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Journal of Nanoparticle Research

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01.07.2013 | Research Paper

Fast, microwave-assisted synthesis of monodisperse HfO₂ nanoparticles

verfasst von: Jonathan De Roo, Katrien De Keukeleere, Jonas Feys, Petra Lommens, Zeger Hens, Isabel Van Driessche

Erschienen in: Journal of Nanoparticle Research | Ausgabe 7/2013

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Abstract

A conventional solvothermal synthesis was compared to a microwave-assisted method for the synthesis of HfO₂ nanoparticles. In a microwave, the reaction could be completed in 3 h, compared to 3 days in an autoclave. In the microwave synthesis, the ensemble of particles was found to have a better size dispersion and a smaller average size (4 nm). The reaction mechanism was investigated and proof for an ether elimination process was provided. Post-synthetic modification with dopamine or dodecanoic acid permitted the suspension of the synthesized particles in both polar and apolar solvents, which is an advantage for further processing.

Vorheriger Artikel Carbon-dot organic surface modifier analysis by solution-state NMR spectroscopy

Nächster Artikel Epithelial cell biocompatibility of silica nanospheres for contrast-enhanced ultrasound molecular imaging

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Titel: Fast, microwave-assisted synthesis of monodisperse HfO2 nanoparticles
verfasst von: Jonathan De Roo
Katrien De Keukeleere
Jonas Feys
Petra Lommens
Zeger Hens
Isabel Van Driessche
Publikationsdatum: 01.07.2013
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 7/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-013-1778-z

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