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Journal of Materials Science
Erschienen in: Journal of Materials Science 10/2019

13.02.2019 | Composites

Fabrication of dispersive α-Co(OH)2 nanosheets on graphene nanoribbons for boosting their oxygen evolution performance

verfasst von: Jingyun Wang, Yipeng Bao, Cao Cui, Zhenyu Zhang, Shumin Li, Jiami Pan, Yingying Zhang, Gaomei Tu, Jin Wang, Zhengquan Li

Erschienen in: Journal of Materials Science | Ausgabe 10/2019

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Abstract

Nanostructured α-Co(OH)2 materials are promising noble-metal-free electrocatalysts for oxygen evolution reaction (OER), but their performance is severally restrained by their poor conductivity. Combination of α-Co(OH)2 and carbon nanotubes (CNTs) can improve their conductivity, but it is difficult to build sufficient interface contact between them due to the mismatched hydrophobicity. Herein, we demonstrate a facile method to in situ grow α-Co(OH)2 nanosheets (NSs) on graphene nanoribbons (GNRs), an intriguing belt-like conductive material after oxidative unzipping of CNTs. Owing to the rich of functional groups, the GNRs can be utilized as substrate in solution to prepare dispersive α-Co(OH)2 nanosheets on their surface. The developed α-Co(OH)2 NSs are well contact with the conductive GNRs substrate and offer sufficient active surface area, showing obviously better OER performance than the α-Co(OH)2 and CNTs/Co(OH)2 prepared under the same condition. The composite electrocatalysts have been characterized by various apparatuses, and their OER activities are explored in detail.
Vorheriger Artikel Preparation of highly hydrophilic PVA/SBA-15 composite materials and their adsorption behavior toward cationic dye: effect of PVA content
Nächster Artikel Facile fabrication of self-healing superhydrophobic nanocomposite films enabled by near-infrared light

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Literatur
1.
Shi YM, Zhang B (2016) Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem Soc Rev 45:1529–1541CrossRef
2.
Zhang HB, Nai JW, Yu L, Lou XW (2017) Metal-organic-framework-based materials as platforms for renewable energy and environmental applications. Joule 1:77–107CrossRef
3.
Montoya JH, Seitz LC, Chakthranont P, Vojvodic A, Jaramillo TF, Nørskov JK (2016) Materials for solar fuels and chemicals. Nat Mater 16:70–81CrossRef
4.
McCrory CCL, Jung S, Ferrer IM, Chatman SM, Peters JC, Jaramillo TF (2015) Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices. J Am Chem Soc 137:4347–4357CrossRef
5.
Yan CZ, Wu HB, Xie Y, Lou XW (2014) Mixed transition-metal oxides: design, synthesis, and energy-related applications. Angew Chem Int Ed 53:1488–1504CrossRef
6.
Yu YF, Shi YM, Zhang B (2018) Synergetic transformation of solid inorganic-organic hybrids into advanced nanomaterials for catalytic water splitting. Acc Chem Res 51:1711–1721CrossRef
7.
Zhao SL, Wang Y, Dong JC, He CT, Yin HJ, An PF, Zhao K, Zhang XF, Gao C, Zhang LJ, Lv JW, Wang JX, Zhang JQ, Khattak AM, Khan NA, Wei ZX, Zhang J, Liu ZY (2016) Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution. Nat Energy 1:16184–16193CrossRef
8.
Gerken JB, McAlpin JG, Chen JY, Rigsby ML, Casey WH, Britt RD, Stahl SS (2011) Electrochemical water oxidation with cobalt-based electrocatalysts from pH 0–14: the thermodynamic basis for catalyst structure, stability, and activity. J Am Chem Soc 133:14431–14442CrossRef
9.
Zheng Y, Jiao Y, Zhu YH, Li LH, Han Y, Chen Y, Du AJ, Jaroniec M, Qiao SZ (2014) Hydrogen evolution by a metal-free electrocatalyst. Nat Commun 5:3783–3790CrossRef
10.
McCrory CCL, Jung S, Peters JC, Jaramillo TF (2013) Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. J Am Chem Soc 135:16977–16987CrossRef
11.
Burke MS, Enman LJ, Batchellor AS, Zou SH, Boettcher SW (2015) Oxygen evolution reaction electrocatalysis on transition metal oxides and (oxy)hydroxides: activity trends and design principles. Chem Mater 27:7549–7558CrossRef
12.
Nong HN, Gan L, Willinger E, Teschner D, Strasser P (2014) IrOx core–shell nanocatalysts for cost-and energy-efficient electrochemical water splitting. Chem Sci 5:2955–2963CrossRef
13.
Chang SH, Danilovic N, Chang KC, Subbaraman R, Paulikas AP, Fong DD, Highland MJ, Baldo PM, Stamenkovic VR, Freeland JW, Eastman JA, Markovic NM (2014) Functional links between stability and reactivity of strontium ruthenate single crystals during oxygen evolution. Nat Commun 5:4191–4199CrossRef
14.
Nong HN, Oh HS, Reier T, Willinger E, Willinger MG, Petkov V, Teschner D, Strasser P (2015) Oxide-supported IrNiOx core–shell particles as efficient, cost-effective, and stable catalysts for electrochemical water splitting. Angew Chem Int Ed 54:2975–2979CrossRef
15.
Zhan Y, Du GJ, Yang SL, Xu CH, Lu MH, Liu ZL, Lee JY (2015) Development of cobalt hydroxide as a bifunctional catalyst for oxygen electrocatalysis in alkaline solution. ACS Appl Mater Interfaces 7:12930–12936CrossRef
16.
Liu PF, Yang S, Zheng LR, Zhang B, Yang HG (2016) Electrochemical etching of acobalt hydroxide for improvement of oxygen evolution reaction. J Mater Chem A 4:9578–9584CrossRef
17.
Wang JY, Cui C, Lin RB, Xu CH, Wang J, Li ZQ (2018) Hybrid cobalt-based electrocatalysts with adjustable compositions for electrochemical water splitting derived from Co2+-loaded MIL-53(Fe) particles. Electrochim Acta 286:397–405CrossRef
18.
Liu ZP, Ma RZ, Osada M, Takada K, Sasaki T (2005) Selective and controlled synthesis of α-and β-cobalt hydroxides in highly developed hexagonal platelets. J Am Chem Soc 127:13869–13874CrossRef
19.
Lei W, Zhi HD, Zheng GW, Feng XZ, Jian J (2013) Layered α-Co(OH)2 nanocones as electrode materials for pseudocapacitors: understanding the effect of interlayer space on electrochemical activity. Adv Funct Mater 23:2758–2764CrossRef
20.
Guo P, Wu J, Li XB, Luo J, Lau WM, Liu H, Sun XL, Liu LM (2018) A highly stable bifunctional catalyst based on 3D Co(OH)2@NCNTs@NF towards overall water-splitting. Nano Energy 47:96–104CrossRef
21.
Jagadale AD, Jamadade VS, Pusawale SN, Lokhande CD (2012) Effect of scan rate on the morphology of potentiodynamically deposited β-Co(OH)2 and corresponding supercapacitive performance. Electrochim Acta 78:92–97CrossRef
22.
Xia XH, Tu JP, Zhang YQ, Mai YJ, Wang XL, Gu CD, Zhao XB (2011) Three-dimentional porous nano-Ni/Co(OH)2 nanoflake composite film: a pseudocapacitive material with superior performance. J Phys Chem C 115:22662–22668CrossRef
23.
Zhang BX, Zhang JL, Tan XN, Tan DX, Shi JB, Zhang FY, Liu LF, Su ZZ, Han BX, Zheng LR, Zhang J (2018) One-step synthesis of ultrathin α-Co(OH)2 nanomeshes and their high electrocatalytic activity toward the oxygen evolution reaction. Chem Commun 54:4045–4048CrossRef
24.
Wu D, Wei YC, Ren X, Ji XQ, Liu YW, Guo XD, Liu Z, Asiri AM, Wei Q, Sun XP (2018) Co(OH)2 nanoparticle-encapsulating conductive nanowires array: room-temperature electrochemical preparation for high-performance water oxidation electrocatalysis. Adv Mater 30:1705366–1705372CrossRef
25.
Jiang YM, Li X, Wang TX, Wang CM (2016) Enhanced electrocatalytic oxygen evolution of α-Co(OH)2 nanosheets on carbon nanotube/polyimide films. Nanoscale 8:9667–9675CrossRef
26.
Jiang DF, Chu ZY, Peng JM, Luo JY, Mao YY, Yang PQ, Jin WQ (2018) One-step synthesis of three-dimensional Co(OH)2/rGO nano-flowers as enzyme-mimic sensors for glucose detection. Electrochim Acta 270:147–155CrossRef
27.
Rahimi SA, Norouzi P, Ganjali MR (2018) One-step cathodic electrodeposition of a cobalt hydroxide–graphene nanocomposite and its use as a high performance supercapacitor electrode material. RSC Adv 8:26818–26827CrossRef
28.
Liu PF, Li X, Yang S, Zu MY, Liu P, Zhang B, Zheng LR, Zhao H, Yang HG (2017) Ni2P(O)/Fe2P(O) interface can boost oxygen evolution electrocatalysis. ACS Energy Lett 2:2257–2263CrossRef
29.
Cai JM, Ruffieux P, Jaafar R, Bieri M, Braun T, Blankenburg S, Muoth M, Seitsonen AP, Saleh M, Feng XL, Müllen K, Fasel R (2010) Atomically precise bottom-up fabrication of graphene nanoribbons. Nature 466:470–473CrossRef
30.
Yan QM, Huang B, Yu J, Zheng FW, Zang J, Wu J, Gu BL, Liu F, Duan WH (2007) Intrinsic current-voltage characteristics of graphene nanoribbon transistors and effect of edge doping. Nano Lett 7:1469–1473CrossRef
31.
Li PP, Zheng YP, Shi T, Wang YD, Li MZ, Chen C, Zhang JX (2016) A solvent-free graphene oxide nanoribbon colloid as filler phase for epoxy-matrix composites with enhanced mechanical, thermal and tribological performance. Carbon 96:40–48CrossRef
32.
Zehtab YA, Chizari K, Jalilov AS, Tour J, Sundararaj U (2015) Helical and dendritic unzipping of carbon nanotubes: a route to nitrogen-doped graphene nanoribbons. ACS Nano 9:5833–5845CrossRef
33.
John R, Shinde DB, Liu L, Ding F, Xu Z, Vijayan C, Pillai VK, Pradeep T (2014) Sequential electrochemical unzipping of single-walled carbon nanotubes to graphene ribbons revealed by in situ raman spectroscopy and imaging. ACS Nano 8:234–242CrossRef
34.
Higginbotham AL, Kosynkin DV, Alexander S, Zhengzong S, Tour JM (2010) Lower-defect graphene oxide nanoribbons from multiwalled carbon nanotubes. ACS Nano 4:2059–2069CrossRef
35.
Dimiev AM, Khannanov A, Vakhitov I, Kiiamov A, Shukhina K, Tour JM (2018) Revisiting the mechanism of oxidative unzipping of multiwall carbon nanotubes to graphene nanoribbons. ACS Nano 12:3985–3993CrossRef
36.
Fortunato GV, Lima FD, Maia G (2016) Oxygen-reduction reaction strongly electrocatalyzed by Pt electrodeposited onto graphene or graphene nanoribbons. J Power Sources 302:247–258CrossRef
37.
Long JL, Xie XQ, Xu J, Gu Q, Chen LM, Wang XX (2012) Nitrogen-doped graphene nanosheets as metal-free catalysts for aerobic selective oxidation of benzylic alcohols. ACS Catal 2:622–631CrossRef
38.
Xie H, Tang SC, Gong ZL, Vongehr S, Fang F, Li M, Meng XK (2014) 3D nitrogen-doped graphene/Co(OH)2-nanoplate composites for high-performance electrochemical pseudocapacitors. RSC Adv 4:61753–61758CrossRef
39.
Liu ZP, Ma RZ, Osada M, Takada K, Sasaki T (2005) Selective and controlled synthesis of α-and β-cobalt hydroxides in highly developed hexagonal platelets. J Am Chem Soc 127:13869–13874CrossRef
40.
Yang ZB, Liu MK, Zhang C, Tjiu WW, Liu TX, Peng HS (2013) Carbon nanotubes bridged with graphene nanoribbons and their use in high-efficiency dye-sensitized solar cells. Angew Chem Int Ed 52:3996–3999CrossRef
41.
Wu ZL, Li CK, Yu JG, Chen XQ (2017) MnO2/reduced graphene oxide nanoribbons: facile hydrothermal preparation and their application in amperometric detection of hydrogen peroxide. Sens Actuators, B 239:544–552CrossRef
42.
Aghazadeh M, Shiri HM, Barmi AAM (2013) Uniform Co(OH)2 disc-like nanostructures prepared by low-temperature electrochemical rout as an electrode material for supercapacitors. Appl Surf Sci 273:237–242CrossRef
43.
Chen S, Qiao SZ (2013) Hierarchically porous nitrogen-doped graphene-NiCo2O4 hybrid paper as an advanced electrocatalytic water-splitting material. ACS Nano 7:10190–10196CrossRef
44.
Fan XB, Peng WC, Li Y, Li XY, Wang SL, Zhang GL, Zhang FB (2010) Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv Mater 20:4490–4493CrossRef
45.
Zhang LJ, Zheng R, Li S, Liu BK, Wang DJ, Wang LL, Xie TF (2014) Enhanced photocatalytic H2 generation on cadmium sulfide nanorods with cobalt hydroxide as cocatalyst and insights into their photogenerated charge transfer properties. ACS Appl Mater Interfaces 6:13406–13412CrossRef
Metadaten
Titel
Fabrication of dispersive α-Co(OH)2 nanosheets on graphene nanoribbons for boosting their oxygen evolution performance
verfasst von
Jingyun Wang
Yipeng Bao
Cao Cui
Zhenyu Zhang
Shumin Li
Jiami Pan
Yingying Zhang
Gaomei Tu
Jin Wang
Zhengquan Li
Publikationsdatum
13.02.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03421-y

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