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2022 | OriginalPaper | Buchkapitel

5. Nano-Objects by Spontaneous Electrostatic Self-Assembly in Aqueous Solution

verfasst von : Alexander Zika, Anja Krieger, Franziska Gröhn

Erschienen in: Supramolecular Assemblies Based on Electrostatic Interactions

Verlag: Springer International Publishing

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Abstract

Electrostatic self-assembly for the formation of well-defined nano-objects in solution represents an emerging field. The key is to use building blocks with a certain geometry and/or a combination of noncovalent interaction types. Polyelectrolytes providing both stability and designability are especially valuable. Central for a targeted design is the fundamental understanding of structure-directing effects. This chapter addresses both an introduction to the field of spontaneous electrostatic self-assembly as well as the state of the art of its understanding. It commences from the special effects of polyelectrolytes, shortly pictures the established areas of polyelectrolyte complexes and block polyelectrolyte micelles, before focusing on novel approaches: Besides discussing the interplay of ionic and π-π interaction in a dendrimer-dye model system, we elucidate how thermodynamics encodes the nanoscale structure: the free energy determines the aggregation number but the entropy/enthalpy ratio the nano-object’s shape. The approach’s versatility applicable for building blocks from linear or cylindrical brush polyelectrolytes, proteins, DNA, polyoxometalate clusters to micelles is demonstrated. We provide examples of photocatalytic activity and triggering of the nano-objects’ size, shape, or function (e.g., enzyme activity) by addressing multiple stimuli such as pH and light. This includes the novel use of photoacids as interconnecting counterions with light-switchable valency.

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Titel: Nano-Objects by Spontaneous Electrostatic Self-Assembly in Aqueous Solution
verfasst von: Alexander Zika
Anja Krieger
Franziska Gröhn
Verlag: Springer International Publishing
Buch: Supramolecular Assemblies Based on Electrostatic Interactions
Print ISBN: 978-3-031-00656-2

Electronic ISBN: 978-3-031-00657-9

Copyright-Jahr: 2022
DOI: https://doi.org/10.1007/978-3-031-00657-9_5

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