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Journal of Materials Science

Erschienen in:

03.01.2021 | Chemical routes to materials

Facile synthesis of nitrogen-doped foam-like carbon materials from purslane stem as efficient metal-free catalysts for oxidative coupling of amines to imines

verfasst von: Yongbin Sun, Chao Hou, Xiaoqun Cao, Kun Liu

Erschienen in: Journal of Materials Science | Ausgabe 10/2021

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Abstract

We synthesized foam-like carbon materials from purslane stem by soxhlet extraction and pyrolysis two steps. The results demonstrate that the solvents used in soxhlet extraction can extract different components from purslane stem and further make significant impacts on the structure and composition of the obtained carbon materials. When applied to catalytic oxidative coupling of amines to imines, the most active catalyst is the carbon material derived from the purslane stem pretreated with ethanol, which can be attributed to its high surface area, large pore size and accessible active sites. In addition, the catalyst shows good stability, which can be recycled at least six times and applicable in the large-scale catalytic reaction. Moreover, the carbon materials derived from celery stem and apricot leaf pretreated with ethanol in soxhlet extraction also show higher catalytic activity than the carbon materials pretreated with ethyl acetate and water, which implies that this simple synthetic process is generally applicable to a certain extent. Hence, this study can provide new way toward the synthesis of high-performance carbon materials from biomass.

Vorheriger Artikel Direct synthesis of hierarchical zeolites through mesoporous 3D wormhole framework using single-head quaternary ammonium salt as structure-directing agent

Nächster Artikel Structural evolutions of layered α-MoO3 crystals during rapid thermal annealing upon Pb-species at elevated temperatures

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Titel: Facile synthesis of nitrogen-doped foam-like carbon materials from purslane stem as efficient metal-free catalysts for oxidative coupling of amines to imines
verfasst von: Yongbin Sun
Chao Hou
Xiaoqun Cao
Kun Liu
Publikationsdatum: 03.01.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 10/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-05664-6

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