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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 9/2017

01.08.2017 | ORIGINAL PAPER

Effects of surface functionalized partially reduced graphene oxide and different compatibilizers on the properties and structure of PP/EPR nanocomposites

verfasst von: Rachida Doufnoune, Nacerddine Haddaoui

Erschienen in: Journal of Polymer Research | Ausgabe 9/2017

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Abstract

In this study polypropylene/ethylene-propylene rubber (PP/EPR) and different amounts of partially reduced graphene oxide (prGO) and its derivatives were investigated. The nanocomposites were also compatibilized with EPR containing diethyl maleate (DEM), glycidyl methacrylate (GMA) and maleic anhydride (MAH) functionality as a means of controlling their ultimate mechanical behaviour and their structural morphology. Mechanical tests show that the addition of pristine prGO to PP/EPR blend promotes tensile strength and Young’s modulus, while reducing elongation at break and impact strength. A significant improvement of these properties was achieved by the presence of functionalized prGO and EPR-g-DEM. TGA analysis showed that the nanocomposites exhibit a higher thermal stability than that of the matrix alone. XRD analysis revealed that the polymer chains have been successfully intercalated into prGO layers. SEM has been used to verify the dispersion of the prGO particles in the matrix and to reveal the developed morphology of PP/EPR, in the presence of compatibilizers and functionalized prGO.
Vorheriger Artikel Preparation, morphology and sonication time dependence of silver nanoparticles in amphiphilic block copolymers of PEO with polystyrene or PMMA
Nächster Artikel Effect of synthesis variables on viscoelastic properties of elastomers filled with carbonyl iron powder

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Literatur
1.
An X, Simmons T, Shah R, Wolfe C, Lewis Kim M, Washington M, Nayak Saroj K, Talapatra S, Kar S (2010) Stable aqueous dispersions of noncovalently functionalized graphene from graphite and their multifunctional high-performance applications. Nano Lett 10(1):4295–4301CrossRef
2.
Stoller MD, Park S, Zhu Y, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8(10):3498–3502CrossRef
3.
Zaman I, Kuan HC, Dai J, Kawashima N, Michelmore A, Dong S, Luong L, Ma J (2012) From nanotubes and silicate layers to graphene platelets for polymer nanocomposites. Nano 4(15):4578–4586
4.
Steurer P, Wissert R, Thamann R, Mülhaupt R (2009) Functionalized graphenes and thermoplastic nanocomposites based upon expanded graphite oxide. Macromol Rapid Commun 30(4–5):316–329CrossRef
5.
Hussain F, Hojjati M, Okamoto M, Gorga RE (2006) Polymer-matrix nanocomposites, processing, Manufacturing and Application: An Overview. J Compos Mater 40(17):1511–1575CrossRef
6.
Bhattacharya M (2016) Polymer nanocomposites - a comparison between carbon nanotubes, graphene and clay as nanofillers. Materials 9(4):262–297CrossRef
7.
Galpaya D, Wang M, Liu M, Motta N, Waclawik E, Ya C (2012) Recent advances in fabrication and characterization of graphene-polymer nanocomposites. Graphene 1:30–49CrossRef
8.
Xu Y, Liu Z, Zhang X, Wang Y, Tian J, Huang Y, Ma Y, Zhang X, Chen Y (2009) A graphene hybrid material covalently functionalized with porphyrin: synthesis and optical limiting property. Adv Mater 21(12):1275–1279CrossRef
9.
Yang H, Li F, Shan C, Han D, Zhang Q, Niu L, Ivaska A (2009) Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement. J Mater Chem 19(26):4632–4638CrossRef
10.
Brodie BC (1859) On the atomic weight of graphite. Philos Trans R Soc 149:249–259CrossRef
11.
Staudenmaier L (1898) Verfahren zur darstellung der graphitsaure. Ber Dtsch Chem Ges 31(2):1481–1487CrossRef
12.
Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Soc 80(6):1339–1339CrossRef
13.
14.
Shahriary L, Athawale AA (2014) Graphene oxide synthesized by using modified hummers approach. Int J Renew Energy Environmental Eng 2(1):58–63
15.
Hontoria-Lucas C, López-Peinado A, López-González J, Rojas-Cervantes M, Martín-Aranda R (1995) Study of oxygen-containing groups in a series of graphite oxides: physical and chemical characterization. Carbon 33(11):1585–1592CrossRef
16.
Lerf A, He HY, Forster M, Klinovski J (1998) Structure of graphite oxide revisited. J Phys Chem B 102(23):4477–4482CrossRef
17.
Kuilla T, Bhadra S, Yao D, Kim NH, Bose S, Lee JH (2010) Recent advances in graphene based polymer composites. Prog Polym Sci 35(11):1350–1375CrossRef
18.
Mo ZL, Xie TT, Zhang JX, Zhao YX, Guo RB (2012) Synthesis and characterization of nanoGs-PPy/epoxy nanocomposites by in situ polymerization. Synth React Inorg, Met-Org, Nano-Met Chem 42(8):1172–1176CrossRef
19.
Bao C, Song L, Xing W, Yuan B, Wilkie CA, Huang J, Guo Y, Hu Y (2012) Preparation of graphene by pressurized oxidation and multiplex reduction and its polymer nanocomposites by masterbatch-based melt blending. J Mater Chem 22(13):6088–6096CrossRef
20.
Zhao X, Zhang Q, Chen D (2010) Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites. Macromolecules 43(5):2357–2363CrossRef
21.
Layek RK, Samanta S, Nandi AK (2012) The physical properties of sulfonated graphene/poly(vinyl alcohol) composites. Carbon 50(3):815–827CrossRef
22.
Jinhong Y, Huang X, Wu C, Jiang P (2011) Permittivity, thermal conductivity and thermal stability of poly(vinylidene fluoride)/graphene nanocomposites. IEEE Trans Dielectr Electr Insul 18(2):478–484CrossRef
23.
Chen Y, Qi Y, Tai Z, Yan X, Zhu F, Xue Q (2012) Preparation, mechanical properties and biocompatibility of graphene oxide/ultrahigh molecular weight polyethylene composites. Eur Polym J 48(6):1026–1033CrossRef
24.
Gonçalves G, Marques Paula AAP, Barros-Timmons A, Bdkin I, Singh Manoj K, Nazanin Emamic N, Grácioa J (2010) Graphene oxide modified with PMMA via ATRP as reinforcement filler. J Mater Chem 20(44):9927–9934CrossRef
25.
Kim H, Miura Y, Macosko CW (2010) Graphene/polyurethane nanocomposites for improved gas barrier and electrical conductivity. Chem Mater 22(11):3441–3450CrossRef
26.
Ren PG, Yan DX, Chen T, Zeng BQ, Li M (2011) Improved properties of highly oriented graphene/polymer nanocomposites. J Appl Polym Sci 121(6):3167–3174CrossRef
27.
Chatterjee S, Wang JW, Kuo WS, Chu BTT (2012) Mechanical reinforcement and thermal conductivity in expanded graphene nanoplatelets reinforced epoxy composites. Chem Phys Lett 531:6–10CrossRef
28.
Potts JR, Lee SH, Alam TM, An J, Stoller MD, Piner RD, Ruoff RS (2011) Thermomechanical properties of chemically modified graphene/poly(methyl methacrylate) composites made by in situ polymerization. Carbon 49:2615–2623CrossRef
29.
Zhang F, Peng X, Yan W, Peng Z, Shen Y (2011) Nonisothermal crystallization kinetics of in situ nylon 6/graphene composites by differential scanning calorimetry. J Polym Sci B Polym Phys 49(49):1381–1388CrossRef
30.
Wang X, Song L, Yang H, Xing W, Lu H (2011) In situ polymerization of graphene nanosheets and polyurethane with enhanced mechanical and thermal properties. J Mater Chem 21:4222–4227CrossRef
31.
Huang YF, Lin CW (2012) Facile synthesis and morphology control of graphene oxide/polyaniline nanocomposites via in-situ polymerization process. Polymer 53(13):2574–2582CrossRef
32.
Lian J, Wang Y, Huang Y, Maa Y, Liua Z, Caib J, Zhang C, Gao H, Chen Y (2009) Electromagnetic interference shielding of graphene/epoxy composites. Carbon 47(3):922–925CrossRef
33.
Kim H, Kobayashi S, Abdurrahim MA, Zhang MJ, Khusainova A, Hillmyer MA, Abdala AA, Macosko CW (2011) Graphene/polyethylene nanocomposites: effect of polyethylene functionalization and blending methods. Polymer 52(8):1837–1846CrossRef
34.
Sánchez-Valdes S, Zapata-Domínguez AG, Martinez-Colunga JG, Mendez-Nonell J, Ramos de Valle LF, Espinoza-Martinez AB, Morales-Cepeda A, Lozano-Ramirez T, Lafleur PG, Ramirez-Vargas E (2016) Influence of functionalized polypropylene on polypropylene/graphene oxide nanocomposite properties. Polym Compos. doi:10.​1002/​pc.​24077
35.
Kornmann X, Linderberg H, Bergund LA (2011) Synthesis of epoxy–clay nanocomposites: influence of the nature of the curing agent on structure. Polymer 42(4):4493–4499
36.
Strumberger N, Gospocic A, Bratulic C (2005) Polymeric materials in automobiles. Promet Traffic Traffico 14(3):149–160
37.
Mehta S, Mirabella FM, Rufener K, Bafna A (2004) Thermoplastic olefin/clay nanocomposites: morphology and mechanical properties. J Appl Polym Sci 92(2):928–936CrossRef
38.
Lim JW, Hassan A, Rahmat AR, Wahit MU (2006) Rubber-toughened polypropylene nanocomposite: effect of polyethylene octene copolymer on mechanical properties and phase morphology. Appl Polym 99(6):3441–3450CrossRef
39.
David IF, Shankland K, McCusker LB, Baerlocher C (2002) Structure determination from powder diffraction data. Oxford University Press Inc, New York,
40.
Friedel RA, Carlson GL (1971) Infrared spectra of ground graphite. J Phys Chem 75(8):1149–1151CrossRef
41.
Matsuo Y, Miyabe T, Fukutsuka T, Sugie Y (2012) Preparation and characterization of alkylamine-intercalated graphite oxide. Carbon 45(5):1005–1012CrossRef
42.
Chernyshova IV, Rao KH, Vidyadhar A (2000) Mechanism of long-chain alkylamines on silicates. A spectroscopic study. 1. Quartz Langmuir 16 (21): 8071–8084
43.
Tong X, Wang H, Wang G, Wan L, Ren Z, Bai J (2011) Controllable synthesis of graphene sheets with different numbers of layers and effect of the number of graphene layers on the specific capacity of anode material in lithium-ion batteries. J Solid State Chem 184(5):982–989CrossRef
44.
Herrera-Alonso M, Abdala AA, McAllister JM, Aksay IA, Prud’homme RK (2007) Intercalation and stitching of graphite oxide with diaminoalkanes. Langmuir 23(21):10644–10649CrossRef
45.
Bellamy LJ (1984) The infrared spectra of complexes molecules. Wiley, New York,
46.
Doufnoune R, Haddaoui N, Riahi F (2006) Elaboration and characterization of an organic/inorganic hybrid material: effect of the interface on the mechanical en thermal behavior of PP/CaCO3 composites. Int J Polym Mater 55(10):815–834CrossRef
47.
Doufnoune R, Haddaoui N, Riahi F (2008) The effects of coupling agents on the mechanical, rheological and thermal properties of calcium carbonate-filled LDPE compatibilized with maleic anhydride-g-LDPE (part II). Int J Polym Mater 57(7):690–708CrossRef
48.
D'Orazio L, Mancarella C, Martuscelli E, Polato F (1991) Polypropylene/ethylene-co-blends influence of molecular structure and composition of EPR on melt rheology, morphology and impact properties of EPR injection molded samples. Polymer 32(7):1186–1194CrossRef
49.
Greco R, Mancarella C, Martuscelli E, Ragosta G, Jinghua Y (1987) Polyolefin blends, 2: effect of EPR composition on structure, morphology and mechanical properties of iPP/EPR alloys. Polymer 28(11):1929–1936CrossRef
50.
Premphet K, Horanont P (2000) Phase structure of ternary polypropylene/elastomer/filler composites: effect of elastomer polarity. Polymer 41(26):9283–9290CrossRef
51.
Premphet K, Horanont P (2000) Phase structure and property relationships in ternary polypropylene/elastomer/filler composites: effect of elastomer polarity. J Appl Polym Sci 76(13):1929–1939CrossRef
52.
Premphet K, Horanont P (1999) Influence of stearic acid treatment of filler particles on the structure and properties of ternary-phase polypropylene composites. J Appl Polym Sci 74(14):3445–3454CrossRef
53.
Frounchi M, Dadbin S, Salehpour Z, Noferesti M (2006) Gas barrier properties of PP/EPDM blend nanocomposites. J Membr Sci 282(1–2):142–148CrossRef
54.
Pukanszky B, Tudos E, Kallo A, Bodor G (1989) Multiple morphology in polypropylene/ethylene-propylene-diene terpolymer blends. Polymer 30(8):1407–1413CrossRef
55.
Zebarjad SM, Bagheri R, Lazzeri A (2001) Hybrid PP–EPR–GF composites, part 1- deformation mechanisms. Plast Rubber Compos 30(8):370–376CrossRef
56.
Mnif N (2008) Elaboration et caractérisation de mélanges complexes à base de polypropylène en vue de son écoconception et de son recyclage dans les véhicules hors d’usage, Ph. D thesis, Institut National des Sciences Appliquées de Lyon, France
57.
Yoo BM, Shin HJ, Yoon HW, Park HB (2014) Graphene and graphene oxide and their uses in barrier polymers. J Appl Polym Sci. doi:10.​1002/​app.​39628
58.
Huang HD, Ren PG, Xu JZ, Xu L, Zhong GJ, Hsiao BS, Li ZM (2014) Improved barrier properties of poly(lactic acid) with randomly dispersed graphene oxide nanosheets. J Membr Sci 464:110–118CrossRef
59.
Nandi D, Talukdar A, Ghosh UC, De A, Bhunia S, Ghosh AK (2012) Reduced graphene oxide/ethylene vinyl acetate co-polymer composite with improved thermal stability and flame retardancy. J Polym Mater 29(4):401–411
60.
Cui Y, Kundalwal SI, Kumar S (2016) Gas barrier performance of graphene/polymer nanocomposites. Carbon 98:313–333CrossRef
61.
Xu WB, Liag G, Wang W, Tang S, He P, Pan WP (2003) PP-PP-g-MAH-Org-MMT nanocomposites. I Intercalation behavior and microstructure. J Appl Polym Sci 88(14):3225–3231CrossRef
62.
Wang Y, Chen FB, Li YC, Wu KC (2004) Melt processing of polypropylene/clay nanocomposites modified with maleated polypropylene compatibilizers. Compos Part B Eng 35(2):111–124CrossRef
Metadaten
Titel
Effects of surface functionalized partially reduced graphene oxide and different compatibilizers on the properties and structure of PP/EPR nanocomposites
verfasst von
Rachida Doufnoune
Nacerddine Haddaoui
Publikationsdatum
01.08.2017
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2017
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-017-1302-8

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