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Fluid Dynamics
Erschienen in: Fluid Dynamics 4/2023

01.08.2023

Diffusion Coefficients of Electronically Excited Molecules

verfasst von: A. S. Sharipov, B. I. Loukhovitski, A. V. Pelevkin

Erschienen in: Fluid Dynamics | Ausgabe 4/2023

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Abstract

The influence of electronic excitation of molecules on their diffusion coefficients is studied. Based on the electrical properties of some molecules (O2, OH, CO, N2, H2O, and HO2) in various electronic states reported elsewhere and obtained by us using quantum-chemical calculations, the binary coefficients of diffusion on the main components of atmospheric air (N2, O2, H2O, and Ar) over a wide temperature range are estimated. It is shown that the diffusion coefficients of electronically excited molecules can differ significantly from those of the specified molecules in the ground electronic state, especially for high excitation energies, and in the case of the diffusion of a polar molecule in a polar buffer gas.
Vorheriger Artikel Heat-Flux Measurement by Sensors Based on Anisotropic Thermoelements in a Gas-Dynamics Experiment Shock Tubes
Nächster Artikel Level Adiabatic Model for the Dissociation of Diatomic Molecules

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Metadaten
Titel
Diffusion Coefficients of Electronically Excited Molecules
verfasst von
A. S. Sharipov
B. I. Loukhovitski
A. V. Pelevkin
Publikationsdatum
01.08.2023
Verlag
Pleiades Publishing
Erschienen in
Fluid Dynamics / Ausgabe 4/2023
Print ISSN: 0015-4628
Elektronische ISSN: 1573-8507
DOI
https://doi.org/10.1134/S0015462823600943

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