-Diaz MJ, Martinez-Ibanez M, Hernandez-Escolano M, Cabedo RIL, Suay J, Gurruchaga M, Goni I (2014) Study of the degradation of hybrid sol-gel coatings in aquous medium. Prog Org Coat 77:1799–1806CrossRef
2.
Vignesh RB, Edison TNJI, Sethuraman MG (2014) Sol-gel coating with 3-mercaptopropyltrimethoxysilane as precursor for corrosion protection of Aluminium metal. J Mater Sci Technol 30:814–820CrossRef
3.
Kirtay S (2014) Preparation of hybrid silica sol-gel coatings on mild steel surfaces and evaluation of their corrosion resistance. Prog Org Coat 77:1861–1866CrossRef
4.
Gandhi JS, Metroke TL, Eastman MA, Van Ooij WJ, Apblett A (2006) Effect of the degree of hydrolysis and condensation of bis-[triethoxysilylpropyl]tetrasulfide on the corrosion protection of coated Aluminum alloy 2024-T3. Corrosion 62:612–623CrossRef
5.
Zheludkevich M, Serra R, Montemor MF, Ferreira MGS (2005) Oxide nanoparticle reservoirs for storage and prolonged release of the corrosion inhibitors. Electrochem Commun 7:836–840CrossRef
6.
Ansari F, Naderi R, Dehghanian C (2015) Improvement in the corrosion resistance of stainless steel 304L in sodium chloride solution by a nanoclay incorporated silane coating. RSC Adv 5:706–716CrossRef
7.
Zaharescu M, Barau L, Raps D, Gammel F, Rosero-Navarro NC, Castro Y, Duran A, Aparicio M (2009) SiO2 based hybrid inorganic-organic films doped with TiO2-CeO2 nanoparticles for corrosion protection of AA2024 and Mg-AZ31B alloys. Corros Sci 51:1998–2005CrossRef
8.
Fedel M, Callone E, Dire S, Deflorian F, Olivier MG, Poelman M (2014) Effect of Na-montmorillonite sonication on the protective properties of hybrid silica coatings. Electrochim Acta 124:90–99CrossRef
9.
Naderi R, Fedel M, Deflorian F, Poelman M, Olivier M (2013) Synergistic effect of clay nanoparticles and cerium component on the corrosion behavior of eco-friendly silane sol-gel layer applied on pure aluminum. Surf Coat Technol 224:93–100CrossRef
10.
Motte C, Poelman M, Roobroeck A, Fedel M, Deflorian F, Olivier MG (2012) Improvement of corrosion protection offerred to galvanized steel by incorporation of lanthanide modified nanoclays in silane layer. Prog Org Coat 74:326–333CrossRef
11.
Ghazi A, Ghasemi E, Mahdavian M, Ramezanzadeh B, Rostami M (2015) The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating. Corros Sci 94:207–215CrossRef
12.
Kong G, Lu J, Zhang S, Che C, Wu H (2010) A comparative study of molybdate/silane composite films on galvanised steel with different treatment processes. Surf Coat Technol 205:545–550CrossRef
13.
Dalmoro V, Dos Santos JH, Armelin E, Aleman C, Azambuja D (2012) Phosphonic acid/silica-based films: A potential treatment for corrosion protection. Corros Sci 60:173–180CrossRef
14.
Cambon J, Ansart F, Bonino J, Turq V (2012) Effect of cerium concentration on corrosion resistance and polymerization of hybrid sol–gel coating on martensitic stainless steel. Prog Org Coat 75:486–493CrossRef
15.
Correa PS, Malfatti CF, Azambuja DS (2011) corrosion behavior study of AZ91 magnesium alloy coated with methyltriethoxysilane doped with cerium ions. Prog Org Coat 72:739–747CrossRef
16.
Trabelsi W, Triki E, Dhouibi L, Ferreira MGS, Zheludkevich ML, Montemor MF (2006) The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanised steel substrates. Surf Coat Technol 200:4240–4250CrossRef
17.
Zandi Zand R, Verbeken K, Adriaens A (2012) Corrosion resistance performance of cerium doped silica sol-gel coatings on 304L stainless steel. Prog Org Coat 75:463–473CrossRef
18.
Bahrami M, Borhani GH, Bakhshi SR, Ghasemi A (2015) Preparation and evaluation of corrosion behaviour of GPTMS-TEOS hybrid coatings containing Zr and Ce on aluminium alloy 6061-T6. J Sol-Gel Sci Technol 76:552–561CrossRef
19.
Barranco V, Carmona N, Galvan JC, Grobelny M, Kwiatkowski L, Villegas MA (2010) Electrochemical study of tailored sol-gel thin films as pre-treatment prior to organic coating for AZ91 magnesium alloy. Prog Org Coat 68:347–355CrossRef
20.
Varma PCR, Duffy B, Cassidy J (2009) Influence of magnesium nitrate on the corrosion performance of sol-gel coated AA2024-T3 aluminium alloy. Surf Coat Technol 204:277–285CrossRef
21.
Roussi E, Tsetsekou A, Skarmoustsou A, Charitidis CA, Karantonis A (2013) Anticorrosion and nanomechanical performance of hybrid organo-silicate coatings integrating corrosion inhibitors. Surf Coat Technol 232:131–141CrossRef
22.
Raps D, Hack T, Wehr J, Zeludkevich ML, Bastos AC, Ferreira MGS, Nuyken O (2009) Electrochemical study of inhibitor-containing organic-inorganic hybrid coatings on AA2024. Corros Sci 51:1012–1021CrossRef
23.
Tian Z, Shi H, Liu F, Xu S, Han EH (2015) Inhibiting effect of 8-hydroxyquinoline on the corrosion of silane based sol-gel coatings on AA2024-T3. Prog Org Coat 82:81–90CrossRef
24.
Asadi N, Naderi R, Saremi M (2014) Determination of optimum concentration of cloisite in an eco-friendly silane sol-gel film to improve corrosion resistance of mild steel. Appl Clay Sci 95:243–251CrossRef
25.
Asadi N, Naderi R, Saremi M, Arman SY, Fedel M, Deflorian F (2014) Study of corrosion protection of mild steel by eco-friendly silane sol-gel coating. J Sol-Gel Sci Technol 70:329–338CrossRef
26.
Asadi N, Naderi R, Saremi M (2014) Effect of curing conditions on the protective performance of an ecofriendly hybrid silane Sol–gel coating with clay nanoparticles applied on mild steel. Ind Eng Chem Res 53:10644CrossRef
27.
Mahdavian M, Naderi R (2011) Corrosion inhibition of mild steel in sodium chloride solution by some zinc complexes. Corros Sci 53:1194–1200CrossRef
28.
Olivier MG, Fedel M, Sciamanna V, Vandermiers C, Motte C, Poelman M, Deflorian F (2011) Study of the effect of nanoclay incorporation on the rheological properties and corrosion protection by a silane layer. Prog Org Coat 72:15–20CrossRef
29.
Rahimi H, Najafabadi AH, Shoja Razavi R, Paimozd E (2013) Optimization of process factors for the synthesis of advanced chromate-free nanocomposite sol-gel coatings for corrosion protection of marine aluminum alloy AA5083 by design of experiment. Prog Org Coat 76:307–317CrossRef
30.
Van Oij WJ, Stacy M, Seth A, Mugada T, Gandhi J, Puomi P (2005) Corrosion protection properties of organofunctional silanes–an overview. Tsinghua Sci Technol 10:639–664CrossRef
31.
Hirschorn B, Orazem ME, Tribollet B, Vivier V, Frateur I, Musiani M (2010) Determination of effective capacitance and film thickness from constant-phase-element parameters. Electrochim Acta 55:6218–6227CrossRef
Metadaten
Titel
Development of an ecofriendly silane sol-gel coating with zinc acetylacetonate corrosion inhibitor for active protection of mild steel in sodium chloride solution
verfasst von
Marzieh Taheri
Reza Naderi
Mohsen Saremi
Mohammad Mahdavian
Publikationsdatum
08.09.2016
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-4180-3

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