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Journal of Materials Science

Erschienen in:

01.07.2014

Facile synthesis of Au nanoparticles supported on polyphosphazene functionalized carbon nanotubes for catalytic reduction of 4-nitrophenol

verfasst von: Xuzhe Wang, Jianwei Fu, Minghuan Wang, Yajie Wang, Zhimin Chen, Jianan Zhang, Jiafu Chen, Qun Xu

Erschienen in: Journal of Materials Science | Ausgabe 14/2014

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Abstract

Carbon nanotubes (CNTs) functionalized with cyclotriphosphazene-containing polyphosphazenes (PZS) were found to cause the facile immobilization of Au nanoparticles on the surface. The PZS functional layers not only improved the dispersion of CNTs in aqueous solution but also used as a platform for subsequent immobilization of Au nanoparticles. The functionalized CNTs and the Au@PZS@CNTs nanohybrids were characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectrometer, X-ray diffraction, thermogravimetric analysis, Atomic absorption spectrum, and X-ray photoelectron spectroscopy. The results showed that the PZS layers with thickness of about 25 nm were formed uniformly on CNT surfaces by polycondensation between hexachlorocyclotriphosphazene and 4,4′-sulfonyldiphenol, and that high density of homogeneously dispersed spherical Au nanoparticles with average size of 6 nm was immobilized on their outer surface. Meanwhile, the catalytic activity and reusability of the Au@PZS@CNTs nanohybrids were investigated by employing the reduction of 4-nitrophenol into 4-aminophenol by NaBH₄ as a model reaction.

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Titel: Facile synthesis of Au nanoparticles supported on polyphosphazene functionalized carbon nanotubes for catalytic reduction of 4-nitrophenol
verfasst von: Xuzhe Wang
Jianwei Fu
Minghuan Wang
Yajie Wang
Zhimin Chen
Jianan Zhang
Jiafu Chen
Qun Xu
Publikationsdatum: 01.07.2014
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 14/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-014-8212-5

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