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Erschienen in: Journal of Sol-Gel Science and Technology 3/2015

01.09.2015 | Original Paper

Effects of seed layer and crystallization process on crystal orientation and properties of NKBT thin films

verfasst von: Wenhan Cui, Xiaohui Wang, Longtu Li

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2015

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Abstract

Lead-free (Na0.85K0.15)0.5Bi0.5TiO3 (NKBT) piezoelectric thin films were fabricated via an aqueous sol–gel method on Pt(111)/Ti/SiO2/Si substrates. The thin films, with and without Pb0.8La0.1Ca0.1Ti0.975O3 seed layer, were obtained by single-crystallization and multiple-crystallization processes. The NKBT thin films derived by multiple-crystallization process exhibited better single perovskite structure, and the films with PLCT seed layers were well crystallized with high (100) orientation. The effects that seed layer and different crystallization processes have on crystal orientation and electrical properties can be attributed to extrinsic and intrinsic contributions, and their different mechanism and ranges of improvement in the dielectricity and piezoelectricity are observed and discussed. The NKBT thin films that prepared by multiple crystallization with PLCT seed layer had the best electric property with ε r of 598, tanδ of 0.08, and d 33 of 136 pm/V.

Graphical Abstract

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Literatur
1.
Zurück zum Zitat Haertling GH (1999) Ferroelectric ceramics history and technology. J Am Ceram Soc 82:797–818CrossRef Haertling GH (1999) Ferroelectric ceramics history and technology. J Am Ceram Soc 82:797–818CrossRef
2.
Zurück zum Zitat Luo L, Zhu H, Zhao C, Wang H, Luo H (2007) Cylinder-shaped ultrasonic motors 4.8 mm in diameter using electroactive piezoelectric materials. Appl Phys Lett 90(5):052904CrossRef Luo L, Zhu H, Zhao C, Wang H, Luo H (2007) Cylinder-shaped ultrasonic motors 4.8 mm in diameter using electroactive piezoelectric materials. Appl Phys Lett 90(5):052904CrossRef
3.
Zurück zum Zitat Herabut ASA (1997) Processing and electromechanical properties of (Bi0.5Na0.5)((1 − 1.5x))LaxTiO3 ceramics. J Am Ceram Soc 80:2954–2958CrossRef Herabut ASA (1997) Processing and electromechanical properties of (Bi0.5Na0.5)((1 − 1.5x))LaxTiO3 ceramics. J Am Ceram Soc 80:2954–2958CrossRef
4.
Zurück zum Zitat Chiang Y-M, Farrey GW, Soukhojak AN (1998) Lead-free high-strain single-crystal piezoelectrics in the alkaline–bismuth–titanate perovskite family. Appl Phys Lett 73(25):3683CrossRef Chiang Y-M, Farrey GW, Soukhojak AN (1998) Lead-free high-strain single-crystal piezoelectrics in the alkaline–bismuth–titanate perovskite family. Appl Phys Lett 73(25):3683CrossRef
5.
Zurück zum Zitat Jones PATGO (2000) The tetragonal phase of Na0.5Bi0.5TiO3—a new variant of the perovskite structure. Acta Crystallogr B 56:426–430CrossRef Jones PATGO (2000) The tetragonal phase of Na0.5Bi0.5TiO3—a new variant of the perovskite structure. Acta Crystallogr B 56:426–430CrossRef
6.
Zurück zum Zitat Jones PATGO (2002) Investigation of the structure and phase transitions in the novel A-site substituted distorted perovskite compound Na(0.5)Bi(0.5)TiO(3). Acta Crystallogr 58:168–178CrossRef Jones PATGO (2002) Investigation of the structure and phase transitions in the novel A-site substituted distorted perovskite compound Na(0.5)Bi(0.5)TiO(3). Acta Crystallogr 58:168–178CrossRef
7.
Zurück zum Zitat Zhou ZH, Xue JM, Li WZ, Wang J, Zhu H, Miao JM (2004) Ferroelectric and electrical behavior of (Na[sub 0.5]Bi[sub 0.5])TiO[sub 3] thin films. Appl Phys Lett 85(5):804CrossRef Zhou ZH, Xue JM, Li WZ, Wang J, Zhu H, Miao JM (2004) Ferroelectric and electrical behavior of (Na[sub 0.5]Bi[sub 0.5])TiO[sub 3] thin films. Appl Phys Lett 85(5):804CrossRef
8.
Zurück zum Zitat Ge W, Liu H, Zhao X, Li X, Pan X, Lin D, Xu H, Jiang X, Luo H (2009) Orientation dependence of electrical properties of 0.96Na0.5Bi0.5TiO3–0.04BaTiO3 lead-free piezoelectric single crystal. Appl Phys A 95(3):761–767CrossRef Ge W, Liu H, Zhao X, Li X, Pan X, Lin D, Xu H, Jiang X, Luo H (2009) Orientation dependence of electrical properties of 0.96Na0.5Bi0.5TiO3–0.04BaTiO3 lead-free piezoelectric single crystal. Appl Phys A 95(3):761–767CrossRef
9.
Zurück zum Zitat Fang X, Shen B, Zhai J, Yao X (2010) Preparation, dielectric and ferroelectric properties of (Na0.5Bi0.5)0.94Ba0.06TiO3 thin films by a sol–gel process. J Sol-Gel Sci Technol 58(1):1–5CrossRef Fang X, Shen B, Zhai J, Yao X (2010) Preparation, dielectric and ferroelectric properties of (Na0.5Bi0.5)0.94Ba0.06TiO3 thin films by a sol–gel process. J Sol-Gel Sci Technol 58(1):1–5CrossRef
10.
Zurück zum Zitat Zhang H, Jiang S, Xiao J, Kajiyoshi K (2010) Piezoelectric and dielectric aging of Bi[sub 0.5](Na[sub 0.82]K[sub 0.18])[sub 0.5]TiO[sub 3] lead-free ferroelectric thick films. J Appl Phys 107(12):124118CrossRef Zhang H, Jiang S, Xiao J, Kajiyoshi K (2010) Piezoelectric and dielectric aging of Bi[sub 0.5](Na[sub 0.82]K[sub 0.18])[sub 0.5]TiO[sub 3] lead-free ferroelectric thick films. J Appl Phys 107(12):124118CrossRef
11.
Zurück zum Zitat Yu T, Kwok KW, Chan HLW (2007) The synthesis of lead-free ferroelectric Bi0.5Na0.5TiO3–Bi0.5K0.5TiO3 thin films by sol–gel method. Mater Lett 61(10):2117–2120CrossRef Yu T, Kwok KW, Chan HLW (2007) The synthesis of lead-free ferroelectric Bi0.5Na0.5TiO3–Bi0.5K0.5TiO3 thin films by sol–gel method. Mater Lett 61(10):2117–2120CrossRef
12.
Zurück zum Zitat Wu Y, Wang X, Li L (2011) Effect of Sc doping on the structure and electrical properties of (Na0.85K0.15)0.5Bi0.5TiO3 thin films prepared by sol–gel processing. J Am Ceram Soc 94(8):2518–2522CrossRef Wu Y, Wang X, Li L (2011) Effect of Sc doping on the structure and electrical properties of (Na0.85K0.15)0.5Bi0.5TiO3 thin films prepared by sol–gel processing. J Am Ceram Soc 94(8):2518–2522CrossRef
13.
Zurück zum Zitat Alkoy EM, Alkoy S, Shiosaki T (2007) The effect of crystallographic orientation and solution aging on the electrical properties of sol–gel derived Pb(Zr0.45Ti0.55)O3 thin films. Ceram Int 33(8):1455–1462CrossRef Alkoy EM, Alkoy S, Shiosaki T (2007) The effect of crystallographic orientation and solution aging on the electrical properties of sol–gel derived Pb(Zr0.45Ti0.55)O3 thin films. Ceram Int 33(8):1455–1462CrossRef
14.
Zurück zum Zitat Guo Y, Akai D, Sawada K, Ishida M, Gu M (2008) Dielectric and tunable properties of highly (110)-oriented (Ba0.65Sr0.35)TiO3 thin films deposited on Pt/LaNiO3/SiO2/Si substrates. J Sol-Gel Sci Technol 49(1):66–70CrossRef Guo Y, Akai D, Sawada K, Ishida M, Gu M (2008) Dielectric and tunable properties of highly (110)-oriented (Ba0.65Sr0.35)TiO3 thin films deposited on Pt/LaNiO3/SiO2/Si substrates. J Sol-Gel Sci Technol 49(1):66–70CrossRef
15.
Zurück zum Zitat Wu Y, Wang X, Zhong C, Li L (2011) Effect of anneal conditions on electrical properties of Mn-doped (Na0.85K0.15)0.5Bi0.5TiO3 thin films prepared by sol–gel method. J Am Ceram Soc 94(6):1843–1849CrossRef Wu Y, Wang X, Zhong C, Li L (2011) Effect of anneal conditions on electrical properties of Mn-doped (Na0.85K0.15)0.5Bi0.5TiO3 thin films prepared by sol–gel method. J Am Ceram Soc 94(6):1843–1849CrossRef
16.
Zurück zum Zitat Chi QG, Li WL, Feng B, Liu CQ, Fei WD (2009) Low-temperature crystallization and orientation evolution of Nb-doped Pb(Zr, Ti)O3 thin films using a Pb0.8Ca0.1La0.1Ti0.975O3 seed layer. Scr Mater 60(4):218–220CrossRef Chi QG, Li WL, Feng B, Liu CQ, Fei WD (2009) Low-temperature crystallization and orientation evolution of Nb-doped Pb(Zr, Ti)O3 thin films using a Pb0.8Ca0.1La0.1Ti0.975O3 seed layer. Scr Mater 60(4):218–220CrossRef
17.
Zurück zum Zitat Wang S-F, Tu C-S, Chang T-L, Chen P-Y, Chen C-S, Hugo Schmidt V, Anthoniappen J (2014) Structural stability and depolarization of manganese-doped (Bi0.5Na0.5)1 − xBaxTiO3 relaxor ferroelectrics. J Appl Phys 116(15):154101CrossRef Wang S-F, Tu C-S, Chang T-L, Chen P-Y, Chen C-S, Hugo Schmidt V, Anthoniappen J (2014) Structural stability and depolarization of manganese-doped (Bi0.5Na0.5)1 − xBaxTiO3 relaxor ferroelectrics. J Appl Phys 116(15):154101CrossRef
18.
Zurück zum Zitat Chi QG, Yang FY, Zhang CH, Chen CT, Zhu HF, Wang X, Lei QQ (2013) Influence of seed layer on crystal orientation and electrical properties of (Na0.85K0.15)0.5Bi0.5TiO3 thin films prepared by a sol–gel process. Ceram Int 39(8):9273–9276CrossRef Chi QG, Yang FY, Zhang CH, Chen CT, Zhu HF, Wang X, Lei QQ (2013) Influence of seed layer on crystal orientation and electrical properties of (Na0.85K0.15)0.5Bi0.5TiO3 thin films prepared by a sol–gel process. Ceram Int 39(8):9273–9276CrossRef
20.
Zurück zum Zitat Taylor DDDV (1997) Evidence of domain wall contribution to the dielectric permittivity in PZT thin films at sub-switching fields. J Appl Phys 82:1973–1975CrossRef Taylor DDDV (1997) Evidence of domain wall contribution to the dielectric permittivity in PZT thin films at sub-switching fields. J Appl Phys 82:1973–1975CrossRef
21.
Zurück zum Zitat Chen L, Nagarajan V, Ramesh R, Roytburd AL (2003) Nonlinear electric field dependence of piezoresponse in epitaxial ferroelectric lead zirconate titanate thin films. J Appl Phys 94(8):5147CrossRef Chen L, Nagarajan V, Ramesh R, Roytburd AL (2003) Nonlinear electric field dependence of piezoresponse in epitaxial ferroelectric lead zirconate titanate thin films. J Appl Phys 94(8):5147CrossRef
22.
Zurück zum Zitat Zhu X, Zhu T, Liu Z, Ming N (2001) Microstructures of grain boundaries in (001)-oriented strontium bismuth tantalate thin films grown by pulsed laser deposition. Appl Phys A Mater Sci Process 72(4):503–507CrossRef Zhu X, Zhu T, Liu Z, Ming N (2001) Microstructures of grain boundaries in (001)-oriented strontium bismuth tantalate thin films grown by pulsed laser deposition. Appl Phys A Mater Sci Process 72(4):503–507CrossRef
23.
Zurück zum Zitat Ruangchalermwong C, Li J-F, Zhu Z-X, Lai F, Muensit S (2009) Enhanced ferro- and piezoelectric properties in (100)-textured Nb-doped Pb(ZrxTi1 − x)O3 films with compositions at morphotropic phase boundary. Thin Solid Films 517(24):6599–6604CrossRef Ruangchalermwong C, Li J-F, Zhu Z-X, Lai F, Muensit S (2009) Enhanced ferro- and piezoelectric properties in (100)-textured Nb-doped Pb(ZrxTi1 − x)O3 films with compositions at morphotropic phase boundary. Thin Solid Films 517(24):6599–6604CrossRef
Metadaten
Titel
Effects of seed layer and crystallization process on crystal orientation and properties of NKBT thin films
verfasst von
Wenhan Cui
Xiaohui Wang
Longtu Li
Publikationsdatum
01.09.2015
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2015
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-015-3742-0

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