Skip to main content
Erschienen in: Topics in Catalysis 13-20/2009

01.12.2009 | Original Paper

EPR and SEM Characterizations of the Contact Between Carbon Black and Cerium Oxide

verfasst von: M. Issa, C. Petit, H. Mahzoul, A. Aboukaïs, J.-F. Brilhac

Erschienen in: Topics in Catalysis | Ausgabe 13-20/2009

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The physicochemical properties of the contact between carbon black (CB) and cerium oxide (CeO2) were investigated using scanning electronic microscopy (SEM) and electron paramagnetic resonance (EPR). Two types of contact were performed: tight and loose for different mixtures of CeO2/CB. A correlation has been established between the results of EPR and SEM and temperature programmed oxidation (TPO) results.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Kampa M, Castanas E (2008) Human health effects of air pollution. Environ Pollut 151:362–367CrossRef Kampa M, Castanas E (2008) Human health effects of air pollution. Environ Pollut 151:362–367CrossRef
2.
Zurück zum Zitat Neeft JPA, Makkee M, Moulijn JA (1996) Metal oxides as catalysts for the oxidation of soot. Chem Eng J 64:295–302 Neeft JPA, Makkee M, Moulijn JA (1996) Metal oxides as catalysts for the oxidation of soot. Chem Eng J 64:295–302
3.
Zurück zum Zitat Bueno-Lopez A, Krishna K, Makkee M, Moulijn JA (2005) Enhanced soot oxidation by lattice oxygen via La3+-doped CeO2. J Catal 230:237–248CrossRef Bueno-Lopez A, Krishna K, Makkee M, Moulijn JA (2005) Enhanced soot oxidation by lattice oxygen via La3+-doped CeO2. J Catal 230:237–248CrossRef
4.
Zurück zum Zitat Mul G, Kapteijn F, Doornkamp C, Moulijn J (1998) Transition metal oxide catalyzed carbon black oxidation: a study with 18O2. J Catal 179:258–266CrossRef Mul G, Kapteijn F, Doornkamp C, Moulijn J (1998) Transition metal oxide catalyzed carbon black oxidation: a study with 18O2. J Catal 179:258–266CrossRef
5.
Zurück zum Zitat van Setten BAAL, Schouten JM, Makkee M, Moulijn JA (2000) Realistic contact for soot with an oxidation catalyst for laboratory studies. Appl Catal B 28:253–257CrossRef van Setten BAAL, Schouten JM, Makkee M, Moulijn JA (2000) Realistic contact for soot with an oxidation catalyst for laboratory studies. Appl Catal B 28:253–257CrossRef
6.
Zurück zum Zitat Fino D, Russo N, Saracco G, Specchia V (2003) The role of suprafacial oxygen in some perovskites for the catalytic combustion of soot. J Catal 217:367–375 Fino D, Russo N, Saracco G, Specchia V (2003) The role of suprafacial oxygen in some perovskites for the catalytic combustion of soot. J Catal 217:367–375
7.
Zurück zum Zitat Ciambellli P, Palma V, Russo P, Vaccaro S (2003) Redox properties of a TiO2 supported Cu–V–K–Cl catalyst in low temperature soot oxidation. J Mol Catal A Chem 204–205:673–681CrossRef Ciambellli P, Palma V, Russo P, Vaccaro S (2003) Redox properties of a TiO2 supported Cu–V–K–Cl catalyst in low temperature soot oxidation. J Mol Catal A Chem 204–205:673–681CrossRef
8.
Zurück zum Zitat Mul G, Neeft JPA, Kapteijn F, Makkee M, Moulijn JA (1995) Soot oxidation catalyzed by a Cu/K/Mo/Cl catalyst: evaluation of the chemistry and performance of the catalyst. Appl Catal B 6:339–352CrossRef Mul G, Neeft JPA, Kapteijn F, Makkee M, Moulijn JA (1995) Soot oxidation catalyzed by a Cu/K/Mo/Cl catalyst: evaluation of the chemistry and performance of the catalyst. Appl Catal B 6:339–352CrossRef
9.
Zurück zum Zitat Setiabudi A, Allart NK, Makkee M, Moulijn JA (2005) In situ visible microscopic study of moltenCs2SO4.V2O5-soot system: physical interaction, oxidation rate, and data evaluation. Appl Catal B 60:241–251 Setiabudi A, Allart NK, Makkee M, Moulijn JA (2005) In situ visible microscopic study of moltenCs2SO4.V2O5-soot system: physical interaction, oxidation rate, and data evaluation. Appl Catal B 60:241–251
10.
Zurück zum Zitat Saab E, Abi-Aad E, Bokova MN, Zhilinskaya EA, Aboukaïs A (2007) EPR characterisation of carbon black in loose and tight contact with Al2O3 and CeO2 catalysts. Carbon 45:561–567CrossRef Saab E, Abi-Aad E, Bokova MN, Zhilinskaya EA, Aboukaïs A (2007) EPR characterisation of carbon black in loose and tight contact with Al2O3 and CeO2 catalysts. Carbon 45:561–567CrossRef
11.
Zurück zum Zitat Saab E, Aouad S, Abi-Aad E, Zhilinskaya EA, Aboukaïs A (2007) Carbon black oxidation in the presence of Al2O3, CeO2, and Mn oxide catalysts: an EPR study. Catal Today 119:286–290CrossRef Saab E, Aouad S, Abi-Aad E, Zhilinskaya EA, Aboukaïs A (2007) Carbon black oxidation in the presence of Al2O3, CeO2, and Mn oxide catalysts: an EPR study. Catal Today 119:286–290CrossRef
12.
Zurück zum Zitat Issa M, Petit C, Brillard A, Brilhac J-F (2008) Effect of the contact between carbon black, catalyst particles on carbon oxidation rate: experiments and modelling. Fuel 87:740–750CrossRef Issa M, Petit C, Brillard A, Brilhac J-F (2008) Effect of the contact between carbon black, catalyst particles on carbon oxidation rate: experiments and modelling. Fuel 87:740–750CrossRef
13.
Zurück zum Zitat Ottaviani MF, Retini G, Cangiotti M, Managni F, Segre U (2002) Characterization of the surface interacting ability of carbon black by means of electronic paramagnetic resonance analysis of adsorbed Cu2+, supported by surface analysis and atomic absorption. Spectrochim Acta A 58:1129–1141CrossRef Ottaviani MF, Retini G, Cangiotti M, Managni F, Segre U (2002) Characterization of the surface interacting ability of carbon black by means of electronic paramagnetic resonance analysis of adsorbed Cu2+, supported by surface analysis and atomic absorption. Spectrochim Acta A 58:1129–1141CrossRef
14.
Zurück zum Zitat Jones CC, Chughtai AR, Murugaverl B, Smith DM (2004) Effects of air/fuel combustion ratio on the polycyclic aromatic hydrocarbon content of carbonaceous soots from selected fuels. Carbon 42:2471–2484CrossRef Jones CC, Chughtai AR, Murugaverl B, Smith DM (2004) Effects of air/fuel combustion ratio on the polycyclic aromatic hydrocarbon content of carbonaceous soots from selected fuels. Carbon 42:2471–2484CrossRef
15.
Zurück zum Zitat Jachym B, Witort I, Wisniewski G (1985) Fiz Ser 54:361 Jachym B, Witort I, Wisniewski G (1985) Fiz Ser 54:361
16.
Zurück zum Zitat Issa M Ph.D. Dissertation, Etude théorique et expérimentale de l’oxydation catalytique du noir de carbone: Influence du contact entre solides. University of Haute-Alsace, Mulhouse Issa M Ph.D. Dissertation, Etude théorique et expérimentale de l’oxydation catalytique du noir de carbone: Influence du contact entre solides. University of Haute-Alsace, Mulhouse
Metadaten
Titel
EPR and SEM Characterizations of the Contact Between Carbon Black and Cerium Oxide
verfasst von
M. Issa
C. Petit
H. Mahzoul
A. Aboukaïs
J.-F. Brilhac
Publikationsdatum
01.12.2009
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 13-20/2009
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-009-9395-x

Weitere Artikel der Ausgabe 13-20/2009

Topics in Catalysis 13-20/2009 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.