Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 6/2018

28.11.2017 | Chemical routes to materials

Fabrication and characterization of thermo-responsive GO nanosheets with controllable grafting of poly(hexadecyl acrylate) chains

verfasst von: Cao Ruirui, Chen Sai, Liu Huanbing, Liu Haihui, Zhang Xingxiang

Erschienen in: Journal of Materials Science | Ausgabe 6/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A series of novel poly(hexadecyl acrylate)-grafted-graphene oxides (PHDA-g-GOs) were fabricated as thermo-responsive GO nanosheets via diazonium addition and surface-initiated atom transfer radical polymerization (SI-ATRP). Various spectroscopic and microscopic evidences confirm the successful fabrication of the thermo-responsive GO nanosheets. The thermo-responsive property and thermal stability of the PHDA-g-GOs were determined by DSC and TGA. Furthermore, we have demonstrated the ability to systematically tune the chain length of polymer molecules covalently bonded to GO nanosheets by SI-ATRP. Comparing the thermo-responsive GO samples, the ∆H m and ∆H c increased as the molar ratio of monomer to initiator increased. Moreover, the T mo, T co, ∆H m and ∆H c values of the PHDA-g-GO3 (with a molar ratio of monomer to initiator as 1000:1) are 31.2, 31.4 °C, 79 and 76 J/g, respectively. Meanwhile, the thermo-responsive GO nanosheets have good thermal stability and shape stability. Therefore, the thermo-responsive GO nanosheet is a very promising functional material and can be used in more areas, such as the fabrication of temperature-sensitive drugs, reagents, fibers and textiles, solar energy storage and temperature sensor.
Vorheriger Artikel Effective size-controlled synthesis and electrochemical characterization of ordered Pt nanopattern arrays from self-assembling block copolymer template
Nächster Artikel A novel biomimetic catalyst constructed by axial coordination of hemin with PAN fiber for efficient degradation of organic dyes

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
2.
Lee SH, Dreyer DR, An JH, Velamakanni A, Piner RD, Park SJ, Zhu YW, Kim SO, Bielawski CW, Ruoff RS (2010) Polymer brushes via controlled, surface-initiated atom transfer radical polymerization (ATRP) from graphene oxide. Macromol Rapid Commun 31:281–288CrossRef
3.
Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183–191CrossRef
4.
Zhang Y, Tan YW, Stormer HL, Kim P (2005) Experimental observation of the quantum hall effect and berry’s phase in graphene. Nature 438:201–204CrossRef
5.
6.
Tong J, Huang HX, Wu M (2016) Facile green fabrication of well dispersed poly(vinylidene fluoride)/graphene oxide nanocomposites with improved properties. Compos Sci Technol 129:183–190CrossRef
7.
Novoselov KS, Geim AK, Morozov S, Jiang D, Dubonos SA, Grigorieva I, Firsov A (2004) Electric field effect in atomically thin carbon films. Science 306:666–669CrossRef
8.
Wan Q, Mao LC, Liu MY, Wang K, Zeng GJ, Xu DZ, Huang HY, Zhang XY, Wei Y (2015) Towards development of a versatile and efficient strategy for fabrication of GO based polymer nanocomposites. Polym Chem 6:7211–7218CrossRef
9.
Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless dirac fermions in graphene. Nature 438:197–200CrossRef
10.
Stoller MD, Park S, Zhu YW, An JH, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8:3498–3502CrossRef
11.
Bitounis D, Ali-Boucetta H, Hong BH, Min DH, Kostarelos K (2013) Prospects and challenges of graphene in biomedical applications. Adv Mater 25:2258–2268CrossRef
12.
Yang K, Zhang S, Zhang GX, Sun XM, Lee S-T, Liu Z (2010) Graphene in mice: ultrahigh in vivo tumor uptake and efficient photothermal therapy. Nano Lett 10:3318–3323CrossRef
13.
Kundu A, Nandi S, Das P, Nandi AK (2015) Fluorescent graphene oxide via polymer grafting: an efficient nanocarrier for both hydrophilic and hydrophobic drugs. ACS Appl Mater Interfaces 7:3512–3523CrossRef
14.
Shi YG, Liu MY, Wang K, Deng FJ, Wan Q, Huang Q, Fu LH, Zhang XY, Wei Y (2015) Bioinspired preparation of thermo-responsive graphene oxide nanocomposites in aqueous solution. Polym Chem 32:5876–5883CrossRef
15.
Lee DY, Yoon SY, Oh YJ, Park SY, In I (2011) Thermo-responsive assembly of chemically reduced graphene and poly(N-isopropylacrylamide). Macromol Chem Phys 212:336–341
16.
Deng Y, Zhang JZ, Li YJ, Hu JH, Yang D, Huang XY (2012) Thermoresponsive graphene oxide-PNIPAM nanocomposites with controllable grafting polymer chains via moderate in situ SET-LRP. Polym Chem 50:4451–4458CrossRef
17.
Alzari V, Nuvoli D, Scognamillo S, Poccinini M, Gioffredi E, Malucelli G, Marceddu S, Sechi M, Sanna V, Mariani A (2011) Graphene-containing thermoresponsive nanocomposite hydrogels of poly(N-isopropylacrylamide) prepared by frontal polymerization. J Mater Chem 21:8727–8733CrossRef
18.
Wang L, Jiang L, Su D, Sun C, Chen MF, Goh K, Chen Y (2014) Non-covalent synthesis of thermo-responsive graphene oxide-perylene bisinides-containing poly(N-isopropylacrylamide) hybrid for organic pigment removal. J Colloid Interface Sci 430:121–128CrossRef
19.
Bak JM, Lee T, Seo EY, Lee Y, Jeong HM, Kim BS, Lee H (2012) Thermoresponsive graphene nanosheets by functionalization with polymer brushes. Polymer 53:316–323CrossRef
20.
Nikdel M, Salami-Kalajahi M, Hosseini MS (2014) Synthesis of poly(2-hydroxyethyl methacrylate-co-acrylic acid)-grafted graphene oxide nanosheets via reversible addition-fragmentation chain transfer polymerization. RSC Adv 4:16743–16750CrossRef
21.
El-Ghazawy RA, Farag RK (2010) Synthesis and characterization of novel pour point depressants based on maleic anhydride-alkyl acrylates terpolymers. J Appl Polym Sci 115:72–78CrossRef
22.
Kirkland BS, Paul DR (2008) Gas transport in poly(n-alkyl acrylate)/poly(m-alkyl acrylate) blends. Polymer 49:507–524CrossRef
23.
Shi HF, Zhang XX, Niu JJ, Wang XC, Yin YP, Preparation method for (methyl) crylic acid long-chain alkyl ester polymer phase change materials. European Patent Resgister, CN102351965 (A)
24.
Cao RR, Liu HH, Chen S, Pei DF, Miao JL, Zhang XX (2017) Fabrication and properties of graphene oxide-grafted-poly(hexadecyl acrylate) as a solid-solid phase change material. Compos Sci Technol 149:262–268CrossRef
25.
Kumar A, Behera B, Thakre GD, Ray SS (2016) Covalently grafted graphene oxide/poly(Cn -acrylate) nanocomposites by surface-initiated ATRP: an efficient antifriction, antiwear, and pour-point-depressant lubricating additive in oil media. Ind Eng Chem Res 55:8491–8500CrossRef
26.
Fang M, Wang KG, Lu HB, Yang YL, Nutt S (2010) Single-layer graphene nanosheets with controlled grafting of polymer chains. J Mater Chem 20:1982–1992CrossRef
27.
Fang M, Wang KG, Lu HB, Yang YL, Nutt S (2009) Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites. J Mater Chem 19:7098–7105CrossRef
28.
Wei QB, Wang XL, Zhou F (2012) A versatile macro-initiator with dual functional anchoring groups for surface-initiated atom transfer radical polymerization on various substrates. Polym Chem 3:2129–2137CrossRef
29.
Ye FL, Lu CJ, Chen HX, Zhang YH, Li NJ, Wang LH, Li H, Xu QF, Lu JM (2014) Initiator-changed memory type: preparation of end-functionalized polymer by ATRP and study of their nonvolatile memory effects. Polym Chem 5:752–760CrossRef
30.
Miao JL, Liu HH, Li W, Zhang XX (2016) Mussel-inspired polydopamine-functionalized graphene as a conductive adhesion promoter and protective layer for silver nanowire transparent electrodes. Langmuir 32:5365–5372CrossRef
31.
Pei DF, Chen S, Li SQ, Shi HF, Li W, Li X, Zhang XX (2016) Fabrication and properties of poly(polyethylene glycol n-alkyl ethervinyl ether)s as polymeric phase change materials. Thermochim Acta 633:161–169CrossRef
32.
Liu LT, Kong LQ, Wang HX, Niu RT, Shi HF (2016) Effect of graphene oxide nanoplatelets on the thermal characteristics and shape-stabilized performance of poly(styrene-co-maleic anhydride)-g-octadecanol comb-like polymeric phase change materials. Sol Energy Mater Sol C 149:40–48CrossRef
33.
Si YC, Samulski ET (2008) Synthesis of water soluble graphene. Nano Lett 8:1679–1682CrossRef
34.
Park SJ, An JH, Jung IH, Piner RD, An SJ, Li XS, Velamakanni A, Ruoff RS (2009) Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents. Nano Lett 9:1593–1597CrossRef
35.
Dyke CA, Tour JM (2003) Solvent-free functionalization of carbon nanotubes. J Am Chem Soc 125:1156–1157CrossRef
36.
Geim AK (2009) Graphene: status and prospects. Science 324:1530–1534CrossRef
37.
Kuila A, Maity N, Layek RK, Nandi AK (2014) On the pH sensitive optoelectronic properties of amphiphilic reduced graphene oxide via grafting of poly(dimethylaminoethyl methacrylate): a signature of P- and N-type doping. J Mater Chem A 2:16039–16050CrossRef
38.
Wang CY, Feng LL, Xin GB, Li W, Zheng J, Tian WH, Li XG (2012) Graphene oxide stabilized polyethylene glycol for heat storage. Phys Chem Chem Phys 14:13233–13238CrossRef
39.
Xiong WL, Chen Y, Hao M, Zhang L, Mei T, Wang JY, Li JH, Wang XB (2015) Facile synthesis of PEG based shape-stabilized phase change materials and their photo-thermal energy conversion. Appl Therm Eng 91:630–637CrossRef
40.
Meng JY, Tang XF, Zhang ZL, Zhang XX, Shi HF (2013) Fabrication and properties of poly(polyethylene glycol octadecyl ether methacrylate). Thermochim Acta 574:116–120CrossRef
41.
Li BX, Liu TX, Hu LY, Wang YF, Nie SB (2013) Facile preparation and adjustable thermal property of stearic acid-graphene oxide composite as shape-stabilized phase change material. Chem Eng J 215–216:819–826CrossRef
42.
Zhao J, Zhu YW, He GG, Xing RS, Pan FS, Jiang ZY, Zhang P, Cao XZ, Wang BY (2016) Incorporating zwitterionic graphene oxides into sodium alginate membrane for efficient water/alcohol separation. ACS Appl Mater Interfaces 8:2097–2103CrossRef
43.
Kan LY, Xu Z, Gao C (2011) General avenue to individually dispersed graphene oxide-based two-dimensional molecular brushes by free radical polymerization. Macromolecules 44:444–452CrossRef
44.
Mondal T, Ashkar R, Butler P, Bhowmick AK, Krishnamoorti R (2016) Graphene nanocomposites with high molecular weight poly(ε-caprolactone) grafts: controlled synthesis and accelerated crystallization. ACS Macro Lett 5:278–282CrossRef
45.
Lomeda JR, Doyle CD, Kosynkin DV, Hwang WF, Tour JM (2008) Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets. J Am Chem Soc 130:16201–16206CrossRef
46.
47.
Kong H, Gao C, Yan DY (2004) Controlled functionalization of multiwalled carbon nanotubes by in situ atom transfer radical polymerization. J Am Chem Soc 126:412–413CrossRef
48.
Cao RR, Li X, Chen S, Yuan HR, Zhang XX (2017) Fabrication and characterization of novel shape-stabilized synergistic phase change materials based on PHDA/GO composites. Energy 138:157–166CrossRef
49.
Zhang Y, Wang LJ, Tang BT, Lu RW, Zhang SF (2016) Form-stable phase change materials with high phase change enthalpy from the composite of paraffin and cross-linking phase change structure. Appl Energy 184:241–246CrossRef
50.
Wang TY, Wang SF, Luo RL, Zhu CY, Akiyama T, Zhang ZG (2016) Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage. Appl Energy 171:113–119CrossRef
Metadaten
Titel
Fabrication and characterization of thermo-responsive GO nanosheets with controllable grafting of poly(hexadecyl acrylate) chains
verfasst von
Cao Ruirui
Chen Sai
Liu Huanbing
Liu Haihui
Zhang Xingxiang
Publikationsdatum
28.11.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 6/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1864-1

Weitere Artikel der Ausgabe 6/2018

Journal of Materials Science 6/2018 Zur Ausgabe

Biomaterials

Structural characteristics and biocompatibility of a casein-based nanocomposite for potential biomedical applications

Energy materials

Nano-dynamic mechanical analysis (nano-DMA) of creep behavior of shales: Bakken case study

Electronic materials

Growth of atomically thin MoS2 flakes on high-κ substrates by chemical vapor deposition

Energy materials

Synergistic carbon-based hole transporting layers for efficient and stable perovskite solar cells

Electronic materials

Comparative study on dynamical stability against strain of pristine and chemically functionalized monolayer honeycomb materials

Metals

Continuous dynamic recrystallization (CDRX) model for aluminum alloys

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise