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25.04.2016 | Original Paper

Facile synthesis of graphene oxide sheet-immobilized perylene diimide radical anion salt and its optical response to different solvents and pH values

verfasst von: Enfang He, Jianmin Wang, Hai Xu, Zemin He, Hailong Wang, Hang Zhao, Yingying Zhang, Ruijun Zhang, Haiquan Zhang

Erschienen in: Journal of Materials Science | Ausgabe 14/2016

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Abstract

Graphene oxide/reduced perylene diimide radical anion hybrid (GO/rSFPDI) with high dispersibility in polar organic solvents has been flexibly developed using N,N′-diethylhexyl-1-bromo-7-pentafluorophenox-perylene diimide (SFPDI). The interaction of the GO with the SFPDI suggested the catalysis of perylene diimide (SFPDI) to reduced perylene diimide radical anion (rSFPDI). The successful preparation of GO/rSFPDI was confirmed via FT-IR, Raman, UV–Vis absorption spectrum, XRD, and SEM. Compared to the two neutral SFPDI and GO, GO/rSFPDI exhibited a novel lower energy electronic transition (max. at 700 nm) in addition to the solvatochromism and characteristics of spectral response to pH. Moreover, the fluorescence emission spectrum of GO/rSFPDI shows strong fluorescence quenching in dilute solution.

Vorheriger Artikel Phase transformation and mechanical behaviour of thermo-mechanically controlled processed high-strength multiphase steel

Nächster Artikel Self-supported ultrathin mesoporous CoFe2O4/CoO nanosheet arrays assembled from nanowires with enhanced lithium storage performance

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Titel: Facile synthesis of graphene oxide sheet-immobilized perylene diimide radical anion salt and its optical response to different solvents and pH values
verfasst von: Enfang He
Jianmin Wang
Hai Xu
Zemin He
Hailong Wang
Hang Zhao
Yingying Zhang
Ruijun Zhang
Haiquan Zhang
Publikationsdatum: 25.04.2016
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 14/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-016-9885-8

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