nach oben

Colloid and Polymer Science

Erschienen in:

29.01.2018 | Original Contribution

Effects of structure on the properties of low-molecular-weight superplasticizer using phosphonate as the adsorption group

verfasst von: Jianfeng Ma, Tao Wang, Shuai Qi, Shimin Fan, Shuzhen Zheng, Qianping Ran

Erschienen in: Colloid and Polymer Science | Ausgabe 3/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Two types of low-molecular-weight superplasticizers using phosphonate as the adsorption group were synthesized in one pot by the Moedrizer-Irani procedure from the single amino-terminated or the double amino-terminated polyethers. Results of cement paste test indicated that single bis(phosphonic acid)amino-terminated polymers (polymer of type A) exhibited good water-reducing ability, while double bis(phosphonic acid)amino-terminated polymers (polymers of type B) showed good fluidity-maintaining abilities and had a longer setting time. Adsorption isotherms indicated that polyether chains of polymer of type B might curl up on the surface of cement particle or form a chelated structure with Ca²⁺ in aqueous phase, which restricted the effect of steric hindrance. And the adsorption layer thickness of polymer M1 was calculated as 0.46 nm through X-ray photoelectron spectroscopy test, while which of polymer M3 was 0.89 nm. Furthermore, cement hydration test and SEM were also used to reveal the effects of structure on the properties of the two different kinds of polymers. These useful information provide the potential to explore new kind of superplasticizers in the future.

Vorheriger Artikel Application of conducting micelles self-assembled from commercial poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) and chitosan for electrochemical biosensor

Nächster Artikel Salt effect on hydrophobically modified polyacrylamide-containing crude oil emulsions: stability and rheology study

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Ramachandran VS (1992) Superplasticizers. Prog Cem Concr 1:345–375

Hommer H (2009) Interaction of polycarboxylate ether with silica fume. J Eur Ceram Soc 29(10):1847–1853. https://doi.org/10.1016/j.jeurceramsoc.2008.12.017 CrossRef

Li Y, Zhang Y, Zheng J, Guo H, Yang C, Li Z, Lu M (2014) Dispersion and rheological properties of concentrated kaolin suspensions with polycarboxylate copolymers bearing comb-like side chains. J Eur CeramSoc 34(1):137–146. https://doi.org/10.1016/j.jeurceramsoc.2013.07.009 CrossRef

Dalas F, Nonat A, Pourchet S, Mosquet M, Rinaldi D, Sabio S (2015) Tailoring the anionic function and the side chains of comb-like superplasticizers to improve their adsorption. Cem Concr Res 67:21–30. https://doi.org/10.1016/j.cemconres.2014.07.024 CrossRef

Rixom MR, Mailvaganam NP (1986) Chemical admixtures for concrete2nd edn. E and F. N, Spon

Yamada K, Takahashi T, Hanehara S, Matsuhisa M (2000) Effects of the chemical structure on the properties of polycarboxylate-type superplasticizer. Cem Concr Res 30(2):197–207. https://doi.org/10.1016/S0008-8846(99)00230-6 CrossRef

Liu X, Wang Z, Zhu J, Zheng Y, Cui S, Lan M, Li H (2014) Synthesis, characterization and performance of a polycarboxylate superplasticizer with amide structure. Colloids Surf A Physicochem Eng Asp 448:119–129. https://doi.org/10.1016/j.colsurfa.2014.02.022 CrossRef

Ran QP, Wang XM, Jiang J, Yang Y Synthesis of block polycarboxylate copolymer and its application in a cement system. Adv Cem Res.2016, 28(3):202–208.https://doi.org/10.1680/jadcr.15.00055

Kong FR, Pan LS, Wang CM, Zhang DL, Xu N (2016) Effects of polycarboxylate superplasticizers with different molecular structure on the hydration behavior of cement paste. Constr Build Mater 105:545–553. https://doi.org/10.1016/j.conbuildmat.2015.12.178 CrossRef

10.

Plank J, Pöllmann K, Zouaoui N, Andres PR, Schaefer C (2008) Synthesis and performance of methacrylic ester based polycarboxylate superplasticizers possessing hydroxy terminated poly(ethylene glycol) side chains. Cem Concr Res 38(10):1210–1216. https://doi.org/10.1016/j.cemconres.2008.01.007 CrossRef

11.

Yamada K, Takahashi T, Hanehara S, Matsuhisa M (2000) Effects of chemical struc-ture on the properties of polycarboxylate-type superplasticizer. Cem ConcrRes 30(2):197–207. https://doi.org/10.1016/S0008-8846(99)00230-6 CrossRef

12.

Shu X, Ran QP, Liu JP, Zhao HX, Zhang Q, Wang XM, Yang Y, Liu JZ (2016) Tailoring the solution conformation of polycarboxylate superplasticizer toward the improvement of dispersing performance in cement paste. Constr Build Mater 116:289–298. https://doi.org/10.1016/j.conbuildmat.2016.04.127 CrossRef

13.

Habbaba A, Plank J (2012) Surface chemistry of ground granulated blast furnace slagin cement pore solution and its impact on the effectiveness of polycarboxylate superplasticizers. J Am Ceram Soc 95(2):768–775. https://doi.org/10.1111/j.1551-2916.2011.04968.x CrossRef

14.

Bonen D, Sakar SL (1995) The superplasticizer adsorption capacity of cement paste, pore solution composition, and parameters affecting flow loss. Cem Concr Res 25(7):1423–1434. https://doi.org/10.1016/0008-8846(95)00137-2 CrossRef

15.

Kukhar, VP, Hudson HR. (2000) Aminophosphonic and aminophosphinic acids: chemistry and biological activity. Eds.; Wiley: Chichester

16.

Poupot M, Griffe L, Marchand P et al (2006) Design of phosphorylated dendritic architectures to promote human monocyte activation. FASEB J 13:2339–2351CrossRef

17.

Matty JM, Tomson MB (1988) Effect of multiple precipitation inhibitors on calcium carbonate nucleation. Appl Geochem 3:549–556CrossRef

18.

Fang JL, Li Y, Ye XR et al (1993) Passive films and corrosion protection due to phosphonic acid inhibitors. Corrosion (Houston, TX, U. S.) 49:266–271CrossRef

19.

Qi L, Sehgal A, Castaing JC et al (2008) Redispersible hybrid nanopowders: cerium oxide nanoparticle complexes with phosphonated-PEG oligomers. ACS Nano 2:879–888CrossRef

20.

Basly B, Felder-Flesch D, Perriat P et al (2010) Dendronized iron oxide nanoparticles as contrast agents for MRI. ChemCommun(Cambridge) 46:985–987

21.

Kueny-Stotz M, Mamlouk-Chaouachi H, Felder-Flesch D (2011) Synthesis of patent blue derivatized hydrophilic dendrons dedicated to sentinel node detection in breast cancer. Tetrahedron Lett 52(22):2906–2909. https://doi.org/10.1016/j.tetlet.2011.03.144 CrossRef

22.

Lamanna G, Kueny-Stotz M, Mamlouk-Chaouachi H et al (2011) Dendronized iron oxide nanoparticles for multimodal imaging. Biomaterials 32:8562–8573CrossRef

23.

Boyer C, Bulmus V, Priyanto P et al (2009) The stabilization and bio-functionalization of iron oxide nanoparticles using heterotelechelic polymers. J MaterChem 19:111–123

24.

Daou TJ, Pourroy G, Greneche JM et al (2009) Water soluble dendronized iron oxide nanoparticles. Dalton Trans:4442–4449

25.

Moedritzer K, Irani R (1966) The direct synthesis of α-aminomethylphosphonic acids. Mannich-type reactions with orthophosphorous acid. J Org Chem 31(5):1603–1607. https://doi.org/10.1021/jo01343a067 CrossRef

26.

Turrin CO, Hameau A, Caminade AM (2012) Application of the Kabachnik–Fields and Moedritzer–Irani procedures for the preparation of Bis(phosphonomethyl)amino-and bis[(dimethoxyphosphoryl) -methyl]amino-terminated poly(ethylene glycol). Synthesis 44(11):1628–1630. https://doi.org/10.1055/s-0031-1290985 CrossRef

27.

Fields EK (1952) The synthesis of esters of substituted amino phosphonic acids. J Am Chem Soc 74(6):1528–1531. https://doi.org/10.1021/ja01126a054 CrossRef

28.

Ran QP, Ma JF, Wang T, Zhao HX, Song FY, Fan SM, Yang Y, Lyu ZF, Liu JP (2016) Synthesis, characterization and dispersion properties of a series of bi(phosphonic acid)amino-terminated polymers. Colloid. Polym. Sci 294:189–198CrossRef

29.

Ran QP, Song FY, Wang T, Fan SM, Ma JF, Yang Y, Liu JP Effect of the different hydrophobic groups of polycarboxylate superplasticizers on the properties in cement mortars. Polym Compos.2017,38(9):1783–1791. https://doi.org/10.1002/pc.23748

30.

Flatt RJ, Houst YF (2001) A simplified view on chemical effects perturbing the action of superplasticizers. Cem Concr Res 31(8):1169–1176. https://doi.org/10.1016/S0008-8846(01)00534-8 CrossRef

31.

Uchikawa H, Hanehara S, Sawaki D (1997) The role of steric repulsive force in the dispersion of cement particles in fresh paste prepared with organic admixture. Cem Concr Res 27:37–50CrossRef

32.

Zingg A, Winnefeld F, Holzer L, Pakusch J, Becker S, Figi R, Gauckler L (2009) Interaction of polycarboxylate-based superplasticizers with cements containing different C(3)A amounts. Cem Concr Compos 31(3):153–162. https://doi.org/10.1016/j.cemconcomp.2009.01.005 CrossRef

33.

Flatt RJ, Schober I, Raphael E, Plassard C, Lesniewska E (2009) Conformation of adsorbed comb copolymer dispersants. Langmuir 25(2):845–855. https://doi.org/10.1021/la801410e CrossRef

34.

Zhang Y, Kong X (2015) Correlations of the dispersing capability of NSF and PCE types of superplasticizer and their impacts on cement hydration with the adsorption in fresh cement pastes. Cem Concr Res 69:1–9. https://doi.org/10.1016/j.cemconres.2014.11.009 CrossRef

Titel: Effects of structure on the properties of low-molecular-weight superplasticizer using phosphonate as the adsorption group
verfasst von: Jianfeng Ma
Tao Wang
Shuai Qi
Shimin Fan
Shuzhen Zheng
Qianping Ran
Publikationsdatum: 29.01.2018
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 3/2018
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-018-4272-4

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 3/2018

Soft multiple emulsions demonstrating reversible freeze-thawing capacity and enhanced skin permeability of diclofenac sodium

Nitrogen-containing porous carbon materials by twin polymerization

Thermo- and pH-responsive phase separation of N-isopropylacrylamide with 4-vinylpyridine random copolymer in aqueous solutions

Novel humic acid-based carbon materials: adsorption thermodynamics and kinetics for cadmium(II) ions

Temperature and pH dual responsive 2-(dimethylamino)ethanethiol modified starch derivatives via a thiol-yne reaction for drug delivery

Tuning the solubilization behavior of the CTAB/C9OH-C12OH micellar system with quaternary ammonium salts

Premium Partner

Marktübersichten