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Journal of Materials Science
Erschienen in: Journal of Materials Science 4/2015

01.02.2015 | Original Paper

Electrochemical copolymerization of 3,4-ethylenedioxythiophene and 6-cyanoindole and its electrochromic property

verfasst von: Chenxi Li, Changlong Liu, Liang Shi, Guangming Nie

Erschienen in: Journal of Materials Science | Ausgabe 4/2015

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Abstract

A novel copolymer based on 6-cyanoindole (6CNIn) and 3,4-ethylenedioxythiophene (EDOT) was electrochemically synthesized in acetonitrile containing tetrabutylammonium tetrafluoroborate (TBATFB). The copolymer P(6CNIn-co-EDOT) was characterized by cyclic voltammetry, FT-IR, 1H NMR, SEM, and spectroelectrochemical analysis. According to the results of FT-IR and 1H NMR spectra, the electrochemical copolymerization located at C(2), C(3) position of 6CNIn. Spectroelectrochemical analysis indicates this copolymer film has distinct electrochromic properties, which can convert between brick-red in the reduced state and sky-blue in the oxidized state. Thus, an electrochromic device (ECD) based on P(6CNIn-co-EDOT) and poly(3,4-ethylenedioxythiophene) was also constructed, which had a color change from dark green in neutral state to dark blue in oxidized state. This ECD showed good optical contrast (30 % at 485 nm, 32 % at 610 nm), high coloration efficiency (216 cm2 C−1 at 485 nm, 223 cm2 C−1 at 610 nm), fast response time (0.7 s at 485 nm, 0.9 s at 610 nm), and long-term stability.
Vorheriger Artikel Synthesis and characterization of nanosized NiO@Ti0.94V0.06O1.94B0.06 with enhanced photocatalytic activity under visible light
Nächster Artikel Microwave-hydrothermal synthesis of Co-doped FeS2 as a visible-light photocatalyst

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Metadaten
Titel
Electrochemical copolymerization of 3,4-ethylenedioxythiophene and 6-cyanoindole and its electrochromic property
verfasst von
Chenxi Li
Changlong Liu
Liang Shi
Guangming Nie
Publikationsdatum
01.02.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 4/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8746-6

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