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Journal of Materials Science
Erschienen in: Journal of Materials Science 4/2018

25.10.2017 | Energy materials

Double-shelled hollow Na2FePO4F/C spheres cathode for high-performance sodium-ion batteries

verfasst von: Rui Ling, Shu Cai, Dongli Xie, Wenyu Shen, Xudong Hu, Yue Li, Shaoshuai Hua, Yangyang Jiang, Xiaohong Sun

Erschienen in: Journal of Materials Science | Ausgabe 4/2018

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Abstract

In this study, the hierarchical hollow Na2FePO4F/C microspheres as high-performance cathode for sodium-ion batteries (SIBs) are developed by adjusting the reaction time of solvothermal synthesis. With prolonging solvothermal time, the structure of the microspheres gradually changes from urchin-like hollow structure to acanthosphere-like hollow structure and finally to double-shelled hollow structure. Dissolution–recrystallization mechanism is proposed to better understand the formation of the double-shelled hollow microspheres of Na2FePO4F/C. When evaluated as cathode materials for SIBs, the double-shelled hollow Na2FePO4F/C sample delivers a discharge capacity as high as 120.1 mAh g−1 at 0.1 C and maintains the capacity retention of 92.5% at 1 C after 200 cycles. For the purpose of explaining the improved electrochemical performance of the double-shelled hollow Na2FePO4F/C materials, all the electrodes are analyzed with cyclic voltammetry and electrochemical impedance spectroscopy. It is found that the excellent electrochemical performances are mainly attributed to its unique structure, which can enhance electronic and ionic conductivity during repeated Na+ insertion/extraction processes.
Vorheriger Artikel Scalable and inexpensive strategy to fabricate CuO/ZnO nanowire heterojunction for efficient photoinduced water splitting
Nächster Artikel Direct growth of Cu2ZnSnS4 on three-dimensional porous reduced graphene oxide thin films as counter electrode with high conductivity and excellent catalytic activity for dye-sensitized solar cells

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Metadaten
Titel
Double-shelled hollow Na2FePO4F/C spheres cathode for high-performance sodium-ion batteries
verfasst von
Rui Ling
Shu Cai
Dongli Xie
Wenyu Shen
Xudong Hu
Yue Li
Shaoshuai Hua
Yangyang Jiang
Xiaohong Sun
Publikationsdatum
25.10.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 4/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1738-6

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