Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 6/2017

03.05.2017 | Original Contribution

Electrically conducting polymeric microspheres comprised of sulfonated polystyrene cores coated with poly(3,4-ethylenedioxythiophene)

verfasst von: Aleksei V. Kubarkov, Olga A. Pyshkina, Evgeny A. Karpushkin, Keith J. Stevenson, Vladimir G. Sergeyev

Erschienen in: Colloid and Polymer Science | Ausgabe 6/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Oxidative chemical polymerization of 3,4-ethylenedioxythiophene was carried with 5.8-μm sulfonated polystyrene latex particles as template. Polymerization led to formation of poly(3,4-ethylenedioxythiophene) distributed over the surface of template particles. Increase in initial monomer concentration resulted in the change of poly(3,4-ethylenedioxythiophene) morphology from isolated clusters to continuous 0.2–0.5-μm-thick surface shells. Structure of poly(3,4-ethylenedioxythiophene) coatings had crucial influence on the surface charge and macroscopic electrical conductivity of composite latex particles.
Vorheriger Artikel Predictions of Takayanagi model for tensile modulus of polymer/CNT nanocomposites by properties of nanoparticles and filler network
Nächster Artikel Facile tailor-made enhancement in proton conductivity of sulfonated poly(ether ether ketone) by graphene oxide nanosheet for polymer electrolyte membrane fuel cell applications

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
McCarthy CP, McGuinness NB, Carolan PB, Fox CM, Alcock-Earley BE, Breslin CB, Rooney AD (2013) Electrochemical deposition of hollow N-substituted polypyrrole microtubes from an acoustically formed emulsion. Macromolecules 46:1008–1016. doi:10.​1021/​ma302493e CrossRef
2.
Gao W, Sattayasamitsathit S, Uygun A, Pei A, Ponedal A, Wang J (2012) Polymer-based tubular microbots: role of composition and preparation. Nano 4:2447. doi:10.​1039/​c2nr30138e
3.
Jin E, Lu X, Bian X, Kong L, Zhang W, Wang C (2010) Unique tetragonal starlike polyaniline microstructure and its application in electrochemical biosensing. J Mater Chem 20:3079. doi:10.​1039/​b925753e CrossRef
4.
Kim SH, Kim JH, Choi HJ, Park J (2015) Pickering emulsion polymerized poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/polystyrene composite particles and their electric stimuli-response. RSC Adv 5:72387–72393. doi:10.​1039/​C5RA10661C CrossRef
5.
6.
7.
Fan W, Zhang C, Tjiu WW, Pramoda KP, He C, Liu T (2013) Graphene-wrapped polyaniline hollow spheres as novel hybrid electrode materials for supercapacitor applications. ACS Appl Mater Interfaces 5:3382–3391. doi:10.​1021/​am4003827 CrossRef
8.
Fabregat G, Estrany F, Casas MT, Alemán C, Armelin E (2014) Detection of dopamine using chemically synthesized multilayered hollow microspheres. J Phys Chem B 118:4702–4709. doi:10.​1021/​jp500959j CrossRef
9.
Liu YD, Zhang K, Zhang WL, Choi HJ (2012) Conducting material-incorporated electrorheological fluids: core-shell structured spheres. Aust J Chem 65:1195–1202. doi:10.​1071/​CH12129 CrossRef
10.
Liu YD, Kim JE, Choi HJ (2011) Core-shell structured monodisperse poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonic acid) coated polystyrene microspheres and their electrorheological response. Macromol Rapid Commun 32:881–886. doi:10.​1002/​marc.​201100160 CrossRef
11.
Han MG, Sperry J, Gupta A, Huebner CF, Ingram ST, Foulger SH (2007) Polyaniline coated poly(butyl methacrylate) core-shell particles: roll-to-roll printing of templated electrically conductive structures. J Mater Chem 17:1347–1352. doi:10.​1039/​b618343c CrossRef
12.
Morales-Tirado JA, Silence SM, Chung JT (2008) Particle having conductive polymer surface additive. U.S. Pat. 7 419 754
13.
Kirchmeyer S, Reuter K (2005) Scientific importance, properties and growing applications of poly(3,4-ethylenedioxythiophene). J Mater Chem 15:2077–2088. doi:10.​1039/​b417803n CrossRef
14.
Kelly TL, Yamada Y, Che SPY, Yano K, Wolf MO (2008) Monodisperse poly(3,4-ethylenedioxythiophene)–silica microspheres: synthesis and assembly into crystalline colloidal arrays. Adv Mater 20:2616–2621. doi:10.​1002/​adma.​200703131 CrossRef
15.
Kelly TL, Yano K, Wolf MO (2009) Supercapacitive properties of PEDOT and carbon colloidal microspheres. ACS Appl Mater Interfaces 1:2536–2543. doi:10.​1021/​am900575v CrossRef
16.
Zhou W, Hu X, Bai X, Zhou S, Sun C, Yan J, Chen P (2011) Synthesis and electromagnetic, microwave absorbing properties of core–shell Fe3O4–poly(3,4-ethylenedioxythiophene) microspheres. ACS Appl Mater Interfaces 3:3839–3845. doi:10.​1021/​am2004812 CrossRef
17.
Luo S-C, Yu H, Wan ACA, Han Y, Ying JY (2008) A general synthesis for PEDOT-coated nonconductive materials and PEDOT hollow particles by aqueous chemical polymerization. Small 4:2051–2058. doi:10.​1002/​smll.​200800033 CrossRef
18.
Khan MA, Armes SP (1999) Synthesis and characterization of micrometer-sized poly(3,4-ethylenedioxythiophene)-coated polystyrene latexes. Langmuir 15:3469–3475. doi:10.​1021/​la9815897 CrossRef
19.
Han MG, Foulger SH (2004) Crystalline colloidal arrays composed of poly(3,4-ethylenedioxythiophene)-coated polystyrene particles with a stop band in the visible regime. Adv Mater 16:231–234. doi:10.​1002/​adma.​200305642 CrossRef
20.
21.
22.
23.
Khan MA, Armes SP, Perruchot C, Ouamara H, Chehimi MM, Greaves SJ, Watts JF (2000) Surface characterization of poly(3,4-ethylenedioxythiophene)-coated latexes by X-ray photoelectron spectroscopy. Langmuir 16:4171–4179. doi:10.​1021/​la991390+ CrossRef
24.
Burchell MJ, Cole MJ, Lascelles SF, Khan MA, Barthet C, Wilson SA, Cairns DB, Armes SP (1999) Acceleration of conducting polymer-coated latex particles as projectiles in hypervelocity impact experiments. J Phys D Appl Phys 32:1719–1728. doi:10.​1088/​0022-3727/​32/​14/​325 CrossRef
25.
Han MG, Foulger SH (2004) Preparation of poly(3,4-ethylenedioxythiophene) (PEDOT) coated silica core–shell particles and PEDOT hollow particles. Chem Commun 2154–2155. doi:10.​1039/​B409396H
26.
Lefebvre M, Qi Z, Rana D, Pickup PG (1999) Chemical synthesis, characterization, and electrochemical studies of poly(3,4-ethylenedioxythiophene)/poly(styrene-4-sulfonate) composites. Chem Mater 11:262–268. doi:10.​1021/​cm9804618 CrossRef
27.
Zotti G, Zecchin S, Schiavon G, Louwet F, Groenendaal L, Crispin X, Osikowicz W, Salaneck W, Fahlman M (2003) Electrochemical and XPS studies toward the role of monomeric and polymeric sulfonate counterions in the synthesis, composition, and properties of poly(3,4-ethylenedioxythiophene). Macromolecules 36:3337–3344. doi:10.​1021/​ma021715k CrossRef
28.
Diah AWM, Quirino JP, Belcher W, Holdsworth CI (2014) Investigation of the doping efficiency of poly(styrene sulfonic acid) in poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonic acid) dispersions by capillary electrophoresis: CE and CEC. Electrophoresis 35:1976–1983. doi:10.​1002/​elps.​201400056 CrossRef
29.
Stöcker T, Köhler A, Moos R (2012) Why does the electrical conductivity in PEDOT:PSS decrease with PSS content? A study combining thermoelectric measurements with impedance spectroscopy. J Polym Sci Part B Polym Phys 50:976–983. doi:10.​1002/​polb.​23089 CrossRef
30.
Yuan Q, Yang L, Wang M, Wang H, Ge X, Ge X (2009) The mechanism of the formation of multihollow polymer spheres through sulfonated polystyrene particles. Langmuir 25:2729–2735. doi:10.​1021/​la803724r CrossRef
31.
32.
33.
Li H-M, Liu J-C, Zhu F-M, Lin S-A (2001) Synthesis and physical properties of sulfonated syndiotactic polystyrene ionomers. Polym Int 50:421–428. doi:10.​1002/​pi.​646 CrossRef
34.
Kvarnström C, Neugebauer H, Blomquist S, Ahonen HJ, Kankare J, Ivaska A (1999) In situ spectroelectrochemical characterization of poly(3,4-ethylenedioxythiophene). Electrochim Acta 44:2739–2750. doi:10.​1016/​S0013-4686(98)00405-8 CrossRef
35.
Matsushita S, Yan B, Yamamoto S, Jeong YS, Akagi K (2014) Helical carbon and graphite films prepared from helical poly(3,4-ethylenedioxythiophene) films synthesized by electrochemical polymerization in chiral nematic liquid crystals. Angew Chem Int Ed 53:1659–1663. doi:10.​1002/​anie.​201308462 CrossRef
36.
Diah AWM, Quirino JP, Belcher W, Holdsworth CI (2016) An assessment of the effect of synthetic and doping conditions on the processability and conductivity of poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonic acid). Macromol Chem Phys 217:1907–1916. doi:10.​1002/​macp.​201600165 CrossRef
Metadaten
Titel
Electrically conducting polymeric microspheres comprised of sulfonated polystyrene cores coated with poly(3,4-ethylenedioxythiophene)
verfasst von
Aleksei V. Kubarkov
Olga A. Pyshkina
Evgeny A. Karpushkin
Keith J. Stevenson
Vladimir G. Sergeyev
Publikationsdatum
03.05.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 6/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4101-1

Weitere Artikel der Ausgabe 6/2017

Colloid and Polymer Science 6/2017 Zur Ausgabe

Original Contribution

Hydrophilic drug-loaded PLGA nanoparticles for transdermal delivery

Original Contribution

Preparation of metal ion-mediated Furosemide molecularly imprinted polymer: synthesis, characterization, and drug release studies

Original Contribution

Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase

Original Contribution

Facile tailor-made enhancement in proton conductivity of sulfonated poly(ether ether ketone) by graphene oxide nanosheet for polymer electrolyte membrane fuel cell applications

Original Contribution

Formation and hosting properties of polyacrylate–surfactant complexes

Original Contribution

Predictions of Takayanagi model for tensile modulus of polymer/CNT nanocomposites by properties of nanoparticles and filler network

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise