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Topics in Catalysis
Erschienen in: Topics in Catalysis 14-16/2014

01.09.2014 | Original Paper

Electro-Oxidation of Glycerol on Platinum Modified by Adatoms: Activity and Selectivity Effects

verfasst von: Youngkook Kwon, Thomas J. P. Hersbach, Marc T. M. Koper

Erschienen in: Topics in Catalysis | Ausgabe 14-16/2014

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Abstract

Antimony irreversibly adsorbed on a carbon supported platinum electrode oxidizes glycerol selectively to dihydroxyacetone with a lower onset potential (ca. 150 mV) and a higher peak current density (ca. 170 %) compared to clean Pt/C. Pb, In, and Sn also promote the catalytic activity of glycerol oxidation, however the reaction pathway towards the primary alcohol oxidation remains unchanged. Higher surface coverage by adatoms on Pt/C generally increases the activity of glycerol oxidation.
Vorheriger Artikel Au Catalysts for Acetylene Hydrochlorination and Carbon Monoxide Oxidation
Nächster Artikel Role of Lattice Oxygen in the Propane Combustion Over Pt/Yttria-Stabilized Zirconia : Isotopic Studies

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Literatur
1.
Zhou CH, Beltramini JN, Fan YX, Lu GQ (2008) Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals. Chem Soc Rev 37:527–549CrossRef
2.
Behr A, Eilting J, Irawadi K, Leschinski J, Lindner F (2008) Improved utilisation of renewable resources: New important derivatives of glycerol. Green Chem 10:13–30CrossRef
3.
Katryniok B, Kimura H, Skrzynska E, Girardon JS, Fongarland P, Capron M, Ducoulombier R, Mimura N, Paul S, Dumeignil F (2011) Selective catalytic oxidation of glycerol: perspectives for high value chemicals. Green Chem 13:1960–1979CrossRef
4.
Woerz N, Brandner A, Claus P (2010) Platinum-bismuth-catalyzed oxidation of glycerol: kinetics and the origin of selective deactivation. J Phys Chem C 114:1164–1172CrossRef
5.
Painter RM, Pearson DM, Waymouth RM (2010) Selective catalytic oxidation of glycerol to dihydroxyacetone. Angew Chem Int Ed 49:9456–9459CrossRef
6.
Simoes M, Baranton S, Coutanceau C (2012) Electrochemical valorisation of glycerol. ChemSusChem 5:2106–2124CrossRef
7.
Svitel J, Sturdik E (1994) Product yield and by-product formation in glycerol conversion to dihydroxyacetone by gluconobacter-oxydans. J Ferment Bioeng 78:351–355CrossRef
8.
Carrettin S, McMorn P, Johnston P, Griffin K, Kiely CJ, Hutchings GJ (2003) Oxidation of glycerol using supported Pt, Pd and Au catalysts. Phys Chem Chem Phys 5:1329–1336CrossRef
9.
Demirel S, Lehnert K, Lucas M, Claus P (2007) Use of renewables for the production of chemicals: glycerol oxidation over carbon supported gold catalysts. Appl Catal B 70:637–643CrossRef
10.
Hu W, Knight D, Lowry B, Varma A (2010) Selective oxidation of glycerol to dihydroxyacetone over Pt-Bi/C catalyst: optimization of catalyst and reaction conditions. Ind Eng Chem Res 49:10876–10882CrossRef
11.
Kimura H (1993) Selective oxidation of glycerol on a platinum-bismuth catalyst by using a fixed-bed reactor. Appl Catal A 105:147–158CrossRef
12.
Kimura H, Tsuto K, Wakisaka T, Kazumi Y, Inaya Y (1993) Selective oxidation of glycerol on a platinum bismuth catalyst. Appl Catal A 96:217–228CrossRef
13.
Xin L, Zhang Z, Wang Z, Li W (2012) Simultaneous generation of mesoxalic acid and electricity from glycerol on a gold anode catalyst in anion-exchange membrane fuel cells. ChemCatChem 4:1105–1114CrossRef
14.
Zhang Z, Xin L, Li W (2012) Electrocatalytic oxidation of glycerol on Pt/C in anion-exchange membrane fuel cell: cogeneration of electricity and valuable chemicals. Appl Catal B 119:40–48CrossRef
15.
Zhang Z, Xin L, Qi J, Chadderdon DJ, Li W (2013) Supported Pt, Pd and Au nanoparticle anode catalysts for anion-exchange membrane fuel cells with glycerol and crude glycerol fuels. Appl Catal B 136:29–39
16.
Zhang Z, Xin L, Qi J, Wang Z, Li W (2012) Selective electro-conversion of glycerol to glycolate on carbon nanotube supported gold catalyst. Green Chem 14:2150–2152CrossRef
17.
Gomes JF, Gasparotto LHS, Tremiliosi-Filho G (2013) Glycerol electro-oxidation over glassy-carbon-supported Au nanoparticles: direct influence of the carbon support on the electrode catalytic activity. Phys Chem Chem Phys 15:10339–10349CrossRef
18.
Gomes JF, Martins CA, Janete Giz M, Tremiliosi-Filho G, Camara GA (2013) Insights into the adsorption and electro-oxidation of glycerol: self-inhibition and concentration effects. J Catal 301:154–161CrossRef
19.
Kwon Y, Birdja Y, Spanos I, Rodriguez P, Koper MTM (2012) Highly selective electro-oxidation of glycerol to dihydroxyacetone on platinum in the presence of bismuth. ACS Catal 2:759–764CrossRef
20.
Kwon Y, Schouten KJP, Koper MTM (2011) Mechanism of the catalytic oxidation of glycerol on polycrystalline gold and platinum electrodes. ChemCatChem 3:1176–1185CrossRef
21.
Kwon Y, Koper MTM (2010) Combining voltammetry with HPLC: application to electro-oxidation of glycerol. Anal Chem 82:5420–5424CrossRef
22.
Rodriguez P, Solla-Gullon J, Vidal-Iglesias FJ, Herrero E, Aldaz A, Feliu JM (2005) Determination of (111) ordered domains on platinum electrodes by irreversible adsorption of bismuth. Anal Chem 77:5317–5323CrossRef
23.
Kwon Y, Raaijman SJ, Koper MTM (2014) Role of peroxide in the catalytic activity of gold for oxidation reactions in aqueous media: an electrochemical study. ChemCatChem 6:79–81. doi:10.​1002/​cctc.​201300460
24.
Climent V, Herrero E, Feliu JM (1998) Electrocatalysis of formic acid and CO oxidation on antimony-modified Pt(111) electrodes. Electrochim Acta 44:1403–1414CrossRef
25.
Herrero E, Feliu JM, Aldaz A (1994) Poison formation reaction from formic acid on Pt(100) electrodes modified by irreversibly adsorbed bismuth and antimony. J Electroanal Chem 368:101–108CrossRef
Metadaten
Titel
Electro-Oxidation of Glycerol on Platinum Modified by Adatoms: Activity and Selectivity Effects
verfasst von
Youngkook Kwon
Thomas J. P. Hersbach
Marc T. M. Koper
Publikationsdatum
01.09.2014
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 14-16/2014
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-014-0292-6

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