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Erschienen in: Colloid and Polymer Science 9/2013

01.09.2013 | Original Contribution

Electrochemical property of graphene oxide/polyaniline composite prepared by in situ interfacial polymerization

verfasst von: Van Hoa Nguyen, Lulu Tang, Jae-Jin Shim

Erschienen in: Colloid and Polymer Science | Ausgabe 9/2013

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Abstract

Graphene oxide–polyaniline composites were synthesized by an interfacial method using two green solvents, water and an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate), as the two phases. The interfacial polymerization of aniline was carried out at room temperature in the presence of graphene oxide dispersed in the aqueous phase. The analysis revealed the surface of the graphene sheets to be coated with a smooth thin layer of polyaniline. The thermal stability of the composites was much better than that of bare graphene oxide. The composites were used to modify the glass carbon electrodes for the chemical detection of hydrogen peroxide in aqueous media. This method is a facile, efficient, and green route for the development of doped polyaniline materials suitable for chemical sensors.

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Literatur
1.
Zurück zum Zitat Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV et al (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197–200CrossRef Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV et al (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197–200CrossRef
2.
Zurück zum Zitat Zhang YB, Tan YW, Stormer HL, Kim P (2005) Experimental observation of the quantum Hall effect and Berry's phase in graphene. Nature 438:201–204CrossRef Zhang YB, Tan YW, Stormer HL, Kim P (2005) Experimental observation of the quantum Hall effect and Berry's phase in graphene. Nature 438:201–204CrossRef
3.
Zurück zum Zitat Dan YP, Lu Y, Kybert NJ, Luo JT, Johnson ATC (2009) Intrinsic response of graphene vapor sensors. Nano Lett 9:1472–1475CrossRef Dan YP, Lu Y, Kybert NJ, Luo JT, Johnson ATC (2009) Intrinsic response of graphene vapor sensors. Nano Lett 9:1472–1475CrossRef
4.
Zurück zum Zitat Robinson JT, Perkins FK, Snow ES, Wei ZQ, Sheehan PE (2008) Reduced graphene oxide molecular sensors. Nano Lett 8:3137–3140CrossRef Robinson JT, Perkins FK, Snow ES, Wei ZQ, Sheehan PE (2008) Reduced graphene oxide molecular sensors. Nano Lett 8:3137–3140CrossRef
5.
Zurück zum Zitat Ohno Y, Maehashi K, Yamashiro Y, Matsumoto K (2009) Electrolyte-gated graphene field-effect transistors for detecting pH and protein adsorption. Nano Lett 9:3318–3322CrossRef Ohno Y, Maehashi K, Yamashiro Y, Matsumoto K (2009) Electrolyte-gated graphene field-effect transistors for detecting pH and protein adsorption. Nano Lett 9:3318–3322CrossRef
6.
Zurück zum Zitat Zhang K, Zhang WL, Choi HJ (2012) Facile fabrication of self-assembled PMMA/graphene oxide composite particles and their electroresponsive properties. Colloid Polym Sci. doi:10.1007/s00396-012-2814-8 Zhang K, Zhang WL, Choi HJ (2012) Facile fabrication of self-assembled PMMA/graphene oxide composite particles and their electroresponsive properties. Colloid Polym Sci. doi:10.​1007/​s00396-012-2814-8
7.
Zurück zum Zitat Huang B, Li ZY, Liu ZR, Zhou G, Hao SG, Wu J, Gu BL, Duan WH (2008) Adsorption of gas molecules on graphene nanoribbons and its implication for nanoscale molecule sensor. J Phys Chem C 112:13442–13446CrossRef Huang B, Li ZY, Liu ZR, Zhou G, Hao SG, Wu J, Gu BL, Duan WH (2008) Adsorption of gas molecules on graphene nanoribbons and its implication for nanoscale molecule sensor. J Phys Chem C 112:13442–13446CrossRef
8.
9.
Zurück zum Zitat Leenaerts O, Partoens B, Peeters FM (2008) Adsorption of H2O, NH3, CO, NO2, and NO on graphene: a first-principles study. Phys Rev B 77:125416–125422CrossRef Leenaerts O, Partoens B, Peeters FM (2008) Adsorption of H2O, NH3, CO, NO2, and NO on graphene: a first-principles study. Phys Rev B 77:125416–125422CrossRef
10.
Zurück zum Zitat Yang J, Burkinshaw SM, Zhou J, Monkman AP, Brown PJ (2003) Fabrication and characteristics of 2-acrylamino-2-methyl-1-propanesulfonic acid-doped polyaniline hollow fibers. Adv Mater 15:1081–1084CrossRef Yang J, Burkinshaw SM, Zhou J, Monkman AP, Brown PJ (2003) Fabrication and characteristics of 2-acrylamino-2-methyl-1-propanesulfonic acid-doped polyaniline hollow fibers. Adv Mater 15:1081–1084CrossRef
11.
Zurück zum Zitat Alivisatos AP (1996) Semiconductor clusters, nanocrystals, and quantum dots. Science 271:933–937CrossRef Alivisatos AP (1996) Semiconductor clusters, nanocrystals, and quantum dots. Science 271:933–937CrossRef
12.
Zurück zum Zitat Dhand C, Das M, Datta M, Malhotra BD (2011) Recent advances in polyaniline based biosensors. Biosens Bioelectron 26:2811–2821CrossRef Dhand C, Das M, Datta M, Malhotra BD (2011) Recent advances in polyaniline based biosensors. Biosens Bioelectron 26:2811–2821CrossRef
13.
Zurück zum Zitat Bhadra S, Khastgir D, Singha NK, Lee JH (2009) Progress in preparation, processing and applications of polyaniline. Prog Polym Sci 34:783–810CrossRef Bhadra S, Khastgir D, Singha NK, Lee JH (2009) Progress in preparation, processing and applications of polyaniline. Prog Polym Sci 34:783–810CrossRef
14.
Zurück zum Zitat Sergeyeva TA, Lavrik NV, Piletsky SA, Rachkov AE, Elskaya AV (1996) Polyaniline label-based conductometric sensor for IgG detection. Sens Actuat B-Chem 34:283–288CrossRef Sergeyeva TA, Lavrik NV, Piletsky SA, Rachkov AE, Elskaya AV (1996) Polyaniline label-based conductometric sensor for IgG detection. Sens Actuat B-Chem 34:283–288CrossRef
15.
Zurück zum Zitat Luo YC, Do JS (2004) Urea biosensor based on PANi(urease)-Nafion/Au composite electrode. Biosens Bioelectron 20:15–23CrossRef Luo YC, Do JS (2004) Urea biosensor based on PANi(urease)-Nafion/Au composite electrode. Biosens Bioelectron 20:15–23CrossRef
16.
Zurück zum Zitat Wang Y, Li Z, Wang J, Li J, Lin Y (2011) Graphene and graphene oxide: biofunctionalization and applications in biotechnology. Trends Biotechnol 29:205–212CrossRef Wang Y, Li Z, Wang J, Li J, Lin Y (2011) Graphene and graphene oxide: biofunctionalization and applications in biotechnology. Trends Biotechnol 29:205–212CrossRef
17.
Zurück zum Zitat Huang X, Yin Z, Wu S, Qi X, He Q, Zhang Q et al (2011) Graphene-based materials: synthesis, characterization, properties, and applications. Small 7:1876–1902CrossRef Huang X, Yin Z, Wu S, Qi X, He Q, Zhang Q et al (2011) Graphene-based materials: synthesis, characterization, properties, and applications. Small 7:1876–1902CrossRef
18.
Zurück zum Zitat Zhou X, Wu T, Hu B, Yang G, Han B (2010) Synthesis of graphene/polyaniline composite nanosheets mediated by polymerized ionic liquid. Chem Commun 46:3663–3665CrossRef Zhou X, Wu T, Hu B, Yang G, Han B (2010) Synthesis of graphene/polyaniline composite nanosheets mediated by polymerized ionic liquid. Chem Commun 46:3663–3665CrossRef
19.
Zurück zum Zitat Huang YF, Lin CW (2012) Polyaniline-intercalated graphene oxide sheet and its transition to a nanotube through a self-curling process. Polymer 53:1079–1085CrossRef Huang YF, Lin CW (2012) Polyaniline-intercalated graphene oxide sheet and its transition to a nanotube through a self-curling process. Polymer 53:1079–1085CrossRef
20.
Zurück zum Zitat Fan Y, Liu JH, Yang CP, Yu M, Liu P (2011) Graphene–polyaniline composite film modified electrode for voltammetric determination of 4-aminophenol. Sens Actuat B-Chem 157:669–674CrossRef Fan Y, Liu JH, Yang CP, Yu M, Liu P (2011) Graphene–polyaniline composite film modified electrode for voltammetric determination of 4-aminophenol. Sens Actuat B-Chem 157:669–674CrossRef
21.
Zurück zum Zitat Bao Y, Song J, Mao Y, Han D, Yang F, Niu L et al (2011) Graphene oxide-templated polyaniline microsheets toward simultaneous electrochemical determination of AA/DA/UA. Electroanalysis 23:878–884CrossRef Bao Y, Song J, Mao Y, Han D, Yang F, Niu L et al (2011) Graphene oxide-templated polyaniline microsheets toward simultaneous electrochemical determination of AA/DA/UA. Electroanalysis 23:878–884CrossRef
22.
Zurück zum Zitat Nguyen VH, Kim BK, Jo YL, Shim JJ (2012) Preparation and antibacterial activity of silver nanoparticles-decorated graphene composites. J Supercrit Fluid 72:28–35CrossRef Nguyen VH, Kim BK, Jo YL, Shim JJ (2012) Preparation and antibacterial activity of silver nanoparticles-decorated graphene composites. J Supercrit Fluid 72:28–35CrossRef
23.
Zurück zum Zitat Tang Q, Wu J, Sun H, Lin J, Fan S, Hu D (2008) Polyaniline/polyacrylamide conducting composite hydrogel with a porous structure. Carbohyd Polym 74:215–219CrossRef Tang Q, Wu J, Sun H, Lin J, Fan S, Hu D (2008) Polyaniline/polyacrylamide conducting composite hydrogel with a porous structure. Carbohyd Polym 74:215–219CrossRef
24.
Zurück zum Zitat Pouget JP, Jozefowica ME, Epstein AJ, Tang X, MacDiarmid AG (1991) X-ray structure of polyaniline. Macromolecules 24:779–789CrossRef Pouget JP, Jozefowica ME, Epstein AJ, Tang X, MacDiarmid AG (1991) X-ray structure of polyaniline. Macromolecules 24:779–789CrossRef
25.
Zurück zum Zitat Wang H, Hao Q, Yang X, Lu L, Wang X (2010) Effect of graphene oxide on the properties of its composite with polyaniline. ACS Appl Mater Inter 2:821–828CrossRef Wang H, Hao Q, Yang X, Lu L, Wang X (2010) Effect of graphene oxide on the properties of its composite with polyaniline. ACS Appl Mater Inter 2:821–828CrossRef
26.
Zurück zum Zitat Hu H, Wang X, Wang J, Wan L, Liu F, Zheng H et al (2010) Preparation and properties of graphene nanosheets–polystyrene nanocomposites via in situ emulsion polymerization. Chem Phys Lett 484:247–253CrossRef Hu H, Wang X, Wang J, Wan L, Liu F, Zheng H et al (2010) Preparation and properties of graphene nanosheets–polystyrene nanocomposites via in situ emulsion polymerization. Chem Phys Lett 484:247–253CrossRef
27.
Zurück zum Zitat Fan X, Peng W, Li Y, Li X, Wang S, Zhang G et al (2008) Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv Mater 20:4490–4493CrossRef Fan X, Peng W, Li Y, Li X, Wang S, Zhang G et al (2008) Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv Mater 20:4490–4493CrossRef
28.
Zurück zum Zitat Chitara B, Krupanidhi SB, Rao CNR (2011) Solution processed reduced graphene oxide ultraviolet detector. Appl Phys Lett 99:113114–113116CrossRef Chitara B, Krupanidhi SB, Rao CNR (2011) Solution processed reduced graphene oxide ultraviolet detector. Appl Phys Lett 99:113114–113116CrossRef
29.
Zurück zum Zitat Stejskal J, Kratochvil P, Radhakrishnan N (1993) Polyaniline dispersions 2. UV–Vis absorption spectra. Synth Met 61:225–231CrossRef Stejskal J, Kratochvil P, Radhakrishnan N (1993) Polyaniline dispersions 2. UV–Vis absorption spectra. Synth Met 61:225–231CrossRef
30.
Zurück zum Zitat Laviron E (1979) General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems. J Electroanal Chem Interfac 101:19–28CrossRef Laviron E (1979) General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems. J Electroanal Chem Interfac 101:19–28CrossRef
Metadaten
Titel
Electrochemical property of graphene oxide/polyaniline composite prepared by in situ interfacial polymerization
verfasst von
Van Hoa Nguyen
Lulu Tang
Jae-Jin Shim
Publikationsdatum
01.09.2013
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 9/2013
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-013-2940-y

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