Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 5/2017

26.09.2016 | Original Paper

Effects of incorporating acrylolsobutyl polyhedral oligomeric silsesquioxane on the properties of P(N-isopropylacrylamide-co-poly(ethylene glycol) diacrylate) hybrid hydrogels

verfasst von: Xiaoman Hou, Wei Yang, Aiming Li, Jiazi Hou, Chunling Zhang

Erschienen in: Polymer Bulletin | Ausgabe 5/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A novel system for enhancing the properties of P(N-isopropylacrylamide-co-poly(ethylene glycol)diacrylate) (P(NIPAM-co-PEGDA)) temperature-sensitive hybrid hydrogels by incorporating acrylolsobutyl polyhedral oligomeric silsesquioxane (MAPOSS) was developed in this study. Inorganic/organic hybrid P(NIPAM-co-PEGDA) hydrogels based on MAPOSS were synthesized via free radical polymerization. Environmental scanning electron microscopy images showed that hydrogels with different feed ratios exhibited significant changes in the porous structure and average pore size. The heterogeneous and irregular network was caused mainly by MAPOSS aggregation. The rigid cage-like nanostructure of MAPOSS had dual opposite effects on polymer thermal properties; this effect was proven through differential scanning calorimetry and thermogravimetric analysis. The mechanical behaviors of the swollen hydrogels investigated through compression test showed that MAPOSS incorporation enhanced the yield strength. Swelling, deswelling and reswelling behaviors of hydrogels with different feed ratios were systematically examined and compared. The increase in MAPOSS provided the hydrogels with improved deswelling rate because of its cage-like nanostructure and hydrophobicity.
Vorheriger Artikel Preparation and properties of plasticized chitosan/starch cast films using AlCl3·6H2O aqueous solution as the solvent
Nächster Artikel Main characteristic of N-bromo poly(styrene-co-divinylbenzene) sulphonamide acid: a cation exchanger and redox polymer

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Lin XK, Chen L, Zhao YP, Dong ZZ (2010) Synthesis and characterization of thermoresponsive shape-memory poly(stearyl acrylate-co-acrylamide) hydrogels. J Mater Sci 45:2703–2707CrossRef
2.
Prettyman JB, Eddington DT (2011) Leveraging stimuli responsive hydrogels for on/off control of mixing. Sensor Actuat B-Chem 157:722–726CrossRef
3.
Wang Y, Yuan ZC, Chen DJ (2011) Thermo- and pH-sensitive behavior of hydrogels based on oligo (ethylene glycol) methacrylates and acrylic acid. J Mater Sci 47:1280–1288CrossRef
4.
ter Schiphorst J, Coleman S, Stumpel JE, Ben Azouz A, Diamond D, Schenning APHJ (2015) Molecular design of light-responsive hydrogels, for in situ generation of fast and reversible valves for microfluidic applications. Chem Mater 27:5925–5931CrossRef
5.
Mori A, Kaito T, Furukawa H (2015) Reconsideration on structural anisotropy of silica hydrogels prepared in magnetic field. Colloid Surf A 482:464–467CrossRef
6.
Zhang N, Liu M, Shen Y, Chen J, Dai L, Gao C (2010) Preparation, properties, and drug release of thermo- and pH-sensitive poly((2-dimethylamino)ethyl methacrylate)/poly (N, diethylacrylamide) semi-IPN hydrogels. J Mater Sci 46:1523–1534CrossRef
7.
Aroguz AZ, Baysal K, Adiguzel Z, Baysal BM (2014) Alginate/polyoxyethylene and alginate/gelatin hydrogels: preparation, characterization, and application in tissue engineering. Appl Biochem Biotechnol 173:433–448CrossRef
8.
Ramanujan RV, Ang KL, Venkatraman S (2006) Magnet–PNIPA hydrogels for bioengineering applications. J Mater Sci 44:1381–1387CrossRef
9.
Qu R, Shen L, Qu A, Wang R, An Y, Shi L (2015) Artificial peroxidase/oxidase multiple enzyme system based on supramolecular hydrogel and its application as a biocatalyst for cascade reactions. ACS Appl Mater Interfaces 7:16694–16705CrossRef
10.
Huang R, Kostanski LK, Filipe CDM, Ghosh R (2009) Environment-responsive hydrogel-based ultrafiltration membranes for protein bioseparation. J Membr Sci 336:42–49CrossRef
11.
Tang Q, Wu J, Lin J, Li Q, Fan S (2008) Two-step synthesis of polyacrylamide/polyacrylate interpenetrating network hydrogels and its swelling/deswelling properties. J Mater Sci 43:5884–5890CrossRef
12.
Jankaew R, Rodkate N, Lamlertthon S, Rutnakornpituk B, Wichai U, Ross G, Rutnakornpituk M (2015) “Smart” carboxymethylchitosan hydrogels crosslinked with poly(isopropylacrylamide) and poly(acrylic acid) for controlled drug release. Polym Test 42:26–36CrossRef
13.
Wang Y, Huang CJ, Jonas U, Wei T, Dostalek J, Knoll W (2010) Biosensor based on hydrogel optical waveguide spectroscopy. Biosens Bioelectron 25:1663–1668CrossRef
14.
Cheng C, Xia D, Zhang X, Chen L, Zhang Q (2015) Biocompatible poly(isopropylacrylamide)-g-carboxymethyl chitosan hydrogels as carriers for sustained release of cisplatin. J Mater Sci 50:4914–4925CrossRef
15.
Palomino K, Suarez-Meraz KA, Serrano-Medina A, Olivas A, Samano EC, Cornejo-Bravo JM (2015) Microstructured poly(isopropylacrylamide) hydrogels with fast temperature response for pulsatile drug delivery. J Polym Res 22:199CrossRef
16.
Chen J, Pei Y, Yang L-M, Shi L-L, Luo H-J (2005) Synthesis and properties of poly(isopropylacrylamide-co-acrylamide) hydrogels. Macromol Symp 225:103–112CrossRef
17.
Sa-Lima H, Tuzlakoglu K, Mano JF, Reis RL (2011) Thermoresponsive poly(isopropylacrylamide)-g-methylcellulose hydrogel as a three-dimensional extracellular matrix for cartilage-engineered applications. J Biomed Mater Res Part A 98:596–603CrossRef
18.
Hu J, Kurokawa T, Nakajima T, Sun TL, Suekama T, Wu ZL, Liang SM, Gong JP (2012) High fracture efficiency and stress concentration phenomenon for microgel-reinforced hydrogels based on double-network principle. Macromolecules 45:9445–9451CrossRef
19.
Argun A, Can V, Altun U, Okay O (2014) Nonionic double and triple network hydrogels of high mechanical strength. Macromolecules 47:6430–6440CrossRef
20.
Miyata T, Asami N, Uragami T (2009) Structural design of stimuli-responsive bioconjugated hydrogels that respond to a target antigen. J Polym Sci Pol Phys 47:2144–2157CrossRef
21.
Xia M, Wu W, Liu F, Theato P, Zhu M (2015) Swelling behavior of thermosensitive nanocomposite hydrogels composed of oligo(ethylene glycol) methacrylates and clay. Eur Polym J 69:472–482CrossRef
22.
Li X, Kong X, Zhang J, Wang Y, Wang Y, Shi S, Guo G, Luo F, Zhao X, Wei Y, Qian Z (2011) A novel composite hydrogel based on chitosan and inorganic phosphate for local drug delivery of camptothecin nanocolloids. J Pharm Sci 100:232–241CrossRef
23.
Haraguchi K, H-j Li, H-y Ren, Zhu M (2010) Modification of nancomposite gels by irreversible rearrangement of polymer/clay network structure through drying. Macromolecules 43:9848–9853CrossRef
24.
Li Y, Zhang W, Hsieh I et al (2011) Breaking symmetry toward nonspherical Janus particles based on polyhedral oligomeric silsesquioxanes: molecular design, “click” synthesis, and hierarchical structure. J Am Chem Soc 133:10712–10715CrossRef
25.
Zhang W, Müller A (2013) Architecture, self-assembly and properties of well-defined hybrid polymers based on polyhedral oligomeric silsequioxane (POSS). Prog Polym Sci 38:1121–1162CrossRef
26.
Zeng K, Liu Y, Zheng S (2008) Poly(ethylene imine) hybrids containing polyhedral oligomeric silsesquioxanes: preparation, structure and properties. Eur Polym J 44:3946–3956CrossRef
27.
Prządka D, Andrzejewska E, Marcinkowska A (2015) Multimethacryloxy-POSS as a crosslinker for hydrogel materials. Eur Polym J 72:34–49CrossRef
28.
Blanco I, Bottino FA (2015) The influence of the nature of POSSs cage’s periphery on the thermal stability of a series of new bridged POSS/PS nanocomposites. Polym Degrad Stabil 121:180–186CrossRef
29.
Wang L, Zeng K, Zheng S (2011) Hepta(3,3,3-trifluoropropyl) polyhedral oligomeric silsesquioxane-capped poly(isopropylacrylamide) telechelics: synthesis and behavior of physical hydrogels. ACS Appl Mater Inter 3:898–909CrossRef
30.
Dutta S, Dhara D (2015) Effect of preparation temperature on salt-induced deswelling and pattern formation in poly(isopropylacrylamide) hydrogels. Polymer 76:62–69CrossRef
31.
Zhang X, Li C et al (2014) A novel temperature and pH dual-responsive hybrid hydrogel with polyhedral oligomeric silsesquioxane as crosslinker: synthesis, characterization and drug release properties. Polym Int 63:2030–2041CrossRef
32.
Pan M, Zhang C, Zhai X, Qu L, Mu J (2014) Effect of hexaphenoxycyclotriphosphazene combined with octapropylglycidylether polyhedral oligomeric silsesquioxane on thermal stability and flame retardancy of epoxy resin. High Perform Polym 26:744–752CrossRef
33.
Chen Y, Xiong Y et al (2013) Synthesis and characterization of polyhedral oligomeric silsesquioxane hybrid co-crosslinked poly(N-isopropylacrylamide-co-dimethylaminoethyl methacrylate) hydrogels. J Polym Ssi Pol Phys 51:1494–1504CrossRef
34.
Yang J, Dong X, Gao Y, Zhang W (2015) One-step synthesis of methacrylated POSS cross-linked poly(N-isopropylacrylamide) hydrogels by γ-irradiation. Mater Lett 157:81–84CrossRef
Metadaten
Titel
Effects of incorporating acrylolsobutyl polyhedral oligomeric silsesquioxane on the properties of P(N-isopropylacrylamide-co-poly(ethylene glycol) diacrylate) hybrid hydrogels
verfasst von
Xiaoman Hou
Wei Yang
Aiming Li
Jiazi Hou
Chunling Zhang
Publikationsdatum
26.09.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 5/2017
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1807-z

Weitere Artikel der Ausgabe 5/2017

Polymer Bulletin 5/2017 Zur Ausgabe

Original Paper

The effects of carbon nanotubes, blend composition and glycidyl methacrylate-grafted polypropylene compatibilizer on the morphology, mechanical and electrical properties of polypropylene-polyamide 6 blends

Original Paper

Mechanical, physical and dynamical properties of glass fiber and waste fishnet hybrid composites

Original Paper

Glucose oxidase immobilization onto Au/poly[anthranilic acid-co-3-carboxy-N-(2-thenylidene)aniline]/PVAc electrospun nanofibers

Original Paper

Microwave-assisted synthesis of poly(glycidyl azide-co-tetrahydrofuran)

Original Paper

Preparation of the chitosan/polyacrylonitrile semi-IPN hydrogel via glutaraldehyde vapors for the removal of Rhodamine B dye

Original Paper

Characterization of a triblock copolymer, poly(ethylene glycol)-polylactide-poly(ethylene glycol), with different structures for anticancer drug delivery applications

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise