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Journal of Nanoparticle Research

Erschienen in:

01.01.2016 | Research Paper

Effects of porous structure of carbon hosts on preparation and electrochemical performance of sulfur/carbon composites for lithium–sulfur batteries

verfasst von: Tuliang Wang, Pengcheng Shi, Jingjuan Chen, Sheng Cheng, Hongfa Xiang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 1/2016

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Abstract

Three kinds of carbon hosts, Ketjenblack (KB, high surface area and porosity), black pearls 2000 (BP2000, high surface area and moderate porosity), and ordered mesoporous carbon nanospheres (OMCN, low surface area and porosity), have been used as conductive hosts in the sulfur/carbon (S/C) composite cathodes for lithium–sulfur (Li–S) batteries. To correlate the carbon properties (surface area and pore volume), the electrochemical performances of S/C composite cathodes with the same sulfur content (60 wt%) have been investigated in detail. S/KB and S/BP2000 composites with high surface porosity can provide more reactive sites for sulfur, which can result in increasing the utilization rate of sulfur, reducing the polarization, and improving the high-rate capability. Large pore volume can effectively capture the polysulfide species and improve easy passages for ion transport, which can promote long-term cycling stability and reduce the resistance of Li–S batteries.

Vorheriger Artikel Highly dispersive nano-TiO2 in situ growing on functional graphene with high photocatalytic activity

Nächster Artikel Synthesis of TiO2 nanoparticles containing Fe, Si, and V using multiple diffusion flames and catalytic oxidation capability of carbon-coated nanoparticles

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Titel: Effects of porous structure of carbon hosts on preparation and electrochemical performance of sulfur/carbon composites for lithium–sulfur batteries
verfasst von: Tuliang Wang
Pengcheng Shi
Jingjuan Chen
Sheng Cheng
Hongfa Xiang
Publikationsdatum: 01.01.2016
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 1/2016
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-016-3331-3

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