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Journal of Materials Science
Erschienen in: Journal of Materials Science 10/2021

03.01.2021 | Chemical routes to materials

Direct synthesis of hierarchical zeolites through mesoporous 3D wormhole framework using single-head quaternary ammonium salt as structure-directing agent

verfasst von: Tianyi Fu, He Ding, Jingshuang Zhang, Peng Bai, Jiafei Lyu, Xianghai Guo

Erschienen in: Journal of Materials Science | Ausgabe 10/2021

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Abstract

Hierarchical aluminosilicate zeolites with uniform mesoporosity were successfully synthesized by one-stage crystallization under constant temperature with a novel single-head quaternary ammonium salt ([C18H37–N+(CH3)2–C6H12–N(CH3)2]Br−) as mesoporogen and structure-directing agent (SDA). Through precisely controlling the molar ratio of Si/Al and synthetic time, the mesoporous 3D wormhole framework (MCM-48) and crystalline microporous MFI structure were simultaneously constructed, revealed by a series of in-depth characteristic studies. Combining the advantages of the significantly improved diffusion from the mesoporous MCM-48 and the strong framework acidity of the crystalline microporous MFI zeolite, the hierarchical aluminosilicate zeolites exhibited outstanding catalytic activity with good reusability towards bulky aldol condensation compared with the conventional meso- or microporous zeolites.

Graphical abstract

Vorheriger Artikel Synthesis of Pt-doped SnO2 flower-like hierarchical structure and its gas sensing properties to isopropanol
Nächster Artikel Facile synthesis of nitrogen-doped foam-like carbon materials from purslane stem as efficient metal-free catalysts for oxidative coupling of amines to imines

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Metadaten
Titel
Direct synthesis of hierarchical zeolites through mesoporous 3D wormhole framework using single-head quaternary ammonium salt as structure-directing agent
verfasst von
Tianyi Fu
He Ding
Jingshuang Zhang
Peng Bai
Jiafei Lyu
Xianghai Guo
Publikationsdatum
03.01.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-05659-3

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