Skip to main content
Erschienen in: Environmental Earth Sciences 7/2013

01.04.2013 | Original Article

Exceedance of air quality standards resulting from pyro-metallurgical production of copper: a case study, Bor (Eastern Serbia)

verfasst von: Snezana M. Serbula, Tanja S. Kalinovic, Jelena V. Kalinovic, Ana A. Ilic

Erschienen in: Environmental Earth Sciences | Ausgabe 7/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This study represents air quality data of SO2 and As concentrations around the mining–metallurgical complex Bor (Serbia) from 1994 to 2008. Daily and annual SO2 concentrations greatly exceed current air quality standards in the studied area. The “hot spot” with the highest SO2 and As annual concentrations during 15 years was the urban-industrial area (the town core). Daily SO2 concentrations and meteorological parameters during the period from 2005 to 2008 were statistically analysed to develop suitable prediction equations for daily SO2 concentrations. Anode copper production is an important but not the only factor that has influence on SO2 concentrations. By stepwise multiple linear regression analysis, it was determined that daily SO2 concentrations are most influenced by maximum wind gust, relative humidity and air temperature at all the measuring sites. The prediction equations of daily SO2 concentrations represent a good model with regression coefficients from 0.854 to 0.926 at all the measuring sites. Correlation analysis showed that eastern and western winds increase SO2 concentrations, thus increasing the health risk of the inhabitants in the study area.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Akpinar S, Oztop HF, Akpinar EK (2008) Evaluation of relationship between meteorological parameters and air pollutant concentrations during winter season in Elazığ, Turkey. Environ Monit Assess 146:211–224CrossRef Akpinar S, Oztop HF, Akpinar EK (2008) Evaluation of relationship between meteorological parameters and air pollutant concentrations during winter season in Elazığ, Turkey. Environ Monit Assess 146:211–224CrossRef
Zurück zum Zitat ATSDR (2000) Agency for toxic substances and disease registry: toxicological profile for arsenic. US Department of Health and Human Services, Public Health Service, USA ATSDR (2000) Agency for toxic substances and disease registry: toxicological profile for arsenic. US Department of Health and Human Services, Public Health Service, USA
Zurück zum Zitat Banerjee T, Singh SB, Srivastava RK (2011) Development and performance evaluation of statistical models correlating air pollutants and meteorological variables at Pantnagar, India. Atmos Res 99:505–517CrossRef Banerjee T, Singh SB, Srivastava RK (2011) Development and performance evaluation of statistical models correlating air pollutants and meteorological variables at Pantnagar, India. Atmos Res 99:505–517CrossRef
Zurück zum Zitat Boyd R, Barnes S-J, De Caritat P, Chekushin VA, Melezhik VA, Reimann C, Zientek ML (2009) Emissions from the copper–nickel industry on the Kola Peninsula and at Noril’sk, Russia. Atmos Environ 43:1474–1480CrossRef Boyd R, Barnes S-J, De Caritat P, Chekushin VA, Melezhik VA, Reimann C, Zientek ML (2009) Emissions from the copper–nickel industry on the Kola Peninsula and at Noril’sk, Russia. Atmos Environ 43:1474–1480CrossRef
Zurück zum Zitat Çelik MB, Kadi İ (2007) The relation between meteorological factors and pollutants concentrations in Karabük city. GU J Sci 20:87–95 Çelik MB, Kadi İ (2007) The relation between meteorological factors and pollutants concentrations in Karabük city. GU J Sci 20:87–95
Zurück zum Zitat Chu PC, Chen Y, Lu S (2008) Atmospheric effects on winter SO2 pollution in Lanzhou, China. Atmos Res 89:365–373CrossRef Chu PC, Chen Y, Lu S (2008) Atmospheric effects on winter SO2 pollution in Lanzhou, China. Atmos Res 89:365–373CrossRef
Zurück zum Zitat Costabile F, Bertoni G, Desantis F, Wang F, Weimin H, Fenglei L, Allegrini I (2006) A preliminary assessment of major air pollutants in the city of Suzhou, China. Atmos Environ 40:6380–6395CrossRef Costabile F, Bertoni G, Desantis F, Wang F, Weimin H, Fenglei L, Allegrini I (2006) A preliminary assessment of major air pollutants in the city of Suzhou, China. Atmos Environ 40:6380–6395CrossRef
Zurück zum Zitat Csavina J, Landázuri A, Wonaschütz A, Rine K, Rheinheimer P, Barbaris B, Conant W, Sáez AE, Betterton EA (2011) Metal and metalloid contaminants in atmospheric aerosols from mining operations. Water Air Soil Pollut 221:145–157CrossRef Csavina J, Landázuri A, Wonaschütz A, Rine K, Rheinheimer P, Barbaris B, Conant W, Sáez AE, Betterton EA (2011) Metal and metalloid contaminants in atmospheric aerosols from mining operations. Water Air Soil Pollut 221:145–157CrossRef
Zurück zum Zitat Denby B, Sundvor I, Cassiani M, de Smet P, de Leeuw F, Horálek J (2010) Spatial mapping of ozone and SO2 trends in Europe. Sci Total Environ 408:4795–4806CrossRef Denby B, Sundvor I, Cassiani M, de Smet P, de Leeuw F, Horálek J (2010) Spatial mapping of ozone and SO2 trends in Europe. Sci Total Environ 408:4795–4806CrossRef
Zurück zum Zitat EC (2000) Ambient air pollution by As, Cd and Ni compounds, working group on As, Cd and Ni compounds, position paper, final version, DG environment EC (2000) Ambient air pollution by As, Cd and Ni compounds, working group on As, Cd and Ni compounds, position paper, final version, DG environment
Zurück zum Zitat EC (2004) Council Directive 2004/107/EC relating to arsenic, cadmium, mercury, nickel and polycyclic aromatic hydrocarbons in ambient air, Official J Eur Commun L23, pp 3–6 EC (2004) Council Directive 2004/107/EC relating to arsenic, cadmium, mercury, nickel and polycyclic aromatic hydrocarbons in ambient air, Official J Eur Commun L23, pp 3–6
Zurück zum Zitat EC (2008) Council Directive 2008/50/EC of the European Parliament and of the Council of 21 May 2008 on ambient air quality and cleaner air for Europe. Official J Eur Union, L 152/1, 11 Jun 2008 EC (2008) Council Directive 2008/50/EC of the European Parliament and of the Council of 21 May 2008 on ambient air quality and cleaner air for Europe. Official J Eur Union, L 152/1, 11 Jun 2008
Zurück zum Zitat EIA Study-New (2010) Smelter and sulphuric acid plant project. Faculty of Metallurgy, University of Belgrade, SNC Lavalin, pp 1–16 EIA Study-New (2010) Smelter and sulphuric acid plant project. Faculty of Metallurgy, University of Belgrade, SNC Lavalin, pp 1–16
Zurück zum Zitat Fowler D, Pilegaard K, Sutton MA et al (2009) Atmospheric composition change: ecosystems–atmosphere interactions. Atmos Environ 43:5193–5267CrossRef Fowler D, Pilegaard K, Sutton MA et al (2009) Atmospheric composition change: ecosystems–atmosphere interactions. Atmos Environ 43:5193–5267CrossRef
Zurück zum Zitat Gallero FJG, Vallejo AMG, Umbrìa A, Baena JG (2006) Multivariate statistical analysis of meteorological and air pollution data in the “Campo De Gibraltar” region, Spain. Environ Monit and Assess 119:405–423CrossRef Gallero FJG, Vallejo AMG, Umbrìa A, Baena JG (2006) Multivariate statistical analysis of meteorological and air pollution data in the “Campo De Gibraltar” region, Spain. Environ Monit and Assess 119:405–423CrossRef
Zurück zum Zitat Hayes RB (1997) The carcinogenicity of metals in humans. Cancer Cause Control 8:371–385CrossRef Hayes RB (1997) The carcinogenicity of metals in humans. Cancer Cause Control 8:371–385CrossRef
Zurück zum Zitat İçağa Y, Sabah E (2009) Statistical analysis of air pollutants and meteorological parameters in Afyon, Turkey. Environ Model Assess 14:259–266CrossRef İçağa Y, Sabah E (2009) Statistical analysis of air pollutants and meteorological parameters in Afyon, Turkey. Environ Model Assess 14:259–266CrossRef
Zurück zum Zitat Ilten N, Selici AT (2008) Investigating the impacts of some meteorological parameters on air pollution in Balikesir, Turkey. Environ Monit Assess 140:267–277CrossRef Ilten N, Selici AT (2008) Investigating the impacts of some meteorological parameters on air pollution in Balikesir, Turkey. Environ Monit Assess 140:267–277CrossRef
Zurück zum Zitat IPCS (2001) International Programme on Chemical Safety: environmental health criteria on arsenic and arsenic compounds arsenic and arsenic compounds: environmental health criteria, vol 224, 2nd edn. WHO, Geneva IPCS (2001) International Programme on Chemical Safety: environmental health criteria on arsenic and arsenic compounds arsenic and arsenic compounds: environmental health criteria, vol 224, 2nd edn. WHO, Geneva
Zurück zum Zitat ISO 10498 (2004) International Organization for Standardization: ambient air-determination of sulfur dioxide, ultraviolet fluorescence method. IOS, Geneva ISO 10498 (2004) International Organization for Standardization: ambient air-determination of sulfur dioxide, ultraviolet fluorescence method. IOS, Geneva
Zurück zum Zitat Kan H, Wong C-M, Vichit-Vadakan N, Qian Z et al (2010) Short-term association between sulfur dioxide and daily mortality: the Public Health and Air Pollution in Asia (PAPA) study. Environ Res 110:258–264CrossRef Kan H, Wong C-M, Vichit-Vadakan N, Qian Z et al (2010) Short-term association between sulfur dioxide and daily mortality: the Public Health and Air Pollution in Asia (PAPA) study. Environ Res 110:258–264CrossRef
Zurück zum Zitat Mamtimin B, Meixner FX (2011) Air pollution and meteorological processes in the growing dryland city of Urumqi (Xinjiang, China). Sci Total Environ 409:1277–1290CrossRef Mamtimin B, Meixner FX (2011) Air pollution and meteorological processes in the growing dryland city of Urumqi (Xinjiang, China). Sci Total Environ 409:1277–1290CrossRef
Zurück zum Zitat Mining and Metallurgy Institute Bor (MMI) (2008) Reports on quality of ambient air in Bor from 1994 to 2008, Sector for measuring and control of gaseous and dust parameters, Department for Chemical-Technical Control Mining and Metallurgy Institute Bor (MMI) (2008) Reports on quality of ambient air in Bor from 1994 to 2008, Sector for measuring and control of gaseous and dust parameters, Department for Chemical-Technical Control
Zurück zum Zitat Özden Ö, Döğeroğlu T, Kara S (2008) Assessment of ambient air quality in Eskişehir, Turkey. Environ Int 34:678–687CrossRef Özden Ö, Döğeroğlu T, Kara S (2008) Assessment of ambient air quality in Eskişehir, Turkey. Environ Int 34:678–687CrossRef
Zurück zum Zitat Pedrero P, Tardón C, López E (2009) Descriptive mathematical techniques to study historical data: an application to sulfur dioxide pollution in the city of Talcahuano, Chile. Atmos Environ 43:6279–6286CrossRef Pedrero P, Tardón C, López E (2009) Descriptive mathematical techniques to study historical data: an application to sulfur dioxide pollution in the city of Talcahuano, Chile. Atmos Environ 43:6279–6286CrossRef
Zurück zum Zitat Pfafflin JR, Ziegler EN (2006) Encyclopedia of environmental science and engineering, 5th edn. Taylor and Francis Group, Boca Raton Pfafflin JR, Ziegler EN (2006) Encyclopedia of environmental science and engineering, 5th edn. Taylor and Francis Group, Boca Raton
Zurück zum Zitat Pires JCM, Sousa SIV, Pereira MC, Alvim-Ferraz MCM, Martins FG (2008) Management of air quality monitoring using principal component and cluster analysis-Part I: SO2 and PM10. Atmos Environ 42:1249–1260CrossRef Pires JCM, Sousa SIV, Pereira MC, Alvim-Ferraz MCM, Martins FG (2008) Management of air quality monitoring using principal component and cluster analysis-Part I: SO2 and PM10. Atmos Environ 42:1249–1260CrossRef
Zurück zum Zitat Samoli E, Nastos PT, Paliatsos AG, Katsouyanni K, Priftis KN (2011) Acute effects of air pollution on pediatric asthma exacerbation: evidence of association and effect modification. Environ Res 111:418–424CrossRef Samoli E, Nastos PT, Paliatsos AG, Katsouyanni K, Priftis KN (2011) Acute effects of air pollution on pediatric asthma exacerbation: evidence of association and effect modification. Environ Res 111:418–424CrossRef
Zurück zum Zitat Sánchez de la Campa AM, de la Rosa JD, Sánchez-Rodas D, Oliveira V, Alastuey A, Querol X, Ariza JLG (2008) Arsenic speciation study of PM 2.5 in an urban area near a copper smelter. Atmos Environ 42:6487–6495CrossRef Sánchez de la Campa AM, de la Rosa JD, Sánchez-Rodas D, Oliveira V, Alastuey A, Querol X, Ariza JLG (2008) Arsenic speciation study of PM 2.5 in an urban area near a copper smelter. Atmos Environ 42:6487–6495CrossRef
Zurück zum Zitat Santacatalina M, Carratalá A, Mantilla E (2011) Influence of local and regional Mediterranean meteorology on SO2 ground-level concentrations in SE Spain. J Environ Monit 13:1634–1645CrossRef Santacatalina M, Carratalá A, Mantilla E (2011) Influence of local and regional Mediterranean meteorology on SO2 ground-level concentrations in SE Spain. J Environ Monit 13:1634–1645CrossRef
Zurück zum Zitat Say NP (2006) Lignite-fired thermal power plants and SO2 pollution in Turkey. Energ Policy 34:2690–2701CrossRef Say NP (2006) Lignite-fired thermal power plants and SO2 pollution in Turkey. Energ Policy 34:2690–2701CrossRef
Zurück zum Zitat SEPA (2009) Serbian Environmental Protection Agency: environmental reports for the republic of Serbia 2005–2008. The Ministry of Environmental Protection and Spatial Planning, Belgrade (in Serbian) SEPA (2009) Serbian Environmental Protection Agency: environmental reports for the republic of Serbia 2005–2008. The Ministry of Environmental Protection and Spatial Planning, Belgrade (in Serbian)
Zurück zum Zitat Serbula SM, Antonijevic MM, Milosevic NM, Milic SM, Ilic AA (2010) Concentrations of particulate matter and arsenic in Bor (Serbia). J Hazard Mater 181:43–51CrossRef Serbula SM, Antonijevic MM, Milosevic NM, Milic SM, Ilic AA (2010) Concentrations of particulate matter and arsenic in Bor (Serbia). J Hazard Mater 181:43–51CrossRef
Zurück zum Zitat Serbula SM, Miljkovic DDj, Kovacevic RM, Ilic AA (2012) Assessment of airborne heavy metal pollution using plant parts and topsoil. Ecotox Environ Safe 76:209–214CrossRef Serbula SM, Miljkovic DDj, Kovacevic RM, Ilic AA (2012) Assessment of airborne heavy metal pollution using plant parts and topsoil. Ecotox Environ Safe 76:209–214CrossRef
Zurück zum Zitat Tabaku A, Bejtja G, Bala S, Toci E, Resuli J (2011) Effects of air pollution on children’s pulmonary health. Atmos Environ 45:7540–7545CrossRef Tabaku A, Bejtja G, Bala S, Toci E, Resuli J (2011) Effects of air pollution on children’s pulmonary health. Atmos Environ 45:7540–7545CrossRef
Zurück zum Zitat The Official Gazette of The Republic of Serbia (2010) Regulation on alterations and anexes of the Regulation on conditions for monitoring and the requirements for air quality improvement. No. 75/10 The Official Gazette of The Republic of Serbia (2010) Regulation on alterations and anexes of the Regulation on conditions for monitoring and the requirements for air quality improvement. No. 75/10
Zurück zum Zitat Turalioğlu FS, Nuhoğlu A, Bayraktar H (2005) Impacts of some meteorological parameters on SO2 and TSP concentrations in Erzurum, Turkey. Chemosphere 59:1633–1642CrossRef Turalioğlu FS, Nuhoğlu A, Bayraktar H (2005) Impacts of some meteorological parameters on SO2 and TSP concentrations in Erzurum, Turkey. Chemosphere 59:1633–1642CrossRef
Zurück zum Zitat Vet R, Ro C-U (2008) Contribution of Canada–United States transboundary transport to wet deposition of sulphur and nitrogen oxides-A mass balance approach. Atmos Environ 42:518–2529CrossRef Vet R, Ro C-U (2008) Contribution of Canada–United States transboundary transport to wet deposition of sulphur and nitrogen oxides-A mass balance approach. Atmos Environ 42:518–2529CrossRef
Zurück zum Zitat WHO (2005) World Health Organization: air quality guidelines, Global update 2005. Particulate matter, ozone, nitrogen dioxide and sulfur dioxide. Regional Office for Europe, Copenhagen WHO (2005) World Health Organization: air quality guidelines, Global update 2005. Particulate matter, ozone, nitrogen dioxide and sulfur dioxide. Regional Office for Europe, Copenhagen
Zurück zum Zitat WHO (2006) World Health Organization: air quality guidelines. Global update 2005. Regional Office for Europe, Copenhagen WHO (2006) World Health Organization: air quality guidelines. Global update 2005. Regional Office for Europe, Copenhagen
Zurück zum Zitat Zhang X, Jiang H, Jin J, Xu X, Zhang Q (2012) Analysis of acid rain patterns in Northeastern China using a decision tree method. Atmos Environ 46:590–596CrossRef Zhang X, Jiang H, Jin J, Xu X, Zhang Q (2012) Analysis of acid rain patterns in Northeastern China using a decision tree method. Atmos Environ 46:590–596CrossRef
Metadaten
Titel
Exceedance of air quality standards resulting from pyro-metallurgical production of copper: a case study, Bor (Eastern Serbia)
verfasst von
Snezana M. Serbula
Tanja S. Kalinovic
Jelena V. Kalinovic
Ana A. Ilic
Publikationsdatum
01.04.2013
Verlag
Springer-Verlag
Erschienen in
Environmental Earth Sciences / Ausgabe 7/2013
Print ISSN: 1866-6280
Elektronische ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-012-1886-6

Weitere Artikel der Ausgabe 7/2013

Environmental Earth Sciences 7/2013 Zur Ausgabe