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2022 | OriginalPaper | Buchkapitel

6. Electrostatic Layer-by-Layer Self-Assembly Method: A Physico-Chemical Perspective

verfasst von : Eduardo Guzmán, Ana Mateos-Maroto, Francisco Ortega, Ramón G. Rubio

Erschienen in: Supramolecular Assemblies Based on Electrostatic Interactions

Verlag: Springer International Publishing

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Abstract

The use of the Layer-by-Layer (LbL) method for the fabrication of structural and functional materials through the alternate deposition of polyelectrolyte bearing opposite charges has undergone a spectacular development due to the numerous avenues that offer for controlling the assembly process by simply tuning some operational parameters or characteristic of the layering molecules. This is only possible by a careful examination of the physicochemical bases underlying the assembly process. This chapter tries to provide a broad physicochemical perspective trying to disentangle some of the most fundamental aspects underlying the exploitation of the LbL electrostatic self-assembly for opening new avenues in the design of novel nanomaterials.

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Vorheriges Kapitel Nano-Objects by Spontaneous Electrostatic Self-Assembly in Aqueous Solution

Nächstes Kapitel Supramolecular Assemblies Based on σ-hole Interactions

Kumar B, Park YT, Castro M, Grunlan JC, Feller JF (2012) Fine control of carbon nanotubes–polyelectrolyte sensors sensitivity by electrostatic layer by layer assembly (eLbL) for the detection of volatile organic compounds (VOC). Talanta 88:396–402. https://doi.org/10.1016/j.talanta.2011.11.006

del Mercato LL, Rivera-Gil P, Abbasi AZ, Ochs M, Ganas C, Zins I et al (2010) LbL multilayer capsules: recent progress and future outlook for their use in life sciences. Nanoscale 2(4):458–467. https://doi.org/10.1039/B9NR00341JCrossRefPubMed

del Mercato LL, Ferraro MM, Baldassarre F, Mancarella S, Greco V, Rinaldi R et al (2014) Biological applications of LbL multilayer capsules: from drug delivery to sensing. Adv Colloid Interface Sci 207:139–154. https://doi.org/10.1016/j.cis.2014.02.014CrossRefPubMed

Costa RR, Mano JF (2014) Polyelectrolyte multilayered assemblies in biomedical technologies. Chem Soc Rev 43:3453–3479. https://doi.org/10.1039/C3CS60393HCrossRefPubMed

Silva JM, Reis RL, Mano JF (2016) Biomimetic extracellular environment based on natural origin polyelectrolyte multilayers. Small 12:4308–4342. https://doi.org/10.1002/smll.201601355CrossRefPubMed

Guzmán E, Mateos-Maroto A, Ruano M, Ortega F, Rubio RG (2017) Layer-by-Layer polyelectrolyte assemblies for encapsulation and release of active compounds. Adv Colloid Interface Sci 249:290–307. https://doi.org/10.1016/j.cis.2017.04.009CrossRefPubMed

de Villiers MM, Otto DP, Strydom SJ, Lvov YM (2011) Introduction to nanocoatings produced by layer-by-layer (LbL) self-assembly. Adv Drug Deliv Rev 63:701–715. https://doi.org/10.1016/j.addr.2011.05.011CrossRefPubMed

Lavalle P, Voegel J-C, Vautier D, Senger B, Schaaf P, Ball V (2011) Dynamic aspects of films prepared by a sequential deposition of species: perspectives for smart and responsive materials. Adv Mat 23:1191–1221. https://doi.org/10.1002/adma.201003309

de Villiers MM, Lvov YM (2011) Layer-by-layer self-assembled nanoshells for drug delivery. Adv Drug Deliv Rev 63:699–700. https://doi.org/10.1016/j.addr.2011.06.001CrossRefPubMed

10.

Krogman KC, Cohen RE, Hammond PT, Rubner MF, Wang BN (2013) Industrial-scale spray layer-by-layer assembly for production of biomimetic photonic systems. Bioinspir Biomim 8:045005. https://doi.org/10.1088/1748-3182/8/4/CrossRefPubMed

11.

Zhao S, Caruso F, Dähne L, Decher G, De Geest BG, Fan J et al (2019) The future of layer-by-layer assembly: a tribute to ACS nano associate editor Helmuth Möhwald. ACS Nano 13:6151–6169. https://doi.org/10.1021/acsnano.9b03326CrossRefPubMed

12.

Schlenoff JB (2009) Retrospective on the future of polyelectrolyte multilayers. Langmuir 25:14007–14010. https://doi.org/10.1021/la901950cCrossRefPubMed

13.

Decher G, Schlenoff JB (eds) (2003) Multilayer thin films-sequential assembly of nanocomposite materials. Germany Wiley-VCH Verlag, Berlin

14.

Decher G, Hong JD (1991) Buildup of ultrathin multilayer films by a self-assembly process 2. Consecutive adsorption of anionic and cationic bipolar amphiphiles and polyelectrolytes on charged surfaces. Ber Bunsen-Ges Phys Chem Chem Phys 95:1430–1434. https://doi.org/10.1002/bbpc.19910951122

15.

Decher G, Hong JD (1991) Buildup of ultrathin multilayer films by a self-assembly process 1. Consecutive adsorption of anionic and cationic bipolar amphiphiles on charged surfaces. Makromol Chem, Macromol Symp 46:321–327. https://doi.org/10.1002/masy.19910460145

16.

Decher G, Hong JD, Schmitt J (1992) Buildup of ultrathin multilayer films by a self-assembly process. 3. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces. Thin Solid Films 210:831–835. https://doi.org/10.1016/0040-6090(92)90417-a

17.

Gucht J, Spruijt E, Lemmers M, Cohen Stuart MA (2011) Polyelectrolyte complexes: bulk phases and colloidal systems. J Colloid Interface Sci 361:407–422. https://doi.org/10.1016/j.jcis.2011.05.080

18.

Guzmán E, San Miguel V, Peinado C, Ortega F, Rubio RG (2010) Polyelectrolyte multilayers containing triblock copolymers of different charge ratio. Langmuir 26:11494–11502. https://doi.org/10.1021/la101043zCrossRefPubMed

19.

Guzmán E, Chuliá-Jordán R, Ortega F, Rubio RG (2011) Influence of the percentage of acetylation on the assembly of LbL multilayers of poly(acrylic acid) and chitosan. Phys Chem Chem Phys 13:18200–18207. https://doi.org/10.1039/C1CP21609KCrossRefPubMed

20.

Guzmán E, Cavallo JA, Chuliá-Jordán R, Gómez C, Strumia MC, Ortega F et al (2011) pH-induced changes in the fabrication of multilayers of poly(acrylic acid) and chitosan: fabrication, properties, and tests as a drug storage and delivery system. Langmuir 27:6836–6845. https://doi.org/10.1021/la200522rCrossRefPubMed

21.

Keeney M, Jiang XY, Yamane M, Lee M, Goodman S, Yang F (2015) Nanocoating for biomolecule delivery using layer-by-layer self-assembly. J Mat Chem B 3:8757–8770. https://doi.org/10.1039/C5TB00450KCrossRef

22.

Aggarwal N, Altgärde N, Svedhem S, Zhang K, Fischer S, Groth T (2014) Study on multilayer structures prepared from heparin and semi-synthetic cellulose sulfates as polyanions and their influence on cellular response. Colloids Surf B 116:93–103. https://doi.org/10.1016/j.colsurfb.2013.12.043CrossRef

23.

Hsu BB, Hagerman SR, Hammond PT (2016) Rapid and efficient sprayed multilayer films for controlled drug delivery. J Appl Polym Sci 133:43563. https://doi.org/10.1002/appCrossRef

24.

Zhuk A, Mirza R, Sukhishvili S (2011) Multiresponsive clay-containing layer-by-layer films. ACS Nano 5:8790–8799. https://doi.org/10.1021/nn202812aCrossRefPubMed

25.

Li Y-C, Schulz J, Mannen S, Delhom C, Condon B, Chang S et al (2012) Flame retardant behavior of polyelectrolyte-clay thin film assemblies on cotton fabric. ACS Nano 4:3325–3337. https://doi.org/10.1021/nn100467eCrossRef

26.

Priolo MA, Gamboa D, Holder KM, Grunlan JC (2010) Super gas barrier of transparent polymer-clay multilayer ultrathin films. Nano Lett 10:4970–4974. https://doi.org/10.1021/nl103047k

27.

Correa-Duarte MA, Kosiorek A, Kandulski W, Giersig M, Liz-MarzÃ¡n LM (2005) Layer-by-layer assembly of multiwall carbon nanotubes on spherical colloids. Chem Mat 17:3268–3272. https://doi.org/10.1021/cm047710e

28.

Qin S, Qin D, Ford WT, Herrera JE, Resasco DE (2004) Grafting of poly(4-vinylpyridine) to single-walled carbon nanotubes and assembly of multilayer films. Macromolecules 37:9963–9967. https://doi.org/10.1021/ma048692pCrossRef

29.

Salloum DS, Schlenoff JB (2004) Protein adsorption modalities on polyelectrolyte multilayers. Biomacromol 5:1089–1096. https://doi.org/10.1021/bm034522tCrossRef

30.

Jackler G, Czeslik C, Steitz R, Royer CA (2005) Spatial distribution of protein molecules adsorbed at a polyelectrolyte multilayer. Phys Rev E 71:041912. https://doi.org/10.1103/PhysRevE.71CrossRef

31.

Svensson O, Lindh L, Cárdenas M, Arnebrant T (2006) Layer-by-layer assembly of mucin and chitosan-Influence of surface properties, concentration and type of mucin. J Colloid Interface Sci 299:608–616. https://doi.org/10.1016/j.jcis.2006.02.027CrossRefPubMed

32.

Watanabe J, Shen H, Akashi M (2008) Polyelectrolyte droplets facilitate versatile layer-by-layer coating for protein loading interface. Acta Biomater 4:1255–1262. https://doi.org/10.1016/j.actbio.2008.03.009CrossRefPubMed

33.

Pedano ML, Martel L, Desbrieres J, Defrancq E, Dumy P, Coche-Guerente L et al (2004) Layer-by-layer deposition of Chitosan derivatives and DNA on gold surfaces for the development of biorecognition layers. Anal Lett 37:2235–2250. https://doi.org/10.1081/AL-200028021CrossRef

34.

He P, Bayachou M (2005) Layer-by-layer fabrication and characterization of DNA-wrapped single-walled carbon nanotube particles. Langmuir 21:6086–6092. https://doi.org/10.1021/la050581bCrossRefPubMed

35.

vander Straeten A, Lefèvre D, Demoustier-Champagne S, Dupont-Gillain C (2020) Protein-based polyelectrolyte multilayers. Adv Colloid Interface Sci 280:102161. https://doi.org/10.1016/j.cis.2020

36.

Lipton J, Weng G-M, Rӧhr JA, Wang H, Taylor AD (2020) Layer-by-layer assembly of two-dimensional materials: meticulous control on the nanoscale. Matter 2:1148–1165. https://doi.org/10.1016/j.matt.2020.03.012CrossRef

37.

Stockton WB, Rubner MF (1997) Molecular-level processing of conjugated polymers. 4. Layer-by-layer manipulation of polyaniline via hydrogen-bonding interactions. Macromolecules 30:2717–2725. https://doi.org/10.1021/ma9700486

38.

Wang LY, Wang ZQ, Zhang X, Shen JC (1997) A new approach for the fabrication of an alternating multilayer film of poly(4-vinylpyridine) and poly(acrylic acid) based on hydrogen bonding. Macromol Rapid Commun 18:509–514. https://doi.org/10.1002/marc.997.030180609CrossRef

39.

Shimazaki Y, Mitsuishi M, Ito S, Yamamoto M (1997) Preparation of the layer-by-layer deposited ultrathin film based on the charge-transfer interaction. Langmuir 13:1385–1387. https://doi.org/10.1021/la9609579CrossRef

40.

Anzai J, Kobayashi Y, Nakamura N, Nishimura M, Hoshi T (1999) Layer-by-layer construction of multilayer thin films composed of avidin and biotin-labeled Poly(amine)s. Langmuir 15:221–226. https://doi.org/10.1021/la980743mCrossRef

41.

Bourdillon C, Demaille C, Moiroux J, Savéant JM (1994) Step-by-Step immunological construction of a fully active multilayer enzyme electrode. J Am Chem Soc 116:10328–10329. https://doi.org/10.1021/ja00101a074CrossRef

42.

Xiong HM, Cheng MH, Zhou Z, Zhang X, Shen JC (1998) A new approach to the fabrication of a self-organizing film of heterostructured polymer/Cu₂S nanoparticles. Adv Mater 10:529–532. https://doi.org/10.1002/(SICI)521-4095(199805)10:7%3c529::AID-ADMA529%3e3.0.CO;2-ECrossRef

43.

Serizawa T, Hamada K-i, Kitayama T, Fujimoto N, Hatada K, Akashi M (2000) Stepwise stereocomplex assembly of stereoregular poly(methyl methacrylate)s on a substrate. J Am Chem Soc 122(9):1891–1899. https://doi.org/10.1021/ja9913535

44.

van der Heyden A, Wilczewski M, Labbé P, Auzély R (2006) Multilayer films based on host–guest interactions between biocompatible polymers. Chem Comm 3220–3222. https://doi.org/10.1039/B604672J

45.

Zhu J, Shim BS, Di Prima M, Kotov NA (2011) Transparent conductors from carbon nanotubes LBL-assembled with polymer dopant with π−π electron transfer. J Am Chem Soc 133:7450–7460. https://doi.org/10.1021/ja111687tCrossRefPubMedCentralPubMed

46.

Lvov Y, Ariga K, Ichinose I, Kunitake T (1995) Layer-by-layer architectures of concanavalin A by means of electrostatic and biospecific interactions. J Chem Soc Chem Comm 1995:2313–2314. https://doi.org/10.1039/C39950002313CrossRef

47.

Ichinose I, Kawakami T, Kunitake T (1998) Alternate molecular layers of metal oxides and hydroxyl polymers prepared by the surface sol-gel process. Adv Mat 10:535–539. https://doi.org/10.1002/(sici)521-4095(199805)10:7%3c535::Aid-adma535%3e3.0.Co;2-qCrossRef

48.

Such GK, Quinn JF, Quinn A, Tjipto E, Caruso F (2006) Assembly of ultrathin polymer multilayer films by click chemistry. J Am Chem Soc 128:9318–9319. https://doi.org/10.1021/ja063043+CrossRefPubMed

49.

An Q, Huang T, Shi F (2018) Covalent layer-by-layer films: chemistry, design, and multidisciplinary applications. Chem Soc Rev 47:5061–5098. https://doi.org/10.1039/C7CS00406KCrossRefPubMed

50.

Sukhorukov GB, Donath E, Lichtenfeld H, Knippel E, Knippel M, Budde A et al (1998) Layer-by-layer self assembly of polyelectrolytes on colloidal particles. Colloids Surf A 137:253–266. https://doi.org/10.1016/S0927-7757(98)00213-1 CrossRef

51.

Donath E, Sukhorukov GB, Caruso F, Davis SA, Möhwald H (1998) Novel hollow polymer shells by colloid-templated assembly of polyelectrolytes. Angew Chem Int Ed 37:2201–2205. https://doi.org/10.1002/(SICI)521-3773(19980904)37:16%3c2201::AID-ANIE2201%3e3.0.CO;2-ECrossRef

52.

Caruso F, Donath E, Möhwald H (1998) Influence of polyelectrolyte multilayer coatings on Förster resonance energy transfer between 6-carboxyfluorescein and rhodamine B-labeled particles in aqueous solution. J Phys Chem B 102:2011–2016. https://doi.org/10.1021/jp980198yCrossRef

53.

Guzmán E, Ritacco H, Ortega F, Svitova T, Radke CJ, Rubio RG (2009) Adsorption kinetics and mechanical properties of ultrathin polyelectrolyte multilayers: liquid-supported versus solid-supported films. J Phys Chem B 113:7128–7137. https://doi.org/10.1021/jp811178aCrossRefPubMed

54.

Ferri JK, Dong W-F, Miller R, Mohwald H (2006) Elastic moduli of asymmetric ultrathin free-standing polyelectrolyte nanocomposites. Macromolecules 39:1532–1537. https://doi.org/10.1021/ma0516485CrossRef

55.

Ferri JK, Dong W-F, Miller R (2005) Ultrathin free-standing polyelectrolyte nanocomposites: a novel method for preparation and characterization of assembly dynamics. J Phys Chem B 109:14764–14768. https://doi.org/10.1021/jp052672nCrossRefPubMed

56.

Shchukina EM, Shchukin DG (2012) Layer-by-layer coated emulsion microparticles as storage and delivery tool. Curr Opin Colloid Interface Sci 17:281–289. https://doi.org/10.1016/j.cocis.2012.06.003CrossRef

57.

Cuomo F, Lopez F, Miguel MG, Lindman B (2010) Vesicle-templated layer-by-layer assembly for the production of nanocapsules. Langmuir 26:10555–10560. https://doi.org/10.1021/la100584bCrossRefPubMed

58.

Kozlovskaya V, Zavgorodnya O, Chen Y, Ellis K, Tse HM, Cui W et al (2012) Ultrathin polymeric coatings based on hydrogen-bonded polyphenol for protection of pancreatic islet cells. Adv Funct Mat 22:3389–3398. https://doi.org/10.1002/adfm.201200138CrossRef

59.

Sukhishvili SA, Granick S (2002) Layered, erasable polymer multilayers formed by hydrogen-bonded sequential self-assembly. Macromolecules 35:301–310. https://doi.org/10.1021/ma011346cCrossRef

60.

Hiller J, Mendelsohn JD, Rubner MF (2002) Reversibly erasable nanoporous anti-reflection coatings from polyelectrolyte multilayers. Nat Mat 1:59–63. https://doi.org/10.1038/nmat719CrossRef

61.

Denkbas EB, Ottenbrite RM (2006) Perspectives on: Chitosan drug delivery systems based on their geometries. J Bioact Compat Polym 21:351–368. https://doi.org/10.1177/0883911506066930CrossRef

62.

Städler B, Chandrawati R, Goldie K, Caruso F (2009) Capsosomes: subcompartmentalizing polyelectrolyte capsules using liposomes. Langmuir 25:6725–6732. https://doi.org/10.1021/la900213aCrossRefPubMed

63.

Städler B, Chandrawati R, Price AD, Chong S-F, Breheney K, Postma A et al (2009) A microreactor with thousands of subcompartments: enzyme-loaded liposomes within polymer capsules. Angew Chem Int Ed 48:4359–4362. https://doi.org/10.1002/anie.200900386CrossRef

64.

Chandrawati R, Hosta-Rigau L, Vanderstraaten D, Lokuliyana SA, Städler B, Albericio F et al (2010) Engineering advanced capsosomes: maximizing the number of subcompartments, cargo retention, and temperature-triggered reaction. ACS Nano 4:1351–1361. https://doi.org/10.1021/nn901843j

65.

Hosta-Rigau L, Städler B, Yan Y, Nice EC, Heath JK, Albericio F et al (2010) Capsosomes with multilayered subcompartments: assembly and loading with hydrophobic Cargo. Adv Funct Mat 20:59–66. https://doi.org/10.1002/adfm.200901297CrossRef

66.

Vikulina AS, Skirtach AG, Volodkin D (2019) Hybrids of polymer multilayers, lipids, and nanoparticles: mimicking the cellular microenvironment. Langmuir 35:8565–8573. https://doi.org/10.1021/acs.langmuir.8b04328CrossRefPubMed

67.

Johnston APR, Cortez C, Angelatos AS, Caruso F (2006) Layer-by-layer engineered capsules and their applications. Curr Opin Colloid Interface Sci 11:203–209. https://doi.org/10.1016/j.cocis.2006.05.001CrossRef

68.

Tong W, Song X, Gao C (2012) Layer-by-layer assembly of microcapsules and their biomedical applications. Chem Soc Rev 41:6103–6124. https://doi.org/10.1039/C2CS35088BCrossRefPubMed

69.

Lvov Y, Essler F, Decher G (1993) Combination of polycation/polyanion self-assembly and Langmuir-Blodgett transfer for the construction of superlattice films. J Phys Chem 97:13773–13777CrossRef

70.

Ariga K, Lvov Y, Kunitake T (1997) Assembling alternate dye-polyion molecular films by electrostatic layer-by-layer adsorption. J Am Chem Soc 119:2224–2231. https://doi.org/10.1021/ja963442cCrossRef

71.

Richardson JJ, Cui J, Björnmalm M, Braunger JA, Ejima H, Caruso F (2016) Innovation in layer-by-layer assembly. Chem Rev 116:14828–14867CrossRefPubMed

72.

Hammond PT (2011) Engineering materials layer-by-layer: Challenges and opportunities in multilayer assembly. AIChE J 57:2928–2940CrossRef

73.

Xiang Y, Lu S, Jiang SP (2012) Layer-by-layer self-assembly in the development of electrochemical energy conversion and storage devices from fuel cells to supercapacitors. Chem Soc Rev 41:7291–7321CrossRefPubMed

74.

Michel M, Toniazzo V, Ruch D, Ball V (2012) Deposition mechanisms in layer-by-layer or step-by-step deposition methods: from elastic and impermeable films to soft membranes with ion exchange properties. ISRN Mat Sci 2012:701695

75.

Iler RK (1966) Multilayers of colloidal particles. J Colloid Interface Sci 21:569–594CrossRef

76.

Mateos-Maroto A, Abelenda-Núñez I, Ortega F, Rubio RG, Guzmán E (2021) Polyelectrolyte multilayers on soft colloidal nanosurfaces: a new life for the layer-by-layer method. Polymers 13:1221PubMedCentralCrossRefPubMed

77.

Shim BS, Podsiadlo P, Lilly DG, Agarwal A, Lee J, Tang Z et al (2007) Nanostructured thin films made by Dewetting method of layer-by-layer assembly. Nano Lett 7:3266–3273CrossRefPubMed

78.

Richardson JJ, Björnmalm M, Caruso F (2015) Technology-driven layer-by-layer assembly of nanofilms. Science 348

79.

Fu Y, Li S-J, Xu J, Yang M, Zhang J-D, Jiao Y-H et al (2011) Facile and efficient approach to speed up layer-by-layer assembly: dipping in agitated solutions. Langmuir 27:672–677CrossRefPubMed

80.

Li Y, Wang X, Sun J (2012) Layer-by-layer assembly for rapid fabrication of thick polymeric films. Chem Soc Rev 41:5998–6009CrossRefPubMed

81.

Lee S-S, Hong J-D, Kim CH, Kim K, Koo JP, Lee K-B (2001) Layer-by-layer deposited multilayer assemblies of ionene-type polyelectrolytes based on the spin-coating method. Macromolecules 34:5358–5360CrossRef

82.

Espinosa-Dzib A, Chen J, Zavgorodnya O, Kozlovskaya V, Liang X, Kharlampieva E (2015) Tuning assembly and enzymatic degradation of silk/poly(N-vinylcaprolactam) multilayers via molecular weight and hydrophobicity. Soft Matter 11:5133–5145CrossRefPubMed

83.

Izquierdo A, Ono SS, Voegel JC, Schaaf P, Decher G (2005) Dipping versus spraying: exploring the deposition conditions for speeding up layer-by-layer assembly. Langmuir 21:7558–7567CrossRefPubMed

84.

Kolansinska M, Krastev R, Gutberlet T, Warszynski P (2009) Layer-by-layer deposition of polyelectrolytes. Dipping versus spraying. Langmuir 25:1224–1232

85.

Guzmán E, Rubio RG, Ortega F (2020) A closer physico-chemical look to the layer-by-layer electrostatic self-assembly of polyelectrolyte multilayers. Adv Colloid Interface Sci 282:102197

86.

Kiel M, Mitzscherling S, Leitenberger W, Santer S, Tiersch B, Sievers TK et al (2010) Structural characterization of a spin-assisted colloid-polyelectrolyte assembly: stratified multilayer thin films. Langmuir 26:18499–18502. https://doi.org/10.1021/la103609fCrossRefPubMed

87.

Cho J, Char K, Hong J-D, Lee K-B (2001) Fabrication of highly ordered multilayer films using a spin self-assembly method. Adv Mat 13:1076–1078. https://doi.org/10.1002/521-4095(200107)13:14%3c1076::AID-ADMA1076%3e3.0.CO;2-MCrossRef

88.

Ma L, Cheng M, Jia G, Wang Y, An Q, Zeng X et al (2012) Layer-by-layer self-assembly under high gravity field. Langmuir 28:9849–9856. https://doi.org/10.1021/la301553wCrossRefPubMed

89.

Schlenoff JB, Dubas ST, Farhat T (2000) Sprayed polyelectrolyte multilayers. Langmuir 16:9968–9969. https://doi.org/10.1021/la001312iCrossRef

90.

Elosua C, Lopez-Torres D, Hernaez M, Matias IR, Arregui FJ (2013) Comparative study of layer-by-layer deposition techniques for poly(sodium phosphate) and poly(allylamine hydrochloride). Nanosc Res Lett 8:539. https://doi.org/10.1186/556-276X-8-539

91.

Félix O, Zheng Z, Cousin F, Decher G (2009) Are sprayed LbL-films stratified? A first assessment of the nanostructure of spray-assembled multilayers by neutron reflectometry. C R Chim 12:225–234. https://doi.org/10.1016/j.crci.2008.09.009CrossRef

92.

Dierendonck M, De Koker S, De Rycke R, De Geest BG (2014) Just spray it—LbL assembly enters a new age. Soft Matter 10:804–807. https://doi.org/10.1039/C3SM52202DCrossRefPubMed

93.

Schaaf P, Voegel J-C, Jierry L, Boulmedais F (2012) Spray-assisted polyelectrolyte multilayer buildup: from step-by-step to single-step polyelectrolyte film constructions. Adv Mat 24:1001–1016. https://doi.org/10.1002/adma.201104227CrossRef

94.

Hammond PT (2012) Building biomedical materials layer-by-layer. Mater Today 15:196–206. https://doi.org/10.1016/S369-7021(12)70090-1CrossRef

95.

Ariga K, Ahn E, Park M, Kim B-S (2019) Layer-by-layer assembly: recent progress from layered assemblies to layered nanoarchitectonics. Chem Asian J 14:2553–2566. https://doi.org/10.1002/asia.201900627CrossRefPubMed

96.

Sui Z, Salloum D, Schlenoff JB (2003) Effect of molecular weight on the construction of polyelectrolyte multilayers: stripping versus sticking. Langmuir 19:2491–2495. https://doi.org/10.1021/la026531dCrossRef

97.

Michel M, Izquierdo A, Decher G, Voegel JC, Schaaf P, Ball V (2005) Layer by layer self-assembled polyelectrolyte multilayers with embedded phospholipid vesicles obtained by spraying: integrity of the vesicles. Langmuir 21:7854–7859. https://doi.org/10.1021/la050497wCrossRefPubMed

98.

Lefort M, Boulmedais F, Jierry L, Gonthier E, Voegel JC, Hemmerl J et al (2011) Simultaneous spray coating of interacting species: general rules governing the poly(styrene sulfonate)/poly(allylamine) system. Langmuir 27:4653–4660CrossRefPubMed

99.

Merrill MH, Sun CT (2009) Fast, simple and efficient assembly of nanolayered materials and devices. Nanotechnology 20:075606. https://doi.org/10.1088/0957-4484/20/7/CrossRefPubMed

100.

Mulhearn WD, Kim DD, Gu Y, Lee D (2012) Facilitated transport enhances spray layer-by-layer assembly of oppositely charged nanoparticles. Soft Matter 8:10419–10427. https://doi.org/10.1039/C2SM26456KCrossRef

101.

Alongi J, Carosio F, Frache A, Malucelli G (2013) Layer by Layer coatings assembled through dipping, vertical or horizontal spray for cotton flame retardancy. Carbohydr Polymers 92:114–119. https://doi.org/10.1016/j.carbpol.2012.08.086CrossRef

102.

Lefort M, Popa G, Seyrek E, Szamocki R, Felix O, Hemmerlé J et al (2010) Spray-on organic/inorganic films: a general method for the formation of functional nano- to microscale coatings. Angew Chem Int Ed 49:10110–10113. https://doi.org/10.1002/anie.201002729CrossRef

103.

Hong X, Li J, Wang M, Xu J, Guo W, Li J et al (2004) Fabrication of magnetic luminescent nanocomposites by a layer-by-layer self-assembly approach. Chem Mat 16:4022–4027. https://doi.org/10.1021/cm049422oCrossRef

104.

Sun J, Gao M, Feldmann J (2001) Electric field directed layer-by-layer assembly of highly fluorescent CdTe nanoparticles. J Nanosci Nanotech 1:133–136. https://doi.org/10.1166/jnn.2001.029CrossRef

105.

Shi L, Lu Y, Sun J, Zhang J, Sun C, Liu J et al (2003) Site-Selective lateral multilayer assembly of bienzyme with polyelectrolyte on ITO electrode based on electric field-induced directly layer-by-layer deposition. Biomacromol 4:1161–1167. https://doi.org/10.1021/bm030003eCrossRef

106.

Richardson JJ, Ejima H, Lörcher SL, Liang K, Senn P, Cui J et al (2013) Preparation of nano- and microcapsules by electrophoretic polymer assembly. Angew Chem Int Ed 52:6455–6458. https://doi.org/10.1002/anie.201302092CrossRef

107.

Van Tassel PR (2012) Polyelectrolyte adsorption and layer-by-layer assembly: electrochemical control. Curr Opin Colloid Interface Sci 17:106–113. https://doi.org/10.1016/j.cocis.2011.08.008CrossRef

108.

Richardson JJ, Björnmalm M, Caruso F (2015) Technology-driven layer-by-layer assembly of nanofilms. Science 348:aaa2491. https://doi.org/10.1126/science.aaa2491

109.

Ko YH, Kim YH, Park J, Nam KT, Park JH, Yoo PJ (2011) Electric-field-assisted layer-by-layer assembly of weakly charged polyelectrolyte multilayers. Macromolecules 44:2866–2872. https://doi.org/10.1021/ma102112aCrossRef

110.

Wang Z, Zhang X, Gu J, Yang H, Nie J, Ma G (2014) Electrodeposition of alginate/chitosan layer-by-layer composite coatings on titanium substrates. Carbohydr Polymers 103:38–45. https://doi.org/10.1016/j.carbpol.2013.12.007CrossRef

111.

Mu B, Liu P, Du P, Dong Y, Lu C (2011) Magnetic-targeted pH-responsive drug delivery system via layer-by-layer self-assembly of polyelectrolytes onto drug-containing emulsion droplets and its controlled release. J Polymer Sci A Polymer Chem 49:1969–1976. https://doi.org/10.1002/pola.24623CrossRef

112.

Dey S, Mohanta K, Pal AJ (2010) Magnetic-field-assisted layer-by-layer electrostatic assembly of ferromagnetic nanoparticles. Langmuir 26:9627–9631. https://doi.org/10.1021/la101132zCrossRefPubMed

113.

Caruso F, Caruso RA, Möhwald H (1998) Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science 282:1111–1114CrossRefPubMed

114.

Bertrand P, Jonas A, Laschewsky A, Legras R (2000) Ultrathin polymer coatings by complexation of polyelectrolytes at interfaces: suitable materials, structure and properties. Macromol Rapid Commun 21:319–348CrossRef

115.

Yan Y, Björnmalm M, Caruso F (2014) Assembly of layer-by-layer particles and their interactions with biological systems. Chem Mat 26:452–460CrossRef

116.

Donath E, Walther D, Shilov VN, Knippel E, Budde A, Lowack K et al (1997) Nonlinear hairy layer theory of electrophoretic fingerprinting applied to consecutive layer by layer polyelectrolyte adsorption onto charged polystyrene latex particles. Langmuir 13:5294–5305CrossRef

117.

Sukhorukov GB, Donath E, Davis S, Lichtenfeld H, Caruso F, Popov VI et al (1998) Stepwise polyelectrolyte assembly on particle surfaces: a novel approach to colloid design. Polym Adv Technol 9:759–767CrossRef

118.

Caruso F, Lichtenfeld H, Giersig M, Möhwald H (1998) Electrostatic self-assembly of silica nanoparticle−polyelectrolyte multilayers on polystyrene latex particles. J Am Chem Soc 120(33):8523–8524CrossRef

119.

Bagaria HG, Wong MS (2011) Polyamine-salt aggregate assembly of capsules as responsive drug delivery vehicles. J Mat Chem 21:9454–9466CrossRef

120.

Tong W, Gao C (2008) Multilayer microcapsules with tailored structures for bio-related applications. J Mat Chem 18:3799–3812CrossRef

121.

Voigt A, Lichtenfeld H, Sukhorukov GB, Zastrow H, Donath E, Baumler H et al (1999) Membrane filtration for microencapsulation and microcapsules fabrication by layer-by-layer polyelectrolyte adsorption. Ind Eng Chem Res 38:4037–4043CrossRef

122.

Nagaraja AT, You Y-H, Choi J-W, Hwang J-H, Meissner KE, McShane MJ (2016) Layer-by-layer modification of high surface curvature nanoparticles with weak polyelectrolytes using a multiphase solvent precipitation process. J Colloid Interface Sci 466:432–441CrossRefPubMed

123.

Elizarova IS, Luckham PF (2016) Fabrication of polyelectrolyte multilayered nano-capsules using a continuous layer-by-layer approach. J Colloid Interface Sci 470:92–99CrossRefPubMed

124.

125.

Wilson R, Spiller DG, Prior IA, Bhatt R, Hutchinson A (2007) Magnetic microspheres encoded with photoluminescent quantum dots for multiplexed detection. J Mat Chem 17:4400–4406CrossRef

126.

Szczepanowicz K, Hoel HJ, Szyk-Warszynska L, Bielańska E, Bouzga AM, Gaudernack G et al (2010) Formation of biocompatible nanocapsules with emulsion core and Pegylated shell by polyelectrolyte multilayer adsorption. Langmuir 26:12592–12597. https://doi.org/10.1021/la102061sCrossRefPubMed

127.

Hoogeveen NG, Cohen Stuart MA, Fleer GJ, Böhmer MR (1996) Formation and stability of multilayers of polyelectrolytes. Langmuir 12:3675–3681CrossRef

128.

Bantchev G, Lu Z, Lvov Y (2009) Layer-by-layer nanoshell assembly on colloids through simplified washless process. J Nanosci Nanotechnol 9:396–403CrossRefPubMed

129.

Szczepanowicz K, Dronka-Góra D, Para G, Warszyński P (2010) Encapsulation of liquid cores by layer-by-layer adsorption of polyelectrolytes. J Microencapsul 27:198–204CrossRefPubMed

130.

Grigoriev DO, Bukreeva T, Möhwald H, Shchukin DG (2008) New method for fabrication of loaded micro- and nanocontainers: emulsion encapsulation by polyelectrolyte layer-by-layer deposition on the liquid core. Langmuir 24:999–1004CrossRefPubMed

131.

Thanasukarn P, Pongsawatmanit R, McClements D (2006) Utilization of layer-by-layer interfacial deposition technique to improve freeze–thaw stability of oil-in-water emulsions. Food Res Int 39:721–729CrossRef

132.

Li J, Stöver HDH (2010) Pickering emulsion templated layer-by-layer assembly for making microcapsules. Langmuir 26:15554–15560CrossRefPubMed

133.

Rossier-Miranda FJ, Schroën K, Boom R (2012) Microcapsule production by an hybrid colloidosome-layer-by-layer technique. Food Hydrocolloids 27:119–125CrossRef

134.

Liu H, Gu X, Hu M, Hu Y, Wang C (2014) Facile fabrication of nanocomposite microcapsules by combining layer-by-layer self-assembly and Pickering emulsion templating. RSC Adv 4:16751–16758CrossRef

135.

Guzmán E, Ruano M, Ortega F, Rubio RG (2014) Stratified interpolyelectrolyte complexes: fabrication, structure and properties. In: Visakh PM, Bayraktar O, Picó GA (eds) Polyelectrolytes. Springer International Publishing, Cham (Switzerland), pp 299–347

136.

Richardson JJ, Liang K, Kempe K, Ejima H, Cui J, Caruso F (2013) Immersive polymer assembly on immobilized particles for automated capsule preparation. Adv Mat 25:6874–6878CrossRef

137.

Wang Y, Zhou J, Guo X, Hu Q, Qin C, Liu H et al (2017) Layer-by-layer assembled biopolymer microcapsule with separate layer cavities generated by gas-liquid microfluidic approach. Mater Sci Eng C Mater Biol Appl 81:13–19CrossRefPubMed

138.

Wang Y, Liu Y, Cheng Y, Kim E, Rubloff GW, Bentley WE et al (2011) Coupling electrodeposition with layer-by-layer assembly to address proteins within microfluidic channels. Adv Mater 23:5817–5821CrossRefPubMed

139.

Lee UN, Day JH, Haack AJ, Bretherton RC, Lu W, DeForest CA et al (2020) Layer-by-layer fabrication of 3D hydrogel structures using open microfluidics. Lab Chip 20:525–536PubMedCentralCrossRefPubMed

140.

Alkekhia D, Hammond PT, Shukla A (2020) Layer-by-layer biomaterials for drug delivery. Ann Rev Biomed Eng. 22:1–24CrossRef

141.

Björnmalm M, Yan Y, Caruso F (2014) Engineering and evaluating drug delivery particles in microfluidic devices. J Control Rel 190:139–149CrossRef

142.

Priest C, Quinn A, Postma A, Zelikin AN, Ralston J, Caruso F (2008) Microfluidic polymer multilayer adsorption on liquid crystal droplets for microcapsule synthesis. Lab Chip 8:2182–2187CrossRefPubMed

143.

Matosevic S, Paegel BM (2013) Layer-by-layer cell membrane assembly. Nat Chem 5:958–963PubMedCentralCrossRefPubMed

144.

Mets JM, Wilson JT, Cui W, Chaikof EL (2013) An automated process for layer-by-layer assembly of polyelectrolyte multilayer thin films on viable cell aggregates. Adv Healthc Mater 2:266–270CrossRefPubMed

145.

Kantak C, Beyer S, Yobas L, Bansal T, Trau D (2011) A ‘microfluidic pinball’ for on-chip generation of layer-by-layer polyelectrolyte microcapsules. Lab Chip 11:1030–1035CrossRefPubMed

146.

Raman N, Lee M-R, Palecek SP, Lynn DM (2014) Polymer multilayers loaded with antifungal β-peptides kill planktonic Candida albicans and reduce formation of fungal biofilms on the surfaces of flexible catheter tubes. J Control Release 191:54–62PubMedCentralCrossRefPubMed

147.

Madaboosi N, Uhlig K, Jäger MS, Möhwald H, Duschl C, Volodkin DV (2012) Microfluidics as a tool to understand the build-up mechanism of exponential-like growing films. Macromol Rapid Comm 33:1775–1779CrossRef

148.

Kim H-J, Lee K, Kumar S, Kim J (2005) Dynamic sequential layer-by-layer deposition method for fast and region-selective multilayer thin film fabrication. Langmuir 18:8532–8538CrossRef

149.

Richardson JJ, Teng D, Björnmalm M, Gunawan ST, Guo J, Cui J et al (2014) Fluidized bed layer-by-layer microcapsule formation. Langmuir 30:10028–10034CrossRefPubMed

150.

Noi KF, Roozmand A, Björnmalm M, Richardson JJ, Franks GV, Caruso F (2015) Assembly-controlled permeability of layer-by-layer polymeric microcapsules using a tapered fluidized bed. ACS Appl Mater Interfaces 7(50):27940–27947CrossRefPubMed

151.

Johansson E, Blomberg E, LingstroÌˆm R, Wägberg L (2009) Adhesive interaction between polyelectrolyte multilayers of polyallylamine hydrochloride and polyacrylic acid studied using atomic force microscopy and surface force apparatus. Langmuir 25:2887–2894CrossRefPubMed

152.

Guzmán E, Maestro A, Llamas S, Álvarez-Rodríguez J, Ortega F, Maroto-Valiente Á et al (2016) 3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate). Beilstein J Nanotech 7:197–208CrossRef

153.

Guzmán E, Ritacco H, Rubio JEF, Rubio RG, Ortega F (2009) Salt-induced changes in the growth of polyelectrolyte layers of poly(diallyl-dimethylammonium chloride) and poly(4-styrene sulfonate of sodium). Soft Matter 5:2130–2142CrossRef

154.

Schlenoff JB, Dubas ST (2001) Mechanism of polyelectrolyte multilayer growth: charge overcompensation and distribution. Macromolecules 34:592–598CrossRef

155.

Dubas ST, Schlenoff JB (1999) Factors controlling the growth of polyelectrolyte multilayers. Macromolecules 32:8153–8160CrossRef

156.

Picart C, Lavalle P, Hubert P, Cuisinier FJG, Decher G, Schaaf P et al (2001) Buildup mechanism for poly(L-lysine)/hyaluronic acid films onto a solid surface. Langmuir 17:7414–7424CrossRef

157.

Lavalle P, Gergely C, Cuisinier FJG, Decher G, Schaaf P, Voegel JC et al (2002) Comparison of the structure of polyelectrolyte multilayer films exhibiting a linear and an exponential growth regime: an in situ atomic force microscopy study. Macromolecules 35:4458–4465CrossRef

158.

Schneider A, Richert L, Francius G, Voegel J-C, Picart C (2007) Elasticity, biodegradability and cell adhesive properties of chitosan/hyaluronan multilayer films. Biomed Mater 2:S45–S51CrossRefPubMed

159.

Cini N, Tulun T, Decher G, Ball V (2010) Step-by-step assembly of self-patterning polyelectrolyte films violating (almost) all rules of layer-by-layer deposition. J Am Chem Soc 132 8264–8265

160.

Cini N, Tulun T, Blanck C, Toniazzo V, Ruch D, Decher G et al (2012) Slow complexation dynamics between linear short polyphosphates and polyallylamines: analogies with ‘“layer-by-layer”’ deposition. Phys Chem Chem Phys 14:3048–3056CrossRefPubMed

161.

Elbert DL, Herbert CB, Hubbel JA (1999) Thin polymer layers formed by polyelectrolyte multilayer techniques on biological surfaces. Langmuir 15:5355–5362CrossRef

162.

Subbotin AV, Semenov AN (2021) The structure of polyelectrolyte complex coacervates and multilayers. Macromolecules 54:1314–1328CrossRef

163.

Guzmán E, Fernández-Peña L, Ortega F, Rubio RG (2020) Equilibrium and kinetically-trapped aggregates in polyelectrolyte-oppositely charged surfactant mixtures. Curr Opin Colloid Interface Sci 48:91–108CrossRef

164.

Llamas S, Guzmán E, Baghdadli N, Ortega F, Cazeneuve C, Rubio RG et al (2016) Adsorption of poly(diallyldimethylammonium chloride)—sodium methyl-cocoyl-taurate complexes onto solid surfaces. Colloids Surf A 505:150–157CrossRef

165.

Tang K, Besseling NAM (2016) Formation of polyelectrolyte multilayers: ionic strengths and growth regimes. Soft Matter 12:1032–1040CrossRefPubMed

166.

Xu L, Pristinski D, Zhuk A, Stoddart C, Ankner JF, Sukhishvili SA (2012) Linear versus exponential growth of weak polyelectrolyte multilayers: correlation with polyelectrolyte complexes. Macromolecules 45:3892–3901CrossRef

167.

Lavalle P, Picart C, Mutterer J, Gergely C, Reiss H, Voegel J-C et al (2003) Modeling the buildup of polyelectrolyte multilayer films having exponential growth. J Phys Chem B 108:635–648CrossRef

168.

Picart C, Mutterer J, Richert L, Luo Y, Prestwich GD, Schaaf P et al (2002) Molecular basis for the explanation of the exponential growth of polyelectrolyte multilayers. Proc Nat Acad Sci USA 99:12531–12535PubMedCentralCrossRefPubMed

169.

Jourdainne L, Lecuyer S, Arntz Y, Picart C, Schaaf P, Senger B, et al (2008) Dynamics of poly(l-lysine) in hyaluronic acid/poly(l-lysine) multilayer films studied by fluorescence recovery after pattern photobleaching. Langmuir 24:7842–7847

170.

Sustr D, Hlaváček A, Duschl C, Volodkin D (2018) Multi-fractional analysis of molecular diffusion in polymer multilayers by FRAP: a new simulation-based approach. J Phys Chem B 122(3):1323–1333CrossRefPubMed

171.

Hoda N, Larson RG (2009) Modeling the buildup of exponentially growing polyelectrolyte multilayer films. J Phys Chem B 113:4232–4241CrossRefPubMed

172.

Guzmán E, Ortega F, Rubio RG (2016) Comment on “Formation of polyelectrolyte multilayers: ionic strengths and growth regimes” by K Tang and A. M. Besseling. Soft Matter 12:1032 (12:8460–8463)

173.

Yuan W, Weng G-M, Lipton J, Li CM, Van Tassel PR, Taylor AD (2020) Weak polyelectrolyte-based multilayers via layer-by-layer assembly: approaches, properties, and applications. Adv Colloid Interface Sci 282:102200

174.

Guzmán E, Ritacco HA, Ortega F, Rubio RG (2012) Growth of polyelectrolyte layers formed by poly(4-styrenesulfonate sodium salt) and two different polycations: new insights from study of adsorption kinetics. J Phys Chem C 116:15474–15483CrossRef

175.

Guzmán E, Ritacco H, Ortega F, Rubio RG (2011) Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers. Colloids Surf A 384:274–281CrossRef

176.

McAloney RA, Sinyor M, Dudnik V, Goh MC (2001) Atomic force microscopy studies of salt effects on polyelectrolyte multilayer film morphology. Langmuir 17:6655–6663CrossRef

177.

Haynie DT, Cho E, Waduge P (2011) “In and out diffusion” hypothesis of exponential multilayer film buildup revisited. Langmuir 27:5700–5704CrossRefPubMed

178.

Hernandez-Montelongo J, Nascimento VF, Hernández-Montelongo R, Beppu MM, Cotta MA (2020) Fractal analysis of the formation process and morphologies of hyaluronan/chitosan nanofilms in layer-by-layer assembly. Polymer 191:122283

179.

Naas C, Scheler U, Lappan U (2021) Influence of pH on the growth and the local dynamics of polyelectrolyte multilayers. Macromolecules 54:1043–1051CrossRef

180.

Selin V, Ankner JF, Sukhishvili SA (2017) Nonlinear layer-by-layer films: effects of chain diffusivity on film structure and swelling. Macromolecules 50(16):6192–6201CrossRef

181.

Joanny JF (1999) Polyelectrolyte adsorption and charge inversion. Eur Phys J B 117–122

182.

Berndt P, Kurihara K, Kunitake T (1992) Adsorption of poly(styrenesulfonate) onto an ammonium monolayer on mica: a surface forces study. Langmuir 8:2486–2490CrossRef

183.

Schwarz S, Eichhorn KJ, Wischerhoff E, Laschewsky A (1999) Polyelectrolyte adsorption onto planar surfaces: a study by streaming potential and ellipsometry measurements. Colloids Surf A 159:491–501CrossRef

184.

Ringwald C, Ball V (2015) Shear induced changes in the streaming potential of polyelectrolyte multilayer films. Colloids Surf A 464:41–45CrossRef

185.

Ladam G, Schaad P, Voegel JC, Schaaf P, Decher G, Cuisinier F (2000) In situ determination of the structural properties of initially deposited polyelectrolyte multilayers. Langmuir 16:1249–1255CrossRef

186.

Adamczyk Z, Zembala M, Kolasińska M, Warszyński P (2007) Characterization of polyelectrolyte multilayers on mica and oxidized titanium by streaming potential and wetting angle measurements. Colloids Surf A 302:455–460CrossRef

187.

Ferriz-Mañas M, Schlenoff JB (2014) Zeta potential of polyelectrolyte multilayers using the spinning disk method. Langmuir 30:8776–8783CrossRefPubMed

188.

Fares HM, Schlenoff JB (2017) Equilibrium overcompensation in polyelectrolyte complexes. Macromolecules 50:3968–3978CrossRef

189.

von Klitzing R, Moehwald H (1995) Proton concentration profile in ultrathin polyelectrolyte films. Langmuir 11:3554–3559CrossRef

190.

Fernández-Peña L, Guzmán E, Ortega F, Bureau L, Leonforte F, Velasco D et al (2021) Physico-chemical study of polymer mixtures formed by a polycation and a zwitterionic copolymer in aqueous solution and upon adsorption onto negatively charged surfaces. Polymer 217:123442

191.

Rmaile HH, Schlenoff JB (2002) “Internal pKa’s” in polyelectrolyte multilayers: coupling protons and salt. Langmuir 18:8263–8265CrossRef

192.

Lourenço JMC, Ribeiro PA, Botelho do Rego AM, Raposo M (2007) Counterions in layer-by-layer films—influence of the drying process. J Colloid Interface Sci. 313:26–33

193.

Lourenço JMC, Ribeiro PA, Botelho do Rego AM, Braz Fernandes FM, Moutinho AMC, Raposo M (2004) Counterions in poly(allylamine hydrochloride) and poly(styrene sulfonate) layer-by-layer films. Langmuir 20:8103–8109

194.

Llamas S, Guzmán E, Ortega F, Rubio RG (2020) Adsorption of mixtures of a Pegylated lipid with anionic and Zwitterionic surfactants at solid/liquid. Colloids Interfaces 4:47CrossRef

195.

Ghostine RA, Markarian MZ, Schlenoff JB (2013) Asymmetric growth in polyelectrolyte multilayers. J Am Chem Soc 135:7636–7646CrossRefPubMed

196.

Lehaf AM, Hariri HH, Schlenoff JB (2012) Homogeneity, modulus, and viscoelasticity of polyelectrolyte multilayers by nanoindentation: refining the buildup mechanism. Langmuir 28:6348–6355PubMedCentralCrossRefPubMed

197.

Ghostine RA, Jisr RM, Lehaf A, Schlenoff JB (2013) Roughness and salt annealing in a polyelectrolyte multilayer. Langmuir 11,742−11,750

198.

Volodkin D, von Klitzing R (2014) Competing mechanisms in polyelectrolyte multilayer formation and swelling: Polycation–polyanion pairing versus polyelectrolyte–ion pairing. Curr Opin Colloid Interface Sci 19:25–31

199.

Guzmán E, Ortega F, Prolongo MG, Starov VM, Rubio RG (2011) Influence of the molecular architecture on the adsorption onto solid surfaces: comb-like polymers. Phys Chem Chem Phys 13:16416–16423CrossRefPubMed

200.

Maestro A, Jones D, Sánchez de Rojas Candela C, Guzman E, Duits MHG, Cicuta P (2018) Tuning interfacial properties and processes by controlling the rheology and structure of poly(n-isopropylacrylamide) particles at air/water interfaces. Langmuir 34:7067–7076

201.

Llamas S, Mendoza AJ, Guzmán E, Ortega F, Rubio RG (2013) Salt effects on the air/solution interfacial properties of PEO-containing copolymers: equilibrium, adsorption kinetics and surface rheological behavior. J Colloid Interface Sci 400:49–58CrossRefPubMed

202.

Guzmán E, Ortega F, Baghdadli N, Cazeneuve C, Luengo GS, Rubio RG (2011) Adsorption of conditioning polymers on solid substrates with different charge density. ACS Appl Mat Interfaces. 3:3181–3188CrossRef

203.

Guzmán E, Ortega F, Baghdadli N, Luengo GS, Rubio RG (2011) Effect of the molecular structure on the adsorption of conditioning polyelectrolytes on solid substrates. Colloids Surf A 375:209–218CrossRef

204.

Kotov NA (1999) Layer-by-layer self-assembly: the contribution of hydrophobic interactions. Nanostr Mat 12:789–796CrossRef

205.

Guzmán E, Ritacco H, Rubio JEF, Rubio RG, Ortega F (2009) Salt-induced changes in the growth of polyelectrolyte layers of poly(diallyldimethylammoniumchloride) and poly(4-styrene sulfonate of sodium). Soft Matter 5:2130–2142. https://doi.org/10.1039/B901193ECrossRef

206.

Fares HM, Schlenoff JB (2017) Equilibrium Overcompensation in Polyelectrolyte Complexes. Macromolecules 50(10):3968–3978CrossRef

207.

Panchagnula V, Jeon J, Dobrynin AV (2004) Molecular dynamics simulations of electrostatic layer-by-layer self-assembly. Phys Rev Lett 93(3):037801. https://doi.org/10.1103/PhysRevLett.93CrossRefPubMed

208.

Lösche M, Schmitt J, Decher G, Bouwman WG, Kjaer K (1998) Detailed structure of molecularly thin polyelectrolyte multilayer films on solid substrates as revealed by neutron reflectometry. Macromolecules 31:8893–8906. https://doi.org/10.1021/ma980910pCrossRef

209.

Schmitt J, Griinewald T, Decher G, Pershan PS, Kjaer K, Losche M (1993) Internal structure of layer-by-layer adsorbed polyelectrolyte films: a neutron and X-ray reflectivity study. Macromolecules 26:7058–7063. https://doi.org/10.1021/ma00077a052CrossRef

210.

Rmaile HH, Schlenoff JB (2002) Internal pKa’s in polyelectrolyte multilayers: coupling protons and salt. Langmuir 18:8263–8265. https://doi.org/10.1021/la025624sCrossRef

211.

Kharlampieva E, Kozlovskaya V, Chan J, Ankner JF, Tsukruk VV (2009) Spin-assisted layer-by-layer assembly: variation of stratification as studied with neutron reflectivity. Langmuir 25:14,017–14,024. https://doi.org/10.1021/la9014042

212.

Holmberg K, Jönsson B, Kronberg B, Lindman B (2002) Surfactants and polymers in aqueous solution. Wiley, Chichester, United KingdomCrossRef

213.

Cohen-Stuart MA, Hoogendam CW, de Keizer A (1997) Kinetics of polyelectrolyte adsorption. J Phys Cond Matter 9:7767–7783. https://doi.org/10.1088/0953-8984/9/37/009CrossRef

214.

Lane TJ, Fletcher WR, Gormally MV, Johal MS (2008) Dual-beam polarization interferometry resolves mechanistic aspects of polyelectrolyte adsorption. Langmuir 24:10633–10636. https://doi.org/10.1021/la802496hCrossRefPubMed

215.

Raposo M, Oliveira ON (2000) Energies of adsorption of poly(o-methoxyaniline) layer-by-layer films. Langmuir 16:2839–2844. https://doi.org/10.1021/la990945yCrossRef

216.

Raposo M, Oliveira ON (1998) Adsorption mechanisms in layer-by-layer films. Braz J Phys 28:392–404. https://doi.org/10.1590/S0103-97331998000400014CrossRef

217.

Raposo M, Pontes RS, Mattoso LHC, Oliveira ON (1997) Kinetics of adsorption of poly(o-methoxyaniline) self-assembled films Macromolecules 30:6095–6101. https://doi.org/10.1021/ma970228f

218.

Linse P, Källrot N (2010) Polymer adsorption from bulk solution onto planar surfaces: effect of polymer flexibility and surface attraction in good solvent. Macromolecules 43:2054–2068. https://doi.org/10.1021/ma902338mCrossRef

219.

Kienle DF, Schwartz DK (2019) Complex salt dependence of polymer diffusion in polyelectrolyte multilayers. J Phys Chem Lett 10:987–992. https://doi.org/10.1021/acs.jpclett.9b00004CrossRefPubMed

220.

Das BP, Tsianou M (2017) From polyelectrolyte complexes to polyelectrolyte multilayers: electrostatic assembly, nanostructure, dynamics, and functional properties. Adv Colloid Interface Sci 244:71–89. https://doi.org/10.1016/j.cis.2016.12.004CrossRefPubMed

221.

Porcel C, Lavalle P, Decher G, Senger B, Voegel JC, Schaaf P (2007) Influence of the polyelectrolyte molecular weight on exponentially growing multilayer films in the linear regime. Langmuir 23:1898–1904. https://doi.org/10.1021/la062728kCrossRefPubMed

222.

Nazaran P, Bosio V, Jaeger W, Anghel DF, von Klitzing R (2007) Lateral mobility of polyelectrolyte chains in multilayers. J Phys Chem B 111:8572–8581. https://doi.org/10.1021/jp068768eCrossRefPubMed

223.

Korneev D, Lvov Y, Decher G, Schmitt J, Yaradaikin S (1995) Neutron reflectivity analysis of self assembled film superlattices with alternate layers of deuterated and hydrogenated polysterenesulfonate and polyallylamine. Physica B 213:954–956. https://doi.org/10.1016/0921-4526(95)00333-5CrossRef

224.

Soltwedel O, Ivanova O, Nestler P, Müler M, Köhler R, Helm CA (2010) Interdiffusion in polyelectrolyte multilayers. Macromolecules 43:7288–7293. https://doi.org/10.1021/ma101279qCrossRef

225.

Selin V, Ankner JF, Sukhishvili SA (2017) Nonlinear layer-by-layer films: effects of chain diffusivity on film structure and swelling. Macromolecules 50:6192–6201. https://doi.org/10.1021/acs.macromol.7b01218CrossRef

Titel: Electrostatic Layer-by-Layer Self-Assembly Method: A Physico-Chemical Perspective
verfasst von: Eduardo Guzmán
Ana Mateos-Maroto
Francisco Ortega
Ramón G. Rubio
Verlag: Springer International Publishing
Buch: Supramolecular Assemblies Based on Electrostatic Interactions
Print ISBN: 978-3-031-00656-2

Electronic ISBN: 978-3-031-00657-9

Copyright-Jahr: 2022
DOI: https://doi.org/10.1007/978-3-031-00657-9_6

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