Anzeige
Erschienen in:
2007 | OriginalPaper | Buchkapitel
Thermochemical Analysis of the Composition of the Primary Products
Erschienen in: Thermal Decomposition of Solids and Melts
Verlag: Springer Netherlands
Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.
Wählen Sie Textabschnitte aus um mit Künstlicher Intelligenz passenden Patente zu finden. powered by
Markieren Sie Textabschnitte, um KI-gestützt weitere passende Inhalte zu finden. powered by
Starting in 1981 [1], L’vov and his colleagues tried to interpret the experimental parameter
E
in the Arrhenius equation as the molar enthalpy, Δr
H◦T /ν
, of the desired decomposition reaction. However, it did not affect the traditional interpretation of the parameter
E
. One of the potential reasons for mistrust of this approach could be due to the unreliability of
E
values measured by the traditional Arrhenius plot method. As an illustration, a comment by Vyazovkin [2] can be quoted: “The comparison of theoretical values of the activation energy with the experimental ones may itself present a considerable challenge as the reported values tend to be widely different.”