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Journal of Nanoparticle Research

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01.08.2013 | Research Paper

Electrostatic adsorption of hematite nanoparticles on self-assembled monolayer surfaces

verfasst von: Boris L. T. Lau, Rixiang Huang, Andrew S. Madden

Erschienen in: Journal of Nanoparticle Research | Ausgabe 8/2013

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Abstract

Deposition of nanoparticles (NPs) on different environmental surfaces has important implication on their fate and transport in aquatic systems. This study quantitatively and kinetically analyzed the adsorption of hematite (α-Fe₂O₃) NPs (HNPs) onto self-assembled monolayer modified surfaces using QCM, AFM, and SEM. Experiments were conducted to study the immobilization of two different sizes of HNPs onto gold substrate and surfaces modified with 1-mercapto-11-undecanoic acid and cysteine. It is shown that the extent and rate of HNPs adsorption onto substrate surfaces can be modulated electrostatically. Control over the surface coverage of the adsorbed HNPs has been demonstrated by pH variation. Size-dependent adsorption kinetics was observed, with the 79 nm HNPs adsorbed 2–3 times faster than the 116 nm HNPs.

Vorheriger Artikel Ge nanoparticles by direct oxidation of Zintl alloys and their electrochemical behavior as anodes of Li-ion batteries

Nächster Artikel Effect of surface charge on the colloidal stability and in vitro uptake of carboxymethyl dextran-coated iron oxide nanoparticles

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Titel: Electrostatic adsorption of hematite nanoparticles on self-assembled monolayer surfaces
verfasst von: Boris L. T. Lau
Rixiang Huang
Andrew S. Madden
Publikationsdatum: 01.08.2013
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 8/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-013-1873-1

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