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Erschienen in: European Journal of Wood and Wood Products 3/2015

01.05.2015 | Original

Development of technology for production and application of graphite from hydrolytic lignin

verfasst von: Olga V. Popova, Mikhail Yu. Serbinovskiy, Аnna G. Abramova

Erschienen in: European Journal of Wood and Wood Products | Ausgabe 3/2015

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Abstract

The fine-dispersed artificial graphite is produced from hydrolytic lignin by thermolysis followed by graphitization. The article describes the influence of grinding and thermolysis on the granulometric composition of hydrolytic lignin powders, the carbon-ba se material, produced by thermolysis from lignin and artificial graphite. This research develops the rational technology of producing artificial graphite from lignin, defines its structural and physical characteristics. Graphite consists of particles with a size less than 45 μ for more than 80 %. The degree of graphitization of the graphite from lignin is not less than 94 %. The possibility of application of graphite to synthesis of intercalation compounds and thermally expanded graphite production is described.

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Literatur
Zurück zum Zitat Amutio M, Lopez G, Alvarez J, Moreira R, Duarte G, Nunes J, Olazar M, Bilbao J (2013) Pyrolysis kinetics of forestry residues from the Portuguese Central Inland Region. Chem Eng Res Des 91:2682–2690CrossRef Amutio M, Lopez G, Alvarez J, Moreira R, Duarte G, Nunes J, Olazar M, Bilbao J (2013) Pyrolysis kinetics of forestry residues from the Portuguese Central Inland Region. Chem Eng Res Des 91:2682–2690CrossRef
Zurück zum Zitat Baker DA, Rials TG (2013) Recent advances in low-cost carbon fiber manufacture from lignin. J Appl Polym Sci 130:713–728CrossRef Baker DA, Rials TG (2013) Recent advances in low-cost carbon fiber manufacture from lignin. J Appl Polym Sci 130:713–728CrossRef
Zurück zum Zitat Bilbao R, Millera A, Arauzo (1990) Kinetics of weight loss by thermal decomposition of different lignocellulosic materials. Relation between the results obtained from isothermal and dynamic experiments. Thermochim Acta 165:103–112CrossRef Bilbao R, Millera A, Arauzo (1990) Kinetics of weight loss by thermal decomposition of different lignocellulosic materials. Relation between the results obtained from isothermal and dynamic experiments. Thermochim Acta 165:103–112CrossRef
Zurück zum Zitat Caballero AJ, Font R, Marcilla A (1996) Study of the primary pyrolysis of Kraft lignin at high heating rates: yields and kinetics. J Anal Appl Pyrol 36:159–178CrossRef Caballero AJ, Font R, Marcilla A (1996) Study of the primary pyrolysis of Kraft lignin at high heating rates: yields and kinetics. J Anal Appl Pyrol 36:159–178CrossRef
Zurück zum Zitat Ferdous D, Dalai AK, Bej SK, Thring RW (2002) Pyrolysis of lignins: experimental and kinetic studies. Energy Fuel 16:1405–1412CrossRef Ferdous D, Dalai AK, Bej SK, Thring RW (2002) Pyrolysis of lignins: experimental and kinetic studies. Energy Fuel 16:1405–1412CrossRef
Zurück zum Zitat Fialkov AS (1965) Structure formation and properties of graphitized materials. Metallurgiya, Moscow (in Russian) Fialkov AS (1965) Structure formation and properties of graphitized materials. Metallurgiya, Moscow (in Russian)
Zurück zum Zitat Kadla JF, Kubo S, Gilbert RD, Venditti RA (2002) Lignin-based carbon fibers. In: Hu TQ (ed) Chemical modification, properties, and usage of lignin. Springer, US, pp 121–137CrossRef Kadla JF, Kubo S, Gilbert RD, Venditti RA (2002) Lignin-based carbon fibers. In: Hu TQ (ed) Chemical modification, properties, and usage of lignin. Springer, US, pp 121–137CrossRef
Zurück zum Zitat Kaplunova TS, Abduazimov HA, Ismailova PL, Shermatov BÉ (1990) Gas-chromatographic investigation of the products of the thermolysis of hydrolysis lignin. Chem Nat Compd 26:356–357CrossRef Kaplunova TS, Abduazimov HA, Ismailova PL, Shermatov BÉ (1990) Gas-chromatographic investigation of the products of the thermolysis of hydrolysis lignin. Chem Nat Compd 26:356–357CrossRef
Zurück zum Zitat Khol’kin YT (1989) Technology of the hydrolysis industry. Lesnaya promyshlennost, Moscow (in Russian) Khol’kin YT (1989) Technology of the hydrolysis industry. Lesnaya promyshlennost, Moscow (in Russian)
Zurück zum Zitat Kubo S, Uraki Y, Sano Y (2003) Catalytic graphitization of hardwood acetic acid lignin with nickel acetate. J Wood Sci 49:188–192CrossRef Kubo S, Uraki Y, Sano Y (2003) Catalytic graphitization of hardwood acetic acid lignin with nickel acetate. J Wood Sci 49:188–192CrossRef
Zurück zum Zitat Lai IZ, Sarkanen KV (1971) Isolation and Structural Studies. In: Sarkanen KV, Ludwig CH (eds) Lignins: occurrence, formation, structure and reactions. Wiley, New York, pp 165–240 Lai IZ, Sarkanen KV (1971) Isolation and Structural Studies. In: Sarkanen KV, Ludwig CH (eds) Lignins: occurrence, formation, structure and reactions. Wiley, New York, pp 165–240
Zurück zum Zitat Mohan D, Pittman CU Jr, Steele PH (2006) Pyrolysis of wood/biomass for bio-oil: a critical review. Energ Fuel 20:848–889CrossRef Mohan D, Pittman CU Jr, Steele PH (2006) Pyrolysis of wood/biomass for bio-oil: a critical review. Energ Fuel 20:848–889CrossRef
Zurück zum Zitat Nassar MM, Mackay GDM (1984) Mechanism of thermal decomposition of lignin. Wood Fiber Sci 16:441–453 Nassar MM, Mackay GDM (1984) Mechanism of thermal decomposition of lignin. Wood Fiber Sci 16:441–453
Zurück zum Zitat Popova OV, Popova SS, Olshanskaya LN (2008) Prospects for using artificial graphite produced from lignin in electrodes of chemical power cells. Russ J Appl Chem 81:751–756 Popova OV, Popova SS, Olshanskaya LN (2008) Prospects for using artificial graphite produced from lignin in electrodes of chemical power cells. Russ J Appl Chem 81:751–756
Zurück zum Zitat Rabinovich ML (2010) Wood hydrolysis industry in the Soviet Union and Russia: a mini-review. Cell Chem Technol 44:173–186 Rabinovich ML (2010) Wood hydrolysis industry in the Soviet Union and Russia: a mini-review. Cell Chem Technol 44:173–186
Zurück zum Zitat Várhegyi G, Antal JM, Jakab E, Szabó P (1997) Kinetic modeling of biomass pyrolysis. J Anal Appl Pyrol 42:73–87CrossRef Várhegyi G, Antal JM, Jakab E, Szabó P (1997) Kinetic modeling of biomass pyrolysis. J Anal Appl Pyrol 42:73–87CrossRef
Zurück zum Zitat Wang S, Wang K, Liu Q, Gu Y, Luo Z, Cen K, Fransson T (2009) Comparison of the pyrolysis behavior of lignins from different tree species. Biotechnol Adv 27:562–567CrossRefPubMed Wang S, Wang K, Liu Q, Gu Y, Luo Z, Cen K, Fransson T (2009) Comparison of the pyrolysis behavior of lignins from different tree species. Biotechnol Adv 27:562–567CrossRefPubMed
Zurück zum Zitat Yakovlev AV, Finaenov AI, Zabud’kov SL, Yakovleva EV (2006) Thermally expanded graphite: synthesis, properties, and prospects for use. Russ J Appl Chem 79(11):1741–1751CrossRef Yakovlev AV, Finaenov AI, Zabud’kov SL, Yakovleva EV (2006) Thermally expanded graphite: synthesis, properties, and prospects for use. Russ J Appl Chem 79(11):1741–1751CrossRef
Metadaten
Titel
Development of technology for production and application of graphite from hydrolytic lignin
verfasst von
Olga V. Popova
Mikhail Yu. Serbinovskiy
Аnna G. Abramova
Publikationsdatum
01.05.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
European Journal of Wood and Wood Products / Ausgabe 3/2015
Print ISSN: 0018-3768
Elektronische ISSN: 1436-736X
DOI
https://doi.org/10.1007/s00107-015-0881-5

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