Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2020

16.07.2020 | Original Paper: Sol-gel, hybrids and solution chemistries

Fast responsive thermally stable silica microspheres for sensing evaluation: sol–gel approach

verfasst von: Shumaila Islam, Hazri Bakhtiar, Adil Alshoaibi, Zuhaib Haider, Saira Riaz, Shahzad Naseem

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Cetyltrimethylammonium bromide (CTAB) micelle-templated mesoporous SiO2 particles (MSPs) are synthesized by sol–gel method. The CTAB templated SiO2 particles (SPs) possessed spherical structure with low average surface roughness (Ra) 1 nm. The CTAB template is effectively removed from SPs by 400 °C heat treatment without any cracks and disruption of the bonding between the functional groups and the SiO2 surface. After CTAB template removal, SiO2 microspheres (SMSs) possessed high surface area 640 m2/g, pore radius 10 nm, and Ra ~ 4.4 nm, making them highly attractive for sensing. Thermal gravimetric analysis (TGA) confirmed that SMSs are thermally stable, showing 0.7% weight loss after 429 °C temperature. Phenol red immobilized SMSs show large pKa value 8.1 at 560 nm. Good repeatability, no leaching traces, and fast response time ~0.09 s in basic media suggested that proposed material has potential for opto-chemical sensing/photonic applications.
Vorheriger Artikel A comparative study of microstructure, magnetic, and electromagnetic properties of Zn2W hexaferrite prepared by sol–gel and solid-state reaction methods
Nächster Artikel Microencapsulated phase change materials composited Al2O3–SiO2 aerogel and the thermal regulation properties

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Islam S, Bakhtiar H, Bidin N, Salim AA, Riaz S, Krishnan G, Naseem S (2018) Crack-free high surface area silica-titania nanocomposite coating as opto-chemical sensor device. Sens Actuators A 270:153–161CrossRef
2.
Rodrigues CF, Reis CA, Moreira AF, Ferreira P, Correi IJ (2019) Optimization of gold core-mesoporous silica shell functionalization with TPGS and PEI for cancer therapy. Microporous Mesoporous Mater 285:1–12CrossRef
3.
Xua J, Hong Y, Cheng M, Xue B, Li YX (2019) Vanadyl acetylacetonate grafted on ordered mesoporous silica KIT-6 and itsenhanced catalytic performance for direct hydroxylation of benzene to phenol. Microporous Mesoporous Mater 285:223–230CrossRef
4.
R-Malherbe R, Marque F (2004) Synthesis and characterization of silica microsphere-based mesoporous materials. Mater Sci Semiconductor Process 7:467–469CrossRef
5.
Gupta BD, Sharma DK (1997) Evanescent wave absorption based fiber optic pH sensor prepared by dye doped sol–gel immobilization technique. Opt Commun 140:32–35CrossRef
6.
Rutledge H, Oliva-Chatelain BL, Maguire-Boyle SJ, Flood DL, Barron AR (2014) Imbedding germanium quantum dots in silica by a modified Stöber method. Mater Sci Semiconductor Process 17:7–12CrossRef
7.
Kim B, Yang I, Jung JC, Seung Lee T, Yeom B (2019) Titania nanoparticle-loaded mesoporous silica synthesized through layer-bylayer assembly for the photodegradation of sodium dodecylbenzenesulfonate. Appl Surf Sci 490:38–46CrossRef
8.
Grau EN, Roman G, Díaz Compañy A, Brizuela G, Juan A, Simonetti S (2019) Surface modification vs sorption strength: study of nedaplatin drug supported on silica. Appl Surf Sci 465:693–699CrossRef
9.
Cheng X, Liu S, Lu L, Sui X, Meynen V, Cool P, Vansant EF, Jiang J (2007) Fast fabrication of hollow silica spheres with thermally stable nanoporous shells. Microporous Mesoporous Mater 98:41–46CrossRef
10.
Ottaviani MF, Moscatelli A, Desplantier-Giscard D, Renzo FD, Kooyman PJ, Alonso B, Galarneau A (2004) Synthesis of micelle-templated silicas from cetyltrimethylammonium bromide/1,3,5-trimethylbenzene micelles. J Phys Chem B 108:12123–12129CrossRef
11.
Venkatathri N, Nanjundan S (2009) Synthesis and characterization of a mesoporous silica microsphere from polystyrene. Mater Chem Phys 113:933–936CrossRef
12.
Yongqi H, Zhao H, Li Y (2008) Synthesis method for silica needleshaped nano-hollow structure. Mater Lett 62:3401–3403CrossRef
13.
Venkatathri N (2007) Synthesis of mesoporous silica nanosphere using different templates. Solid State Commun 143:493–497CrossRef
14.
Singh LP, Bhattacharyya SK, Mishra G, Ahalawat S (2011) Functional role of cationic surfactant to control the nano size of silica powder. Appl Nanosci 1:117–122CrossRef
15.
Gonçalves MC (2018) Sol-gel silica nanoparticles in medicine: a natural choice. design, synthesis and products. Molecules 23:2021CrossRef
16.
17.
Avossaa J, Bifulcoa A, Amendolab E, Gesuelec F, Oscuratoc SL, Gizawd Y, Mensitieria G, Brandaa F (2019) Forming nanostructured surfaces through Janus colloidal silica particleswith nanowrinkles: a new strategy to superhydrophobicity. Appl Surf Sci 465:73–81CrossRef
18.
Saidi IA, Sadik F (2016) Synthesis and investigation of phenol red dye doped polymer films. Adv Mater Phys Chem 6:120–128CrossRef
19.
Zulfiqar U, Subhani T, Husain SW (2016) Synthesis and characterization of silica nanoparticles from clay. J Asian Ceram Societies 4:91–96CrossRef
20.
Loryuenyong V, Muanghom T, Apinyanukul T, Rutthongjan P (2011) Synthesis of templated mesoporous silica nanoparticles under base catalysis. Adv Appl Ceram 110:335–340CrossRef
21.
Rameli N, Jumbri K, Wahab RA, Ramli A, Huyop F (2018) Synthesis and characterization of mesoporous silica nanoparticles using ionic liquids as a template. IOP Conf Ser 1123:012068CrossRef
22.
Wu S, Moua C, Lin H (2013) Synthesis of mesoporous silica nanoparticles. Chem Soc Rev 42:3862–3875CrossRef
23.
Veerapandian M, Yun K (2013) Methylene blue dye coated silver–silica nanoparticles with dual functionality fabricated by injection pump and ultrasonochemistry. Mater Res Bull 48:1817–1823CrossRef
24.
Islam S, Bakhtiar H, Haider Z, Riaz S, Naseem S, Chudhary S, Suan LP, Osman SS, Aziz MS (2019) BPB dye confined growth of surfactant assisted mesostructured silica matrix fiber optic sensing traces J Saudi Chem Soc 23(4):427–438CrossRef
25.
Schmid RD, Verger R (1998) Angew Chem Int Ed 37:1608
26.
Kachbouri S, Mnasri N, Elaloui E, Moussaoui Y (2018) Tuning particle morphology of mesoporous silica nanoparticles for adsorption of dyes from aqueous solution. J Saudi Chem Soc 22:405–415CrossRef
27.
Landers J, Gor GY, Neimark AV (2013) Density functional theory methods for characterization of porous materials. Colloids Surf A 437:3–32CrossRef
28.
Narayan R, Nayak UY, Raichur AM, Garg S (2018) Mesoporous silica nanoparticles: a comprehensive review on synthesis and recent advances. Pharmaceutics 10:118CrossRef
29.
Wanyika H, Gatebe E, Kioni P, Tang Z, Gao Y (2011) Synthesis and characterization of ordered mesoporous silica nanoparticles with tunable physical properties by varying molar composition of reagents, African. J Pharm Pharmacol 5:2402–2410
30.
Meng X, Wang Y, Wang H, Zhong J, Chen R (2013) Preparation of the multifunctional antireflective films from a templating composite silica sol with entwining structures. Surf Coat Technol 236:518–524CrossRef
31.
Lu P, Fu W, Huang S, Lin C, Ho M, Chen Y, Cheng H (2018) Methodology for sample preparation and size measurement of commercial ZnO nanoparticles. J food drug Anal 26:128–636
32.
33.
Chauhan SS, Jasra RV, Sharma AL (2012) Phenol red dye functionalized nanostructured silica films as optical filters and pH sensors. Ind Eng Chem Res 51:10381–10389CrossRef
34.
Wang E, Chow K-F, Kwan V, Chin T, Wong C, Bocarsly A (2003) Fast and long term optical sensors for pH based on sol–gels. Analytica Chim Acta 495:45–50CrossRef
35.
Alvarado-Mendez R-L, Andrade-Lucio R, Hernandez-Cruz D, Lessard RA, Avina-Cervantes JG (2005) Design and characterization of pH sensor based on sol–gel silica layer on plastic optical fiber. Sens Actuators B 106:518–522CrossRef
36.
Garcia-Heras M, Gil C, Carmona N, Faber J, Kromka K, Villegas MA (2005) Optical behavior of pH detectors based on sol–gel technology. Anal Chim Acta 540:147–152CrossRef
37.
Kassal P, Surina R, Vrsaljko D, Steinberg IM (2014) Hybrid sol–gel thin films doped with a pH indicator: effect of organic modification on optical pH response and film surface hydrophilicity. J Sol-Gel Sci Technol 69:586–595CrossRef
38.
Suah FBM, Ahmad M, Taib MN (2003) Applications of artificial neural network on signal processing of optical fibre pH sensor based on bromophenol blue doped with sol-gel film. Sens Actuators B 90:182–188CrossRef
39.
Islam S, Bidin N, Riaz S, Naseem S (2017) Self-assembled hierarchical phenolphthalein encapsulated silica nanoparticles: structural, optical and sensing response. Sens Actuators A 266:111–121CrossRef
40.
Makote R, Collinson MM (1999) Organically modified silicate films for stable pH sensors. Analytica Chim Acta 394:195–200CrossRef
41.
Yari A, Dinarvand M (2011) Sol-gel film doped with bromopyrogallol red as a highly sensitive sensing element for a new pH optical sensor. J Iran Chem Soc 8:1091–1097CrossRef
Metadaten
Titel
Fast responsive thermally stable silica microspheres for sensing evaluation: sol–gel approach
verfasst von
Shumaila Islam
Hazri Bakhtiar
Adil Alshoaibi
Zuhaib Haider
Saira Riaz
Shahzad Naseem
Publikationsdatum
16.07.2020
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2020
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-020-05366-0

Weitere Artikel der Ausgabe 3/2020

Journal of Sol-Gel Science and Technology 3/2020 Zur Ausgabe

Original Paper: Sol–gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Study of structural, optical, and dielectric properties of sol–gel derived ZnFe2O4–Al2O3 composite nanoparticles

Original Paper: Sol-gel, hybrids and solution chemistries

The effect of MgO addition on the properties of alumina-based ceramic cores prepared via sol–gel process

Review Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Role of starch in the ceramic powder synthesis: a review

Original Paper: Sol–gel and hybrid materials for energy, environment and building applications

Engineered surface properties of MAPI using different antisolvents for hole transport layer-free perovskite solar cell (HTL-free PSC)

Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Enhanced electrochemical performance of the YBa0.5Sr0.5Co1.4Cu0.6O5+δ cathode material by Sm0.2Ce0.8O1.9 incorporation for solid oxide fuel cells application

Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Investigation of morphological and electrical properties of RTA-processed TiO2 for memristor application

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise