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Journal of Materials Science
Erschienen in: Journal of Materials Science 24/2014

01.12.2014 | Original Paper

Effect of iron on the solubility of hydrogen in tantalum

verfasst von: Manju Taxak, Sanjay Kumar, Smita Sheelvantra, Nagaiyar Krishnamurthy

Erschienen in: Journal of Materials Science | Ausgabe 24/2014

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Abstract

Pressure-composition-isotherms for Ta–Fe–H systems have been investigated in the temperature range 673–873 K. Tantalum–iron alloys (Ta–xFe, x = 0, 1.6 and 3.2 atom  % Fe) were prepared by arc melting using high purity elements. The equilibrium solid solubility of hydrogen in the alloys decreases with an increase of iron content. Thermodynamic parameters of the solution process—the Gibb’s free energy, enthalpy, and entropy, for each of the solutions have been calculated. The relative partial molar enthalpy becomes less negative with increase in iron content, whereas the entropy values are nearly constant for these alloys. The solubility changes were explained on the basis of change in lattice strain energy of tantalum due to iron addition.
Vorheriger Artikel Temperature-dependent material properties of the components of magnetorheological fluids
Nächster Artikel Mechanochemically assisted synthesis of pristine Ca(II)Sn(IV)-layered double hydroxides and their amino acid intercalated nanocomposites

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Metadaten
Titel
Effect of iron on the solubility of hydrogen in tantalum
verfasst von
Manju Taxak
Sanjay Kumar
Smita Sheelvantra
Nagaiyar Krishnamurthy
Publikationsdatum
01.12.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 24/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8557-9

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