2007 | OriginalPaper | Buchkapitel
Effect of the Reactant Crystal Structure on the Composition of the Primary Decomposition Products
Erschienen in: Thermal Decomposition of Solids and Melts
Verlag: Springer Netherlands
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As can be seen from Tables 9.2 and 9.3, for many reactants the composition of the primary gaseous products (oxygen and nitrogen) differs from the equilibrium composition. These products are released, completely or partially, in the form of free atoms. This phenomenon is of remarkable theoretical and practical interest. Some general features of this phenomenon, related to the decompositions of oxides, nitrides and, to some extent, of phosphorus, arsenic, and antimony, are described below.