Skip to main content
Erschienen in: Journal of Nanoparticle Research 12/2012

01.12.2012 | Research Paper

Effect of the polymeric matrix on the structural and magnetic properties of hematite/polymer composites

verfasst von: Angela Longo, Xiao Lei Wang, Antonio Ruotolo, Antonio Peluso, Gianfranco Carotenuto, Rolf Lortz

Erschienen in: Journal of Nanoparticle Research | Ausgabe 12/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The magnetic properties of hematite (α-Fe2O3) nanoparticles synthesized by in situ thermal decomposition of an iron-mercaptide precursor in polymeric matrices are studied. In Polystyrene, nanoparticles with average size ~20 nm can be produced that show ferromagnetic behavior with no Morin transition for temperatures as low as 10 K. Poly(9-vinylcarbazole)-based nanocomposites, produced by the same synthesis process, show a different magnetic behavior with a clear Morin transition. The effect of the polymeric matrix on the structural and magnetic properties of dispersed hematite nanoparticles is discussed. It is concluded that, in heavily viscous medium, the ability to control the particle growth and distribution is compromised.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Aharoni A (1996) Introduction to the Theory of Ferromagnetism. Oxford Science Publications, New york Aharoni A (1996) Introduction to the Theory of Ferromagnetism. Oxford Science Publications, New york
Zurück zum Zitat Amin N, Arajs S (1987) Morin temperature of annealed submicronic α-F2O3 particles. Phys Rev B 35:4810–4811CrossRef Amin N, Arajs S (1987) Morin temperature of annealed submicronic α-F2O3 particles. Phys Rev B 35:4810–4811CrossRef
Zurück zum Zitat Bercoff PG, Bertorello HR (2010) Magnetic properties of hematite with large coercivity. Appl Phys A 100:1019–1027CrossRef Bercoff PG, Bertorello HR (2010) Magnetic properties of hematite with large coercivity. Appl Phys A 100:1019–1027CrossRef
Zurück zum Zitat Carotenuto G, Martorana B, Perlo P, Nicolais L (2003) A universal method for the synthesis of metal and metal sulfide clusters embedded in polymer matrices. J Mater Chem 13:2927–2930CrossRef Carotenuto G, Martorana B, Perlo P, Nicolais L (2003) A universal method for the synthesis of metal and metal sulfide clusters embedded in polymer matrices. J Mater Chem 13:2927–2930CrossRef
Zurück zum Zitat Carotenuto G, Nicolais L, Perlo P (2006) Synthesis of polymer-embedded noble metal clusters by thermolysis of mercaptides dissolved in polymers. Polymer Eng & Sci 46:1016–1021CrossRef Carotenuto G, Nicolais L, Perlo P (2006) Synthesis of polymer-embedded noble metal clusters by thermolysis of mercaptides dissolved in polymers. Polymer Eng & Sci 46:1016–1021CrossRef
Zurück zum Zitat Chantrell RW, El-Hilo M, O’Grady K (1991) Spin-glass behavior in a fine particle system. IEEE Trans Mag 27:3570–3578CrossRef Chantrell RW, El-Hilo M, O’Grady K (1991) Spin-glass behavior in a fine particle system. IEEE Trans Mag 27:3570–3578CrossRef
Zurück zum Zitat Comstock RL (1999) Introduction to magnetism and magnetic recording. Wiley, New York Comstock RL (1999) Introduction to magnetism and magnetic recording. Wiley, New York
Zurück zum Zitat Del Bianco L, Fiorani D, Testa AM, Bonetti E, Savini L, Signoretti S (2002) Magnetothermal behavior of a nanoscale Fe/Fe oxide granular system. Phys Rev B 66:1–11 Del Bianco L, Fiorani D, Testa AM, Bonetti E, Savini L, Signoretti S (2002) Magnetothermal behavior of a nanoscale Fe/Fe oxide granular system. Phys Rev B 66:1–11
Zurück zum Zitat Dorman JL, Fiorani D, El Yamani M (1987) Field dependence of the blocking temperature in the superparamagnetic model: H2/3 coincidence. Phys Lett A 120:95–99CrossRef Dorman JL, Fiorani D, El Yamani M (1987) Field dependence of the blocking temperature in the superparamagnetic model: H2/3 coincidence. Phys Lett A 120:95–99CrossRef
Zurück zum Zitat Dormann JL, Fiorani D, Tronc E (1997) Magnetic relaxation in fine-particle systems. Adv Chem Phys 98:283–494CrossRef Dormann JL, Fiorani D, Tronc E (1997) Magnetic relaxation in fine-particle systems. Adv Chem Phys 98:283–494CrossRef
Zurück zum Zitat Goya GF, Berquò TS, Fonseca FC, Morales MP (2003) Static and dynamic magnetic properties of spherical magnetite nanoparticles. J Appl Phys 94:3520–3528CrossRef Goya GF, Berquò TS, Fonseca FC, Morales MP (2003) Static and dynamic magnetic properties of spherical magnetite nanoparticles. J Appl Phys 94:3520–3528CrossRef
Zurück zum Zitat Kechrakos D, Trohidou KN (2002) Magnetic properties of self-assembled interacting nanoparticles. Appl Phys Lett 81:4574–4576CrossRef Kechrakos D, Trohidou KN (2002) Magnetic properties of self-assembled interacting nanoparticles. Appl Phys Lett 81:4574–4576CrossRef
Zurück zum Zitat Matsumura Y, Maeda H (1986) A new concept for macromolecular therapeutics in cancer chemotherapy: mechanism of tumoritropic accumulation of proteins and the antitumor agent smancs. Cancer Res 46:6387–6392 Matsumura Y, Maeda H (1986) A new concept for macromolecular therapeutics in cancer chemotherapy: mechanism of tumoritropic accumulation of proteins and the antitumor agent smancs. Cancer Res 46:6387–6392
Zurück zum Zitat Morin FJ (1950) Magnetic susceptibility of αFe2O3 and αFe2O3 with added titanium. Phys Rev 78:819–820CrossRef Morin FJ (1950) Magnetic susceptibility of αFe2O3 and αFe2O3 with added titanium. Phys Rev 78:819–820CrossRef
Zurück zum Zitat Morrish A (1994) Canted antiferromagnetism: hematite. World Scientific, Singapore Morrish A (1994) Canted antiferromagnetism: hematite. World Scientific, Singapore
Zurück zum Zitat Mørup S, Tronc E (1994) Superparamagnetic relaxation of weakly interacting particles. Phys Rev Lett 72:3278–3281CrossRef Mørup S, Tronc E (1994) Superparamagnetic relaxation of weakly interacting particles. Phys Rev Lett 72:3278–3281CrossRef
Zurück zum Zitat Mørup S, Bodker F, Hendriksen PV, Linderoth S (1995) Spin-glass-like ordering of the magnetic moments of interacting nanosized maghemite particles. Phys Rev B 52:287–295CrossRef Mørup S, Bodker F, Hendriksen PV, Linderoth S (1995) Spin-glass-like ordering of the magnetic moments of interacting nanosized maghemite particles. Phys Rev B 52:287–295CrossRef
Zurück zum Zitat Nicolais L, Carotenuto G (2005) Metal–polymer nanocomposite. Wiley, New York Nicolais L, Carotenuto G (2005) Metal–polymer nanocomposite. Wiley, New York
Zurück zum Zitat Nicolais L, Carotenuto G (2008) Synthesis of polymer-embedded metal, semimetal, or sulfide clusters by thermolysis of mercaptide molecules dissolved in polymers. Recent Pat Mat Sci 1:1–11CrossRef Nicolais L, Carotenuto G (2008) Synthesis of polymer-embedded metal, semimetal, or sulfide clusters by thermolysis of mercaptide molecules dissolved in polymers. Recent Pat Mat Sci 1:1–11CrossRef
Zurück zum Zitat Peddis D, Cannas C, Musinu A, Piccaluga G (2008a) Coexistence of superparamagnetism and spin-glass like magnetic ordering phenomena in a CoFe2O4–SiO2 nanocomposite. J Phys Chem C 112:5141–5147CrossRef Peddis D, Cannas C, Musinu A, Piccaluga G (2008a) Coexistence of superparamagnetism and spin-glass like magnetic ordering phenomena in a CoFe2O4–SiO2 nanocomposite. J Phys Chem C 112:5141–5147CrossRef
Zurück zum Zitat Peddis D, Mansilla MV, Mørup S, Cannas C, Musinu A, Piccaluga G, D’Orazio F, Lucari F, Fiorani D (2008b) Spin-canting and magnetic anisotropy in ultrasmall CoFe2O4 nanoparticles. J Phys Chem B 112:8507–8513CrossRef Peddis D, Mansilla MV, Mørup S, Cannas C, Musinu A, Piccaluga G, D’Orazio F, Lucari F, Fiorani D (2008b) Spin-canting and magnetic anisotropy in ultrasmall CoFe2O4 nanoparticles. J Phys Chem B 112:8507–8513CrossRef
Zurück zum Zitat Pejaković DA, Kitamura C, Miller JS, Epstein AJ (2002) Photoinduced magnetization in the organic-based magnet Mn(TCNE)x · y(CH2Cl2). Phys Rev Lett 88:1–4 Pejaković DA, Kitamura C, Miller JS, Epstein AJ (2002) Photoinduced magnetization in the organic-based magnet Mn(TCNE)x · y(CH2Cl2). Phys Rev Lett 88:1–4
Zurück zum Zitat Peluso A, Pagliarulo V, Carotenuto G, Pepe GP, Davino D, Visone C, Longo A, Capezzuto F (2009) Synthesis and characterization of polymer embedded iron oxide nanocomposites. Microw Opt Tech Lett 51:2774–2777CrossRef Peluso A, Pagliarulo V, Carotenuto G, Pepe GP, Davino D, Visone C, Longo A, Capezzuto F (2009) Synthesis and characterization of polymer embedded iron oxide nanocomposites. Microw Opt Tech Lett 51:2774–2777CrossRef
Zurück zum Zitat Rath C, Sahu KK, Kulkarni SD, Anand S, Date SK, Das RP, Mishra NC (1999) Microstructure-dependent coercivity in monodispersed hematite particles. Appl Phys Lett 75:4171–4173CrossRef Rath C, Sahu KK, Kulkarni SD, Anand S, Date SK, Das RP, Mishra NC (1999) Microstructure-dependent coercivity in monodispersed hematite particles. Appl Phys Lett 75:4171–4173CrossRef
Zurück zum Zitat Rosi NL, Giljohann DA, Thaxton CS, Lytton-Jean AKR, Han MS, Mirkin CA (2006) Oligonucleotide-modified gold nanoparticles for intracellular gene regulation. Science 312:1027–1030CrossRef Rosi NL, Giljohann DA, Thaxton CS, Lytton-Jean AKR, Han MS, Mirkin CA (2006) Oligonucleotide-modified gold nanoparticles for intracellular gene regulation. Science 312:1027–1030CrossRef
Zurück zum Zitat Sun C, Lee JSH, Zhang M (2008) Magnetic nanoparticles in MR imaging and drug delivery. Adv Drug Delivery Rev 60:1252–1265CrossRef Sun C, Lee JSH, Zhang M (2008) Magnetic nanoparticles in MR imaging and drug delivery. Adv Drug Delivery Rev 60:1252–1265CrossRef
Zurück zum Zitat Weller D, Moser A (1999) Thermal effect limits in ultrahigh-density magnetic recording. IEEE Trans Magn 35:4423–4439CrossRef Weller D, Moser A (1999) Thermal effect limits in ultrahigh-density magnetic recording. IEEE Trans Magn 35:4423–4439CrossRef
Zurück zum Zitat Willard MA, Kurihara LK, Carpenter EE, Calvin S, Harris VG (2004) Chemically prepared magnetic nanoparticles. Int Mat Rev 49:125–170CrossRef Willard MA, Kurihara LK, Carpenter EE, Calvin S, Harris VG (2004) Chemically prepared magnetic nanoparticles. Int Mat Rev 49:125–170CrossRef
Zurück zum Zitat Zaidi NA, Giblin SR, Terry I, Monkman AP (2004) Room temperature magnetic order in an organic magnet derived from polyaniline. Polymer 45:5683–5689CrossRef Zaidi NA, Giblin SR, Terry I, Monkman AP (2004) Room temperature magnetic order in an organic magnet derived from polyaniline. Polymer 45:5683–5689CrossRef
Metadaten
Titel
Effect of the polymeric matrix on the structural and magnetic properties of hematite/polymer composites
verfasst von
Angela Longo
Xiao Lei Wang
Antonio Ruotolo
Antonio Peluso
Gianfranco Carotenuto
Rolf Lortz
Publikationsdatum
01.12.2012
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 12/2012
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-012-1314-6

Weitere Artikel der Ausgabe 12/2012

Journal of Nanoparticle Research 12/2012 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.