nach oben

Cellulose

Erschienen in:

27.11.2015 | Original Paper

Dissolution of cellobiose in the aqueous solutions of chloride salts: Hofmeister series consideration

verfasst von: Zhijing Liu, Chao Zhang, Ruigang Liu, Wushou Zhang, Hongliang Kang, Pingping Li, Yong Huang

Erschienen in: Cellulose | Ausgabe 1/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The effects of chloride salts on the dissolution of cellobiose in aqueous solution were investigated using calorimetry and ¹H NMR. The dissolution of cellobiose in salt solutions is a typical entropy-driven process. The activity of ZnCl₂ and LiCl hydrated ions is enhanced as the hydration number decreases with increasing temperature. Zn²⁺ and Li⁺ hydrates can interact with the oxygen atoms at the O5 and O6 positions of cellobiose and associate with the Cl⁻ anions, leading to the breakage of cellobiose hydrogen bonds. We found that the solubility of cellobiose in aqueous solutions is on the order of ZnCl₂ > LiCl > NaCl > H₂O > KCl > NH₄Cl, which is consistent with the Hofmeister series. For the first time, we recognized the specific ionic effects of the Hofmeister series on the dissolution of cellobiose in salt aqueous solutions. This finding is helpful for understanding the dissolving mechanism of cellulose in aqueous solvents with salts and providing fundamental knowledge for finding and designing new cellulose solvents.

Vorheriger Artikel Effect of xylan in hardwood pulp on the reaction rate of TEMPO-mediated oxidation and the rheology of the final nanofibrillated cellulose gel

Nächster Artikel Glutaraldehyde crosslinking of arabinoxylan produced from corn ethanol residuals

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Allolio C, Salas-Illanes N, Desmukh YS, Hansen MR, Sebastiani D (2013) H-bonding competition and clustering in aqueous LiI. J Phys Chem B 117:9939–9946CrossRef

Altaner CM, Thomas LH, Fernandes AN, Jarvis MC (2014) How cellulose stretches: synergism between covalent and hydrogen bonding. Biomacromolecules 15:791–798CrossRef

Arakawa T, Timasheff SN (1984) Mechanism of protein salting in and salting out by divalent-cation salts—balance between hydration and salt binding. Biochemistry 23:5912–5923CrossRef

Collins KD (2004) Ions from the Hofmeister series and osmolytes: effects on proteins in solution and in the crystallization process. Methods 34:300–311CrossRef

Collins KD, Washabaugh MW (1985) The hofmeister effect and the behavior of water at interfaces. Q Rev Biophys 18:323–422CrossRef

Collins KD, Neilson GW, Enderby JE (2007) Ions in water: characterizing the forces that control chemical processes and biological structure. Biophys Chem 128:95–104CrossRef

Cooper A (2011) Microcalorimetry of heat capacity and volumetric changes in biomolecular interactions-the link to solvation? J Therm Anal Calorim 104:69–73CrossRef

Cox JD, Riedel O (1974) Recommended reference materials for the realization of physicochemical properties: enthalpy. Pure Appl Chem 40:432–433

Fischer S, Voigt W, Fischer K (1999) The behaviour of cellulose in hydrated melts of the composition LiX·nH₂O (X = I⁻, NO₃ ⁻, CH₃COO⁻, ClO₄ ⁻). Cellulose 6:213–219CrossRef

Fischer S, Leipner H, Thummler K, Brendler E, Peters J (2003) Inorganic molten salts as solvents for cellulose. Cellulose 10:227–236CrossRef

Florin E, Kjellander R, Eriksson JC (1984) Salt effects on the cloud point of the poly(ethylene oxide) + water-system. J Chem Soc -Faraday Trans I 80:2889–2910CrossRef

Garbacz P, Price WS (2014) ¹H NMR diffusion studies of water self-diffusion in supercooled aqueous sodium chloride solutions. J Phys Chem A 118:3307–3312CrossRef

Hattori M, Koga T, Shimaya Y, Saito M (1998a) Aqueous calcium thiocyanate solution as a cellulose solvent. Structure and interactions with cellulose. Polym J 30:43–48CrossRef

Hattori M, Shimaya Y, Saito M (1998b) Solubility and dissolved cellulose in aqueous calcium- and sodium-thiocyanate solution. Polym J 30:49–55CrossRef

Hattori M, Shimaya Y, Saito M (1998c) Structural changes in wood pulp treated by 55 wt% aqueous calcium thiocyanate solution. Polym J 30:37–42CrossRef

Heinze T (1998) New ionic polymers by cellulose functionalization. Macromol Chem Phys 199:2341–2364CrossRef

Heinze T, Liebert T (2001) Unconventional methods in cellulose functionalization. Prog Polym Sci 26:1689–1762CrossRef

Hindman JC (1962) Nuclear magnetic resonance effects in aqueous solutions of 1–1 electrolytes. J Chem Phys 36:1000–1015CrossRef

Isobe N, Chen XX, Kim UJ, Kimura S, Wada M, Saito T, Isogai A (2013) TEMPO-oxidized cellulose hydrogel as a high-capacity and reusable heavy metal ion adsorbent. J Hazard Mater 260:195–201CrossRef

Jiang ZW et al (2014) Intermolecular interactions and 3D structure in cellulose-NaOH-urea aqueous system. J Phys Chem B 118:10250–10257CrossRef

Kalcher I, Horinek D, Netz RR, Dzubiella J (2009) Ion specific correlations in bulk and at biointerfaces. J Phys-Condes Matter 21:424108CrossRef

Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: Fascinating biopolymer and sustainable raw material. Angew Chem Int Ed 44:3358–3393CrossRef

Kuga S (1980) The porous structure of cellulose gel regenerated from calcium thiocyanate solution. J Colloid Interface Sci 77:413–417CrossRef

Kunz W, Henle J, Ninham BW (2004) ‘Zur Lehre von der Wirkung der Salze’ (about the science of the effect of salts): Franz Hofmeister’s historical papers. Curr Opin Colloid Interface Sci 9:19–37CrossRef

Leipner H, Fischer S, Brendler E, Voigt W (2000) Structural changes of cellulose dissolved in molten salt hydrates. Macromol Chem Phys 201:2041–2049CrossRef

Letters K (1932) Viscosimetric analysis on the reaction of cellulose with concentrated zinc chloride solutions. Kolloid-Zeitschrift 58:229–239CrossRef

Liebert T (2010) Cellulose solvents—remarkable history, bright future. In: Liebert T, Heinze T, Edgar KJ (eds) Cellulose solvents: for analysis, shaping and chemical modification, vol 1033. American Chemical Society, Washington, DC, pp 3–54. doi:10.1021/bk-2010-1033

Lindman B, Karlstrom G, Stigsson L (2010) On the mechanism of dissolution of cellulose. J Mol Liq 156:76–81CrossRef

Liu ZJ et al (2015) Effects of additives on dissolution of cellobiose in aqueous solvents. Cellulose 22:1641–1652CrossRef

Lukanoff B, Stern W, Loth F, Dautzenber H (1984) Spherical or flat cellulose article preparation by adding formalin to cellulose suspended in calcium thiocyanate melt, heating, cooling, shaping the solution obtained and coagulating. Patent number: DD206675-A

Malinows ER, Knapp PS, Feuer B (1966) NMR studies of aqueous electrolyte solutions. I. Hydration number of NaCl determined from temperature effects on proton shift. J Chem Phys 45:4274–4279CrossRef

Medronho B, Lindman B (2014) Competing forces during cellulose dissolution: from solvents to mechanisms. Curr Opin Colloid Interface Sci 19:32–40CrossRef

Missoum K, Bras J, Belgacem MN (2012) Water redispersible dried nanofibrillated cellulose by adding sodium chloride. Biomacromolecules 13:4118–4125CrossRef

Muller N (1965) Concerning structural models for water and chemical-shift data. J Chem Phys 43:2555–2556CrossRef

Nishio Y, Chiba R, Miyashita Y, Oshima K, Miyajima T, Kimura N, Suzuki H (2002) Salt addition effects on mesophase structure and optical properties of aqueous hydroxypropyl cellulose solutions. Polym J 34:149–157CrossRef

Nishiyama Y, Langan P, Chanzy H (2002) Crystal structure and hydrogen-bonding system in cellulose I_β from synchrotron X-ray and neutron fiber diffraction. J Am Chem Soc 124:9074–9082CrossRef

Okur HI, Kherb J, Cremer PS (2013) Cations bind only weakly to amides in aqueous solutions. J Am Chem Soc 135:5062–5067CrossRef

Piekarski H, Nowicka B (2010) Calorimetric studies of interactions of some peptides with electrolytes, urea and ethanol in water at 298.15 K. J Therm Anal Calorim 102:31–36CrossRef

Ragauskas AJ et al (2006) The path forward for biofuels and biomaterials. Science 311:484–489CrossRef

Roshind MU, Tahtinen P, Niemitz M, Sjhohn R (2008) Complete assignments of the 1H and 13C chemical shifts and J(H, H) coupling constants in NMR spectra of D-glucopyranose and all D-glucopyranosyl-D-glucopyranosides. Carbohydr Res 343:101–112CrossRef

Schaschel E, Day MC (1968) Ion–solvent interaction. Solvation of the sodium ion. J Am Chem Soc 90:503–504CrossRef

Schneider WG, Bernstein HJ, Pople JA (1958) Proton magnetic resonance chemical shift of free (gaseous) and associated (liquid) hydride molecules. J Chem Phys 28:601–607CrossRef

Shoolery JN, Alder BJ (1955) Nuclear magnetic resonance in concentrated aqueous electrolytes. J Chem Phys 23:805–811CrossRef

Solomon BD, Barnes JR, Halvorsen KE (2007) Grain and cellulosic ethanol: history, economics, and energy policy. Biomass Bioenerg 31:416–425CrossRef

Thormann E (2012) On understanding of the Hofmeister effect: how addition of salt alters the stability of temperature responsive polymers in aqueous solutions. RSC Adv 2:8297–8305CrossRef

Traube J (1910) The attraction pressure. J Phys Chem 14:452–470CrossRef

Walrafen GE (1966) Raman spectral studies of effects of temperature on water and electrolyte solutions. J Chem Phys 44:1546–1558CrossRef

Warwicke JO (1967) Effect of chemical reagents on fine structure of cellulose. 4. Action of caustic soda on fine structure of cotton and ramie. J Polym Sci: Polym Chem 5:2579–2593CrossRef

Yang YJ, Shin JM, Kang TH, Kimura S, Wada M, Kim UJ (2014) Cellulose dissolution in aqueous lithium bromide solutions. Cellulose 21:1175–1181CrossRef

Zhang YJ, Cremer PS (2006) Interactions between macromolecules and ions: the Hofmeister series. Curr Opin Chem Biol 10:658–663CrossRef

Zhang YJ, Cremer PS (2010) Chemistry of Hofmeister anions and osmolytes. Annu Rev Phys Chem 61:63–83CrossRef

Zhang Y, Furyk S, Bergbreiter DE, Cremer PS (2005) Specific ion effects on the water solubility of macromolecules: PNIPAM and the Hofmeister series. J Am Chem Soc 127:14505–14510CrossRef

Zhang C, Liu RG, Xiang JF, Kang HL, Liu ZJ, Huang Y (2014) Dissolution mechanism of cellulose in N, N-dimethylacetamide/lithium chloride: revisiting through molecular interactions. J Phys Chem B 118:9507–9514CrossRef

Titel: Dissolution of cellobiose in the aqueous solutions of chloride salts: Hofmeister series consideration
verfasst von: Zhijing Liu
Chao Zhang
Ruigang Liu
Wushou Zhang
Hongliang Kang
Pingping Li
Yong Huang
Publikationsdatum: 27.11.2015
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-015-0827-4

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 1/2016

Effect of addition of microfibrillated cellulose to urea-formaldehyde on selected adhesive characteristics and distribution in particle board

The fiber charge measurement depending on the poly-DADMAC accessibility to cellulose fibers

Permittivity of a composite of cellulose, mineral oil, and water nanoparticles: theoretical assumptions

Phosphoric acid-based preparing of chitin nanofibers and nanospheres

The influences of enzymatic processing on physico-chemical and pigment dyeing characteristics of cotton fabrics

TEMPO nanofibrillated cellulose as template for controlled release of antimicrobial copper from PVA films