Skip to main content
Erschienen in: Tribology Letters 3/2019

01.09.2019 | Original Paper

Effect of Adding Tungsten Disulfide to a Copper Matrix on the Formation of Tribo-Film and on the Tribological Behavior of Copper/Tungsten Disulfide Composites

verfasst von: Lin Zhao, Pingping Yao, Taiming Gong, Haibin Zhou, Minwen Deng, Zonghao Wang, Zhongyi Zhang, Yelong Xiao, Fenghua Luo

Erschienen in: Tribology Letters | Ausgabe 3/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The tribological behavior and formation of tribo-film of copper/tungsten disulfide (WS2) composites featuring 0–30% WS2 volume fractions, prepared using spark plasma sintering were investigated. Results indicated that WS2 as addition into the copper matrix could effectively reduce the coefficient of friction (COF) of Cu/WS2 composites. The lowest COF obtained was 0.16, while the wear rate was approximately 5 × 10−5 mm3·N− 1·m−1 for the Cu/WS2 composite which contained 25vol% of WS2 (here defined as Cu-25WS2). X-ray photoelectron spectroscopy and transmission electron microscopy analyses indicated that an oxygen-rich tribo-film with a thickness of approximately 10 nm was formed on the wear track, while a thick layer which was rich in WS2 and Cu2S and with a thickness of approximately 50 nm was observed below the oxygen-rich tribo-film. The superior tribological properties could ascribed to the formation of these tribo-films.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Hammes, G., Schroeder, R., Binder, C., Klein, A.N., deMello, J.D.B.: Effect of double pressing/double sintering on the sliding wear of self-lubricating sintered composites. Tribol. Int. 70, 119–127 (2014)CrossRef Hammes, G., Schroeder, R., Binder, C., Klein, A.N., deMello, J.D.B.: Effect of double pressing/double sintering on the sliding wear of self-lubricating sintered composites. Tribol. Int. 70, 119–127 (2014)CrossRef
2.
Zurück zum Zitat Lin Liu, Z., Zhang, M., Dienwiebel: The runningin tribological behavior of Pbfree brass and its efect on microstructural evolution. Tribol. Lett. 65, 160 (2017)CrossRef Lin Liu, Z., Zhang, M., Dienwiebel: The runningin tribological behavior of Pbfree brass and its efect on microstructural evolution. Tribol. Lett. 65, 160 (2017)CrossRef
3.
Zurück zum Zitat Gebretsadik, D.W., Hardell, J., Prakash, B.: Friction and wear characteristics of different Pb-free bearing materials in mixed and boundary lubrication regimes. Wear. 340–341, 63–72 (2015)CrossRef Gebretsadik, D.W., Hardell, J., Prakash, B.: Friction and wear characteristics of different Pb-free bearing materials in mixed and boundary lubrication regimes. Wear. 340–341, 63–72 (2015)CrossRef
4.
Zurück zum Zitat Moustafa, S.F., El-Badry, S.A., Sanad, A.M., Kieback, B.: Friction and wear of copper-graphite composites made with Cu-coated and uncoated graphite powders. Wear. 253, 699–710 (2002)CrossRef Moustafa, S.F., El-Badry, S.A., Sanad, A.M., Kieback, B.: Friction and wear of copper-graphite composites made with Cu-coated and uncoated graphite powders. Wear. 253, 699–710 (2002)CrossRef
5.
Zurück zum Zitat Larionova, N.S., Nikonova, R.M., Ladyanov, V.I.: Mechanosynthesis of nanostructured composites copper-fullerite, copper-graphite. Adv. Powder Technol. 29, 399–406 (2018)CrossRef Larionova, N.S., Nikonova, R.M., Ladyanov, V.I.: Mechanosynthesis of nanostructured composites copper-fullerite, copper-graphite. Adv. Powder Technol. 29, 399–406 (2018)CrossRef
6.
Zurück zum Zitat Irtegov, Y., An, V., Machekhina, K., Lemachko, N.: Influence of copper nanoparticles on tribological properties of nanolamellar tungsten disulfide. Key Eng. Mater. 133–136 (2016)CrossRef Irtegov, Y., An, V., Machekhina, K., Lemachko, N.: Influence of copper nanoparticles on tribological properties of nanolamellar tungsten disulfide. Key Eng. Mater. 133–136 (2016)CrossRef
7.
Zurück zum Zitat Jiang, X., Fang, H.C., Xiao, P., Liu, T., Zhu, J.M., Wang, Y.C., Liu, P.F., Li, Y.: Influence of carbon coating with phenolic resin in natural graphite on the microstructures and properties of graphite/copper composites. J. Alloys Compd. 744, 165–173 (2018)CrossRef Jiang, X., Fang, H.C., Xiao, P., Liu, T., Zhu, J.M., Wang, Y.C., Liu, P.F., Li, Y.: Influence of carbon coating with phenolic resin in natural graphite on the microstructures and properties of graphite/copper composites. J. Alloys Compd. 744, 165–173 (2018)CrossRef
8.
Zurück zum Zitat Elkady, O.A.M., Abu-Oqail, A., Ewais, E.M.M., El-Sheikh, M.: Physico-mechanical and tribological properties of Cu/h-BN nanocomposites synthesized by PM route. J. Compd. 625, 309–317 (2015)CrossRef Elkady, O.A.M., Abu-Oqail, A., Ewais, E.M.M., El-Sheikh, M.: Physico-mechanical and tribological properties of Cu/h-BN nanocomposites synthesized by PM route. J. Compd. 625, 309–317 (2015)CrossRef
9.
Zurück zum Zitat Rajkumar, K., Aravindan, S.: Tribological behavior of microwave processed copper–nanographite composites. Tribol. Int. 57, 282–296 (2013)CrossRef Rajkumar, K., Aravindan, S.: Tribological behavior of microwave processed copper–nanographite composites. Tribol. Int. 57, 282–296 (2013)CrossRef
10.
Zurück zum Zitat Zhang, Y., Shockley, J.Michael, Vo, P., Chromik, R.R.: Tribological behavior of cold-sprayed Cu–MoS2 composite coating during dry sliding wear. Tribol. Lett. 62, 9 (2016)CrossRef Zhang, Y., Shockley, J.Michael, Vo, P., Chromik, R.R.: Tribological behavior of cold-sprayed Cu–MoS2 composite coating during dry sliding wear. Tribol. Lett. 62, 9 (2016)CrossRef
11.
Zurück zum Zitat Kato, H., Takama, M., Iwai, Y., Washida, K., Sasaki, Y.: Wear and mechanical properties of sintered copper-tin composites containing graphite or molybdenum disulfide. Wear. 255, 573–578 (2003)CrossRef Kato, H., Takama, M., Iwai, Y., Washida, K., Sasaki, Y.: Wear and mechanical properties of sintered copper-tin composites containing graphite or molybdenum disulfide. Wear. 255, 573–578 (2003)CrossRef
12.
Zurück zum Zitat Linlin Su, F., Gao, X., Han, R., Fu, E., Zhang: Tribological behavior of copper–graphite powder third body on copper-based friction materials. Tribol. Lett. 60, 30 (2015)CrossRef Linlin Su, F., Gao, X., Han, R., Fu, E., Zhang: Tribological behavior of copper–graphite powder third body on copper-based friction materials. Tribol. Lett. 60, 30 (2015)CrossRef
13.
Zurück zum Zitat Xu, S., Gao, X., Hu, M., Wang, D., Jiang, D. Sun, J., Zhou, F., Weng, L., Liu, W.: Microstructure evolution and enhanced tribological properties of Cu-doped WS2 films. Tribol. Lett. 55, 1–13 (2014)CrossRef Xu, S., Gao, X., Hu, M., Wang, D., Jiang, D. Sun, J., Zhou, F., Weng, L., Liu, W.: Microstructure evolution and enhanced tribological properties of Cu-doped WS2 films. Tribol. Lett. 55, 1–13 (2014)CrossRef
14.
Zurück zum Zitat An, V., Anisimov, E., Druzyanova, V., Burtsev, N., Shulepov, I., Khaskelberg, M.: Study of tribological behavior of Cu–MoS2 and Ag–MoS2 nanocomposite lubricants. SpringerPlus. 5, 72 (2016)CrossRef An, V., Anisimov, E., Druzyanova, V., Burtsev, N., Shulepov, I., Khaskelberg, M.: Study of tribological behavior of Cu–MoS2 and Ag–MoS2 nanocomposite lubricants. SpringerPlus. 5, 72 (2016)CrossRef
15.
Zurück zum Zitat Qian, G., Feng, Y., Li, B., Huang, S., Liu, H., Ding, K.: Effect of electrical current on the tribological behavior of the Cu-WS2-G composites in air and vacuum. Chin. J. Mech. Eng. 26, 384–392 (2013)CrossRef Qian, G., Feng, Y., Li, B., Huang, S., Liu, H., Ding, K.: Effect of electrical current on the tribological behavior of the Cu-WS2-G composites in air and vacuum. Chin. J. Mech. Eng. 26, 384–392 (2013)CrossRef
16.
Zurück zum Zitat Tyagi, R., Das, A.K., Mandal, A.: Electrical discharge coating using WS2 and Cu powder mixture for solid lubrication and enhanced tribological performance. Tribol. Int. 120, 80–92 (2018)CrossRef Tyagi, R., Das, A.K., Mandal, A.: Electrical discharge coating using WS2 and Cu powder mixture for solid lubrication and enhanced tribological performance. Tribol. Int. 120, 80–92 (2018)CrossRef
17.
Zurück zum Zitat Huang, S., Feng, Y., Liu, H., Ding, K., Qian, G.: Electrical sliding friction and wear properties of Cu-MoS2-graphite-WS2 nanotubes composites in air and vacuum conditions. Mater. Sci. Eng. A. 560, 685–692 (2013)CrossRef Huang, S., Feng, Y., Liu, H., Ding, K., Qian, G.: Electrical sliding friction and wear properties of Cu-MoS2-graphite-WS2 nanotubes composites in air and vacuum conditions. Mater. Sci. Eng. A. 560, 685–692 (2013)CrossRef
18.
Zurück zum Zitat Kovalchenko, A.M., Fushchich, O.I., Danyluk, S.: The tribological properties and mechanism of wear of Cu-based sintered powder materials containing molybdenum disulfide and molybdenum diselenite under unlubricated sliding against copper. Wear. 290–291,106–123 (2012)CrossRef Kovalchenko, A.M., Fushchich, O.I., Danyluk, S.: The tribological properties and mechanism of wear of Cu-based sintered powder materials containing molybdenum disulfide and molybdenum diselenite under unlubricated sliding against copper. Wear. 290–291,106–123 (2012)CrossRef
19.
Zurück zum Zitat Huiquan, C., Zhiyuan, Q., Lei, Z.: Tribological behavior of Cu matrix composites containing graphite and tungsten disulfide. Tribol. Trans. 6, 1037–1043 (2014) Huiquan, C., Zhiyuan, Q., Lei, Z.: Tribological behavior of Cu matrix composites containing graphite and tungsten disulfide. Tribol. Trans. 6, 1037–1043 (2014)
20.
Zurück zum Zitat Wang, Q., Chen, M., Shan, Z., Sui, C., Zhang, L., Zhu, S., Wang, F.: Comparative study of mechanical and wear behavior of Cu/WS2 composites fabricated by spark plasma sintering and hot pressing. J. Mater. Sci. Technol. 33, 1416–1423 (2017)CrossRef Wang, Q., Chen, M., Shan, Z., Sui, C., Zhang, L., Zhu, S., Wang, F.: Comparative study of mechanical and wear behavior of Cu/WS2 composites fabricated by spark plasma sintering and hot pressing. J. Mater. Sci. Technol. 33, 1416–1423 (2017)CrossRef
21.
Zurück zum Zitat Juszczyk, B., Kulasa, J., Malara, S., Czepelak, M., Malec, W., Cwolek, B., Wierzbicki, Ł: Tribological properties of copper-based composites with lubricating phase particles. Arch. Metall. Mater. 59 (2014) Juszczyk, B., Kulasa, J., Malara, S., Czepelak, M., Malec, W., Cwolek, B., Wierzbicki, Ł: Tribological properties of copper-based composites with lubricating phase particles. Arch. Metall. Mater. 59 (2014)
22.
Zurück zum Zitat Xiao, J., Zhang, W., Liu, L., Zhang, L., Zhang, C.: Tribological behavior of copper-molybdenum disulfide composites. Wear 384–385, 61–71 (2017)CrossRef Xiao, J., Zhang, W., Liu, L., Zhang, L., Zhang, C.: Tribological behavior of copper-molybdenum disulfide composites. Wear 384–385, 61–71 (2017)CrossRef
23.
Zurück zum Zitat BARIN: Thermochemical Data of Pure Substances, Nai-liang, C.H.E.N.G., et al. transl. Beijing: Science Press. (2003) BARIN: Thermochemical Data of Pure Substances, Nai-liang, C.H.E.N.G., et al. transl. Beijing: Science Press. (2003)
24.
Zurück zum Zitat Liang, Y., Che, Y., Liu, X.: Thermodynamic data manual of inorganic. Northeast University Press, Boston (1993) Liang, Y., Che, Y., Liu, X.: Thermodynamic data manual of inorganic. Northeast University Press, Boston (1993)
25.
Zurück zum Zitat Su, Y., Zhang, Y., Song, J., Hu, L.: Tribological behavior and lubrication mechanism of self-lubricating ceramic/metal composites: the effect of matrix type on the friction and wear properties. Wear. 372–373, 130–138 (2017)CrossRef Su, Y., Zhang, Y., Song, J., Hu, L.: Tribological behavior and lubrication mechanism of self-lubricating ceramic/metal composites: the effect of matrix type on the friction and wear properties. Wear. 372–373, 130–138 (2017)CrossRef
26.
Zurück zum Zitat Lin, C.B., Chang, Z., Tung, Y.H., Ko, Y.: Manufacturing and tribological properties of copper matrix/carbon nanotubes composites. Wear. 270, 382–394 (2011)CrossRef Lin, C.B., Chang, Z., Tung, Y.H., Ko, Y.: Manufacturing and tribological properties of copper matrix/carbon nanotubes composites. Wear. 270, 382–394 (2011)CrossRef
27.
Zurück zum Zitat Ted Guo, M.L., Tsao, C.Y.A.: Tribological behavior of aluminum/SiC/nickel-coated graphite hybrid composites. Mater. Sci. Eng. A 333, 134–145 (2002)CrossRef Ted Guo, M.L., Tsao, C.Y.A.: Tribological behavior of aluminum/SiC/nickel-coated graphite hybrid composites. Mater. Sci. Eng. A 333, 134–145 (2002)CrossRef
28.
Zurück zum Zitat Chandrakanth, R.G., Rajkumar, K., Aravindan, S.: Fabrication of copper-TiC-graphite hybrid metal matrix composites through microwave processing. Int. J. Adv. Manuf. Technol. 48, 645–653 (2010)CrossRef Chandrakanth, R.G., Rajkumar, K., Aravindan, S.: Fabrication of copper-TiC-graphite hybrid metal matrix composites through microwave processing. Int. J. Adv. Manuf. Technol. 48, 645–653 (2010)CrossRef
29.
Zurück zum Zitat Xiao, Y., Zhang, Z., Yao, P., Fan, K., Zhou, H., Gong, T., Zhao, L., Deng, M.: Mechanical and tribological behaviors of copper metal matrix composites for brake pads used in high-speed trains. Tribol. Int. 119, 585–592 (2018)CrossRef Xiao, Y., Zhang, Z., Yao, P., Fan, K., Zhou, H., Gong, T., Zhao, L., Deng, M.: Mechanical and tribological behaviors of copper metal matrix composites for brake pads used in high-speed trains. Tribol. Int. 119, 585–592 (2018)CrossRef
30.
Zurück zum Zitat Kotnarowski, A.: Selective transfer phenomenon in copper-steel tribological systems. Solid State Phenom. 147–149, 558–563 (2009)CrossRef Kotnarowski, A.: Selective transfer phenomenon in copper-steel tribological systems. Solid State Phenom. 147–149, 558–563 (2009)CrossRef
31.
Zurück zum Zitat Ejima, T., Saitoh, K., Shinke, N., Taruma, M., Hirai, Y.: Atomic-level analysis of copper sulfide (Cu2S): crystal structure and sliding characteristics. Technology Reports of Kansai University. 54, 23–33(2012) Ejima, T., Saitoh, K., Shinke, N., Taruma, M., Hirai, Y.: Atomic-level analysis of copper sulfide (Cu2S): crystal structure and sliding characteristics. Technology Reports of Kansai University. 54, 23–33(2012)
32.
Zurück zum Zitat Varenberg, M., Ryk, G., Yakhnis, A., Kligerman, Y., Kondekar, N., McDowell, M.T.: Mechano-chemical surface modification with Cu2S: inducing superior lubricity. Tribol. Lett. 64, 28 (2016)CrossRef Varenberg, M., Ryk, G., Yakhnis, A., Kligerman, Y., Kondekar, N., McDowell, M.T.: Mechano-chemical surface modification with Cu2S: inducing superior lubricity. Tribol. Lett. 64, 28 (2016)CrossRef
33.
Zurück zum Zitat Bowden, F.P., Tabor, D.: The friction and lubrication of solids I: Oxford: Clarendon Press (1950) Bowden, F.P., Tabor, D.: The friction and lubrication of solids I: Oxford: Clarendon Press (1950)
34.
Zurück zum Zitat Zhang, J.X.L., Zhou, K.-C., Wang, X.P.: Microscratch behavior of copper–graphite composites. Tribol. Int. 57, 38–45 (2013)CrossRef Zhang, J.X.L., Zhou, K.-C., Wang, X.P.: Microscratch behavior of copper–graphite composites. Tribol. Int. 57, 38–45 (2013)CrossRef
35.
Zurück zum Zitat Futami, T., Ohira, M., Muto, H., Sakai, M.: Contact/scratch-induced surface deformation and damage of copper–graphite particulate composites. Carbon. 47, 2742–2751 (2009)CrossRef Futami, T., Ohira, M., Muto, H., Sakai, M.: Contact/scratch-induced surface deformation and damage of copper–graphite particulate composites. Carbon. 47, 2742–2751 (2009)CrossRef
36.
Zurück zum Zitat Equey, S., Houriet, A., Mischler, S.: Wear and frictional mechanisms of copper-based bearing alloys. Wear. 273, 9–16 (2011)CrossRef Equey, S., Houriet, A., Mischler, S.: Wear and frictional mechanisms of copper-based bearing alloys. Wear. 273, 9–16 (2011)CrossRef
37.
Zurück zum Zitat Colaco, R., Vilar, R.: A model for the abrasive wear of metallic matrix particle-reinforced materials. Wear 254, 625–634 (2003)CrossRef Colaco, R., Vilar, R.: A model for the abrasive wear of metallic matrix particle-reinforced materials. Wear 254, 625–634 (2003)CrossRef
38.
Zurück zum Zitat Lafaye, S.: True solution of the ploughing friction coefficient with elastic recovery in the case of a conical tip with a blunted spherical extremity. Wear. 264, 550–554 (2008)CrossRef Lafaye, S.: True solution of the ploughing friction coefficient with elastic recovery in the case of a conical tip with a blunted spherical extremity. Wear. 264, 550–554 (2008)CrossRef
Metadaten
Titel
Effect of Adding Tungsten Disulfide to a Copper Matrix on the Formation of Tribo-Film and on the Tribological Behavior of Copper/Tungsten Disulfide Composites
verfasst von
Lin Zhao
Pingping Yao
Taiming Gong
Haibin Zhou
Minwen Deng
Zonghao Wang
Zhongyi Zhang
Yelong Xiao
Fenghua Luo
Publikationsdatum
01.09.2019
Verlag
Springer US
Erschienen in
Tribology Letters / Ausgabe 3/2019
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-019-1200-9

Weitere Artikel der Ausgabe 3/2019

Tribology Letters 3/2019 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.