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Journal of Nanoparticle Research

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01.06.2021 | Research paper

Direct dual CaIn₂S₄/Bi₂WO₆ semiconductor nanocomposites with efficient inter-cross-sectional charge carrier transfer for enhanced visible light photocatalysis

verfasst von: Thillai Sivakumar Natarajan, Rajesh J. Tayade

Erschienen in: Journal of Nanoparticle Research | Ausgabe 6/2021

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Abstract

A visible light-responsive redox-mediator-free calcium indium sulfide (CaIn₂S₄) and bismuth tungstate (Bi₂WO₆)–based direct dual semiconductor nanocomposites were prepared by combination of hydrothermal and wetness impregnation methods. The results substantiated the formation of CaIn₂S₄ marigold flowers, the flower-like structure of the Bi₂WO₆, and CaIn₂S₄/Bi₂WO₆ nanocomposites. UV–Vis-DRS analysis confirmed that visible light response of Bi₂WO₆ was considerably enhanced after combining with CaIn₂S₄. The inter-cross-sectional charge carrier transfer during photocatalysis using synthesized catalysts was studied by determining the band position of Bi₂WO₆ and CaIn₂S_4, and photoluminescence analysis. The adsorption of rhodamine B (RhB) dye study revealed that after coupling with CaIn₂S₄, the adsorption capacity of Bi₂WO₆ was significantly improved. For 15%-CaIn₂S₄/Bi₂WO₆, 38% of RhB dye was adsorbed, whereas it was 27% for bare Bi₂WO₆. The 15%-CaIn₂S₄/Bi₂WO₆ nanocomposite showed higher percentage degradation for RhB (82%) dye as compared to the other percentage loaded composites, bare Bi₂WO₆ (59%) and CaIn₂S₄ (72%). Photoluminescence results revealed that photo-generated electron–hole pair recombination rate was drastically suppressed after coupling with CaIn₂S₄ which may be presumed to inter-cross-sectional transfer of photo-generated charge carriers. The synergic effect of enhanced adsorption capacity and efficient separation of electron–hole pairs were accountable for the enhanced photodegradation efficiency under visible light.

Vorheriger Artikel Synthesis of silicon nanoparticles using a novel reactor with an elongated reaction zone created by coaxially aligned SiH4 gas and a CO2 laser beam

Nächster Artikel Bisdemethoxycurcumin-conjugated vitamin E TPGS liposomes ameliorate poor bioavailability of free form and evaluation of its analgesic and hypouricemic activity in oxonate-treated rats

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Titel: Direct dual CaIn2S4/Bi2WO6 semiconductor nanocomposites with efficient inter-cross-sectional charge carrier transfer for enhanced visible light photocatalysis
verfasst von: Thillai Sivakumar Natarajan
Rajesh J. Tayade
Publikationsdatum: 01.06.2021
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 6/2021
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-021-05252-y

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