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11.05.2018 | Original Paper

Effect of Gold on the Adsorption Properties of Acetaldehyde on Clean and h-BN Covered Rh(111) Surface

verfasst von: Arnold Péter Farkas, Ádám Szitás, Gábor Vári, Richárd Gubó, László Óvári, András Berkó, János Kiss, Zoltán Kónya

Erschienen in: Topics in Catalysis | Ausgabe 12-13/2018

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Abstract

Auger electron spectroscopy, high-resolution electron energy loss spectroscopy and temperature programmed desorption methods have been used in order to investigate the adsorption properties and reactions of acetaldehyde on gold decorated rhodium and BN/Rh(111) surfaces. Scanning tunneling microscopy and X-ray photoelectron spectroscopy measurements were carried out to characterize the gold nanoparticles on clean and hexagonal boron nitride (h-BN) covered Rh(111). The adsorption of acetaldehyde was not completely hindered by gold atoms; however, depending on the structure of the outermost bimetallic layer (surface alloy) the dissociation of the parent molecule was suppressed, namely the production of carbon monoxide was inhibited by the gold domains. Our measurements with acetaldehyde on Au/h-BN/Rh(111) confirmed the observation that the lack of suitable adsorption sites eliminates the formation of CO. Nevertheless, increased coverage of gold enhanced the amount of adsorbed aldehyde at low temperature. We may predict that the low reactivity of acetaldehyde on Au/h-BN/Rh(111) significantly determine the ethanol decomposition mechanism on this surface.

Vorheriger Artikel Remarkable NanoConfinement Effects on Equilibrated Reactions: Statistical-Mechanics Modeling Focused on Ir Dimerization Beneath Surface Sites in Pd–Ir Nanoparticles

Nächster Artikel Surface Spectroscopic Analysis of TiO2 and ZnO Nanoparticles Doped with Noble Metals

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Davis JL, Barteau MA (1987) Decarbonylation and decomposition pathways of alcohol’s on Pd(111). Surf Sci 187:387–406. https://doi.org/10.1016/S0039-6028(87)80064-X CrossRef

Davis JL, Barteau MA (1988) The influence of oxygen on the selectivity of alcohol conversion on the Pd(111) surface. Surf Sci 197:123–152. https://doi.org/10.1016/0039-6028(88)90577-8 CrossRef

McCabe RW, Dimaggio CL, Madix RJ (1985) Adsorption and reactions of acetaldehyde on Pt(S)-[6(111) X (100)]. J Phys Chem 89:854–861. https://doi.org/10.1021/j100251a028 CrossRef

Mavrikakis M, Barteau MA (1998) Oxygenate reaction pathways on transition metal surfaces. J Mol Catal A Chem 131:135–147. https://doi.org/10.1016/S1381-1169(97)00261-6 CrossRef

Raskó J, Kiss J (2005) Adsorption and surface reactions of acetaldehyde on alumina-supported noble metal catalysts. Catal Lett 101:71–77. https://doi.org/10.1007/s10562-004-3752-y CrossRef

Raskó J, Kecskés T, Kiss J (2005) FT-IR and mass spectrometric studies on the interaction of acetaldehyde with TiO₂-supported noble metal catalysts. Appl Catal A Gen 287:244–251. https://doi.org/10.1016/j.apcata.2005.04.004 CrossRef

Roberts JM (1990) The atmospheric chemistry of organic nitrates. Atmos Environ 24A:243–287. https://doi.org/10.1016/0960-1686(90)90108-Y CrossRef

Altshuller AP (1993) Production of aldehydes as primary emissions and from secondary atmospheric reactions of alkenes and alkanes during the night and early morning hours. Atmos Environ Part A Gen Top 27:21–32. https://doi.org/10.1016/0960-1686(93)90067-9 CrossRef

Yee A, Morrison SJ, Idriss H (2000) Reactions of ethanol over M/CeO₂ catalysts. Evidence of carbon-carbon bond dissociation at low temperatures over Rh/CeO₂. Catal Today 63:327–335. https://doi.org/10.1016/S0920-5861(00)00476-4 CrossRef

10.

Mattos LV, Jacobs G, Davis BH, Noronha FB (2012) Production of hydrogen from ethanol: review of reaction mechanism and catalyst deactivation. Chem Rev 112:4094–4123CrossRefPubMed

11.

Ferencz Z, Erdohelyi A, Baán K et al (2014) Effects of support and Rh additive on co-based catalysts in the ethanol steam reforming reaction. ACS Catal 4:1205–1218. https://doi.org/10.1021/cs500045z CrossRef

12.

De Lima AFF, Colman RC, Zotin FMZ, Appel LG (2010) Acetaldehyde behavior over platinum based catalyst in hydrogen stream generated by ethanol reforming. Int J Hydrog Energy 35:13200–13205. https://doi.org/10.1016/j.ijhydene.2010.09.030 CrossRef

13.

Varga E, Ferencz Z, Oszkó A et al (2015) Oxidation states of active catalytic centers in ethanol steam reforming reaction on ceria based Rh promoted Co catalysts: an XPS study. J Mol Catal A Chem 397:127–133. https://doi.org/10.1016/j.molcata.2014.11.010 CrossRef

14.

Henderson MA, Zhou Y, White JM (1989) Polymerization and decomposition of acetaldehyde on Ru(001). J Am Chem Soc 111:1185–1193. https://doi.org/10.1021/ja00186a004 CrossRef

15.

Davis JL, Barteau MA (1989) Polymerization and decarbonylation reactions of aldehydes on the Pd(111) surface. J Am Chem Soc 111:1782–1792. https://doi.org/10.1021/ja00187a035 CrossRef

16.

Houtman CJ, Barteau MA (1991) Divergent pathways of acetaldehyde and ethanol decarbonylation on the Rh(111) surface. J Catal 130:528–546. https://doi.org/10.1016/0021-9517(91)90133-O CrossRef

17.

Kovács I, Farkas AP, Szitás Á et al (2017) Adsorption, polymerization and decomposition of acetaldehyde on clean and carbon-covered Rh(111) surfaces. Surf Sci. https://doi.org/10.1016/j.susc.2017.05.016 CrossRef

18.

Karatok M, Vovk EI, Shah AA et al (2016) Erratum: acetaldehyde partial oxidation on the Au(111) model catalyst surface: C-C bond activation and formation of methyl acetate as an oxidative coupling product (Surface Science (2015) 641 (289-293) DOI: 10.1016/j.susc.2015.04.005). Surf Sci 649:152. https://doi.org/10.1016/j.susc.2016.01.011.CrossRef

19.

Meng Q, Shen Y, Xu J et al (2012) Mechanistic understanding of hydrogenation of acetaldehyde on Au(111): a DFT investigation. Surf Sci 606:1608–1617. https://doi.org/10.1016/j.susc.2012.06.014 CrossRef

20.

Pan M, Flaherty DW, Mullins CB (2011) Low-temperature hydrogenation of acetaldehyde to ethanol on H-precovered Au(111). J Phys Chem Lett 2:1363–1367. https://doi.org/10.1021/jz200577n CrossRef

21.

Valden M (1998) Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties. Science 281:1647–1650. https://doi.org/10.1126/science.281.5383.1647 CrossRefPubMed

22.

Haruta M (1997) Size- and support-dependency in the catalysis of gold. Catal Today 36:153–166. https://doi.org/10.1016/S0920-5861(96)00208-8 CrossRef

23.

Haruta M, Daté M (2001) Advances in the catalysis of Au nanoparticles. Appl Catal A Gen 222:427–437. https://doi.org/10.1016/S0926-860X(01)00847-X CrossRef

24.

Dumbuya K, Cabailh G, Lazzari R et al (2012) Evidence for an active oxygen species on Au/TiO₂(110) model catalysts during investigation with in situ X-ray photoelectron spectroscopy. Catal Today 181:20–25. https://doi.org/10.1016/j.cattod.2011.09.035 CrossRef

25.

Liu L, Zhou Z, Guo Q et al (2011) The 2-D growth of gold on single-layer graphene/Ru(0001): enhancement of CO adsorption. Surf Sci 605:L47–L50. https://doi.org/10.1016/j.susc.2011.04.040 CrossRef

26.

Zhang Y, Zhang Y, Ma D et al (2013) Mn atomic layers under inert covers of graphene and hexagonal boron nitride prepared on Rh(111). Nano Res 6:887–896. https://doi.org/10.1007/s12274-013-0365-z CrossRef

27.

Gotterbarm K, Spath F, Bauer U et al (2015) Reactivity of graphene-supported Pt nanocluster arrays. ACS Catal 5:2397–2403. https://doi.org/10.1021/acscatal.5b00245 CrossRef

28.

Corso M (2004) Boron nitride nanomesh. Science 303:217–220. https://doi.org/10.1126/science.1091979 CrossRefPubMed

29.

Ng ML, Preobrajenski AB, Vinogradov AS, Mårtensson N (2008) Formation and temperature evolution of Au nanoparticles supported on the h-BN nanomesh. Surf Sci 602:1250–1255. https://doi.org/10.1016/j.susc.2008.01.028 CrossRef

30.

Koch HP, Laskowski R, Blaha P, Schwarz K (2011) Adsorption of gold atoms on the h-BN/Rh(111) nanomesh. Phys Rev B 84:1–7. https://doi.org/10.1103/PhysRevB.84.245410 CrossRef

31.

Koch HP, Laskowski R, Blaha P, Schwarz K (2012) Adsorption of small gold clusters on the h-BN/Rh(111) nanomesh. Phys Rev B 86:1–7. https://doi.org/10.1103/PhysRevB.86.155404 CrossRef

32.

Patterson MC, Habenicht BF, Kurtz RL et al (2014) Formation and stability of dense arrays of Au nanoclusters on hexagonal boron nitride/Rh(111). Phys Rev B 89:1–10. https://doi.org/10.1103/PhysRevB.89.205423 CrossRef

33.

Farkas AP, Török P, Solymosi F et al (2015) Investigation of the adsorption properties of borazine and characterisation of boron nitride on Rh(111) by electron spectroscopic methods. Appl Surf Sci 354:367–372. https://doi.org/10.1016/j.apsusc.2015.05.060 CrossRef

34.

McKee WC, Patterson MC, Huang D et al (2016) CO adsorption on Au nanoparticles grown on hexagonal boron nitride/Rh(111). J Phys Chem C 120:10909–10918. https://doi.org/10.1021/acs.jpcc.6b01645 CrossRef

35.

Gubó R, Vári G, Kiss J et al (2018) Tailoring the hexagonal boron nitride nanomesh on Rh(111) by gold. Phys Chem Chem Phys. https://doi.org/10.1039/C8CP00790J CrossRefPubMed

36.

Gazsi A, Koós A, Bánsági T, Solymosi F (2011) Adsorption and decomposition of ethanol on supported Au catalysts. Catal Today 160:70–78. https://doi.org/10.1016/j.cattod.2010.05.007 CrossRef

37.

Óvári L, Berkó A, Vári G et al (2016) The growth and thermal properties of Au deposited on Rh(111): formation of an ordered surface alloy. Phys Chem Chem Phys 18:25230–25240. https://doi.org/10.1039/C6CP02128J CrossRefPubMed

38.

Furukawa J, Saegusa T, Fujii H et al (1960) Crystalline polyaldehydes. Die Makromol Chem 37:149–152. https://doi.org/10.1002/macp.1960.020370114 CrossRef

39.

Zhao H, Kim J, Koel BE (2003) Adsorption and reaction of acetaldehyde on Pt(1 1 1) and Sn/Pt(1 1 1) surface alloys. Surf Sci 538:147–159. https://doi.org/10.1016/S0039-6028(03)00602-2 CrossRef

40.

Guan Y, Hensen EJM (2013) Selective oxidation of ethanol to acetaldehyde by Au-Ir catalysts. J Catal 305:135–145. https://doi.org/10.1016/j.jcat.2013.04.023 CrossRef

41.

Henderson MA, Radloff PL, White JM, Mims CA (1988) Surface chemistry of ketene on Ru(001). 1. Surface structures. J Phys Chem 92:11–41. https://doi.org/10.1021/j100325a025 CrossRef

42.

Ćavar E, Westerström R, Mikkelsen A et al (2008) A single h-BN layer on Pt(1 1 1). Surf Sci 602:1722–1726. https://doi.org/10.1016/j.susc.2008.03.008 CrossRef

43.

Frank M, Wolter K, Magg N et al (2001) Phonons of clean and metal-modified oxide films: an infrared and HREELS study. Surf Sci 492:270–284. https://doi.org/10.1016/S0039-6028(01)01475-3 CrossRef

44.

Rokuta E, Hasegawa Y, Suzuki K et al (1997) Phonon dispersion of an epitaxial monolayer film of hexagonal boron nitride on Ni(111). Phys Rev Lett 79:4609–4612. https://doi.org/10.1103/PhysRevLett.79.4609 CrossRef

45.

Berner S, Corso M, Widmer R et al (2007) Boron nitride nanomesh: functionality from a corrugated monolayer. Angew Chem Int Ed 46:5115–5119. https://doi.org/10.1002/anie.200700234 CrossRef

46.

Bus E, Miller JT, Van Bokhoven JA (2005) Hydrogen chemisorption on Al₂O₃-supported gold catalysts. J Phys Chem B 109:14581–14587. https://doi.org/10.1021/jp051660z CrossRefPubMed

47.

Mavrikakis M, Stoltze P, Nørskov JK (2000) Making gold less noble. Catal Lett 64:101–106. https://doi.org/10.1023/A:1019028229377 CrossRef

48.

Yoon B (2005) Charging effects on bonding and catalyzed oxidation of CO on Au₈ clusters on MgO. Science 307:403–407. https://doi.org/10.1126/science.1104168 CrossRefPubMed

49.

Chen M, Cai Y, Yan Z, Goodman DW (2006) On the origin of the unique properties of supported Au nanoparticles. J Am Chem Soc 128:6341–6346. https://doi.org/10.1021/ja0557536 CrossRefPubMed

50.

Sterrer M, Yulikov M, Risse T et al (2006) When the reporter induces the effect: unusual IR spectra of CO on Au 1/MgO(001)/Mo(001). Angew Chem Int Ed 45:2633–2635. https://doi.org/10.1002/anie.200504473 CrossRef

Titel: Effect of Gold on the Adsorption Properties of Acetaldehyde on Clean and h-BN Covered Rh(111) Surface
verfasst von: Arnold Péter Farkas
Ádám Szitás
Gábor Vári
Richárd Gubó
László Óvári
András Berkó
János Kiss
Zoltán Kónya
Publikationsdatum: 11.05.2018
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 12-13/2018
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-018-0979-1

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