nach oben

Polymer Bulletin

Erschienen in:

22.09.2017 | Original Paper

Free radical polymerization of polyvinyl butyral/polyethylene glycol diacrylate copolymer for removing organic dyes from waste water

verfasst von: Salah Lotfy, Manal Fawzy Abou Taleb

Erschienen in: Polymer Bulletin | Ausgabe 7/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Copolymers of polyvinyl butyral (PVB)/polyethylene glycol diacrylate (PEGDA) were prepared by free radical polymerization using gamma irradiation. The physical properties such as gelation, swelling and the thermal behavior of the prepared PVB/PEGDA copolymer were investigated as a function of molecular weight of PEGDA. The thermal behavior of blank PVB (PVB/PEGDA)-575 and (PVB/PEGDA)-750 copolymers as a function of absorbed dose up to 100 kGy was determined using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The thermal stability of the prepared copolymers was improved by gamma irradiation, PEGDA and the increasing of PEGDA molecular weight. Two textile dyes, Diamine Fast Scarlet GG and Direct Pink 3B, were used as model anionic dyes. The adsorption of PVB/PEGDA hydrogels of different molecular weights was investigated towards the two anionic dyes by the batch equilibrium method. The adsorption capacity of the copolymers was evaluated as a function of initial dye concentration, different molecular weight, and time. The equilibrium data obtained in batch experiments were correlated to Langmuir and Freundlich isotherm equations. Results showed that the adsorption of Direct Pink 3B fitted well to the Langmuir model, while the adsorption pattern of Diamine Fast Scarlet GG followed the Freundlich isotherm, which suggests heterogeneity of the adsorption sites on the copolymer. Thermodynamic data revealed spontaneous exothermic processes and was a physisorption reaction. Our results demonstrate that the PVB/PEGDA copolymer is very promising for removing organic dyes from waste water.

Vorheriger Artikel Improved electrical heating properties for polymer nanocomposites by electron beam irradiation

Nächster Artikel Rhodamine B-decorated poly(hydroxypropyl acrylate) and their effects on the self-assembly of breath figure arrays

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Sanghi R, Bhatttacharya B, Singh V (2002) Cassia angustifolia seed gum as an effective natural coagulant for decolourisation of dye solutions. Green Chem 4:252–254. doi:10.1039/b200067a CrossRef

Guendy HR (2010) Removal of Azo reactive, direct dyes from wastewater using different coagulants at different pH. J Appl Sci Res 6:956–963

El-Sigeny S, Mohamed SK, Abou Taleb MF (2014) Radiation synthesis and characterization of styrene/acrylic acid/organophilic montmorillonite hybrid nanocomposite for sorption of dyes from aqueous solutions. Polym Compos 35:2353–2364. doi:10.1002/pc.22902 CrossRef

Baseri JR, Palanisamy PN, Sivakumar P (2012) Comparative studies of the adsorption of direct dye on activated carbon and conducting polymer composite. J Chem 9:1122–1134

Kornaros M, Lyberatos G (2006) Biological treatment of wastewaters from a dye manufacturing company using a trickling filter. J Hazard Mater 136:95–102. doi:10.1016/j.jhazmat.2005.11.018 CrossRefPubMed

Zahrim AY, Tizaoui C, Hilal N (2011) Coagulation with polymers for nanofiltration pre-treatment of highly concentrated dyes: a review. Desalination 266:1–16. doi:10.1016/j.desal.2010.08.012 CrossRef

Zhao W, Wu Z, Wang D (2006) Ozone direct oxidation kinetics of cationic red X-GRL in aqueous solution. J Hazard Mater 137:1859–1865. doi:10.1016/j.jhazmat.2006.05.032 CrossRefPubMed

Capar G, Yetis U, Yilmaz L (2006) Membrane based strategies for the pre-treatment of acid dye bath wastewaters. J Hazard Mater 135:423–430. doi:10.1016/j.jhazmat.2005.12.008 CrossRefPubMed

Liu C, Wu J, Chiu H et al (2007) Removal of anionic reactive dyes from water using anion exchange membranes as adsorbers. Water Res 41:1491–1500. doi:10.1016/j.watres.2007.01.023 CrossRefPubMed

10.

Muruganandham M, Swaminathan M (2006) TiO2–UV photocatalytic oxidation of reactive yellow 14: effect of operational parameters. J Hazard Mater 135:78–86. doi:10.1016/j.jhazmat.2005.11.022 CrossRefPubMed

11.

Khan MA, Lee S-H, Kang S et al (2011) Adsorption studies for the removal of methyl tert-butyl ether on various commercially available gas from an aqueous medium. Sep Sci Technol 46:1121–1130. doi:10.1080/01496395.2010.551395 CrossRef

12.

Sheshmani S, Ashori A, Hasanzadeh S (2014) Removal of acid orange 7 from aqueous solution using magnetic graphene/chitosan: a promising nano-adsorbent. Int J Biol Macromol 68:218–224. doi:10.1016/j.ijbiomac.2014.04.057 CrossRefPubMed

13.

Cuerda-Correa EM, Domínguez-Vargas JR, Olivares-Marín FJ, de Heredia JB (2010) On the use of carbon blacks as potential low-cost adsorbents for the removal of non-steroidal anti-inflammatory drugs from river water. J Hazard Mater 177:1046–1053. doi:10.1016/j.jhazmat.2010.01.026 CrossRefPubMed

14.

Malarvizhi R, Ho Y-S (2010) The influence of pH and the structure of the dye molecules on adsorption isotherm modeling using activated carbon. Desalination 264:97–101. doi:10.1016/j.desal.2010.07.010 CrossRef

15.

Ignat M-E, Dulman V, Onofrei T (2012) Reactive Red 3 and direct brown 95 dyes adsorption onto chitosan. Cellul Chem Technol 46:357–367

16.

Abou Taleb MF, Hegazy DE, Ismail SA (2012) Radiation synthesis, characterization and dye adsorption of alginate-organophilic montmorillonite nanocomposite. Carbohydr Polym. doi:10.1016/j.carbpol.2011.10.058 CrossRef

17.

Taleb MFA, El-Mohdy HLA, El-Rehim HAA (2009) Radiation preparation of PVA/CMC copolymers and their application in removal of dyes. J Hazard Mater. doi:10.1016/j.jhazmat.2009.02.001 CrossRefPubMed

18.

Denizli A, Tanyolaç D, Salih B et al (1997) Adsorption of heavy-metal ions on Cibacron Blue F3GA-immobilized microporous polyvinylbutyral-based affinity membranes. J Memb Sci 137:1–8. doi:10.1016/S0376-7388(97)00172-5 CrossRef

19.

Singh V, Kumari PL, Tiwari A, Pandey S (2010) Alumina-supported microwave synthesis of cassia marginata seed gum-graft-polyacrylamide. J Appl Polym Sci 117:3630–3638

20.

Pandey S, Tiwari S (2015) Facile approach to synthesize chitosan based composite—characterization and cadmium(II) ion adsorption studies. Carbohydr Polym 134:646–656. doi:10.1016/j.carbpol.2015.08.027 CrossRefPubMed

21.

Pandey S, Ramontja J (2016) Natural bentonite clay and its composites for dye removal: current state and future potential. Am J Chem Appl 3:8–19

22.

Panic VV, Madzarevic ZP, Volkov-Husovic T, Velickovic SJ (2013) Poly(methacrylic acid) based hydrogels as sorbents for removal of cationic dye basic yellow 28: kinetics, equilibrium study and image analysis. Chem Eng J 217:192–204. doi:10.1016/j.cej.2012.11.081 CrossRef

23.

Abdel-Halim ES, Al-Deyab SS (2011) Hydrogel from crosslinked polyacrylamide/guar gum graft copolymer for sorption of hexavalent chromium ion. Carbohydr Polym 86:1306–1312. doi:10.1016/j.carbpol.2011.06.033 CrossRef

24.

Chen K, Liu C, Huang H et al (2013) Polyvinyl butyral-based thin film polymeric electrolyte for dye-sensitized solar cell with long-term stability. Int J Electrochem Sci 8:3524–3539

25.

Ma X, Sun Q, Su Y et al (2007) Antifouling property improvement of poly(vinyl butyral) ultrafiltration membranes through acid treatment. Sep Purif Technol 54:220–226. doi:10.1016/j.seppur.2006.09.006 CrossRef

26.

Bhattacharyya R, Ray SK (2015) Removal of congo red and methyl violet from water using nano clay filled composite hydrogels of poly acrylic acid and polyethylene glycol. Chem Eng J 260:269–283. doi:10.1016/j.cej.2014.08.030 CrossRef

27.

Dhaliwal AK, Hay JN (2002) The characterization of polyvinyl butyral by thermal analysis. Thermochim Acta 391:245–255. doi:10.1016/S0040-6031(02)00187-9 CrossRef

28.

Son K, Lee J (2016) Synthesis and characterization of poly(ethylene glycol) based thermo-responsive hydrogels for cell sheet engineering. Materials (Basel) 9:854. doi:10.3390/ma9100854 CrossRef

29.

Padmavathi NC, Chatterji PR (1996) Structural characteristics and swelling behavior of poly(ethylene glycol) diacrylate hydrogels ^†. Macromolecules 29:1976–1979. doi:10.1021/ma950827r CrossRef

30.

Weber LM, Lopez CG, Anseth KS (2009) Effects of PEG hydrogel crosslinking density on protein diffusion and encapsulated islet survival and function. J Biomed Mater Res, Part A 90A:720–729. doi:10.1002/jbm.a.32134 CrossRef

31.

Hamid ZAA, Lim KW (2016) Evaluation of UV-crosslinked Poly(ethylene glycol) Diacrylate/Poly(dimethylsiloxane) dimethacrylate hydrogel: properties for tissue engineering application. Procedia Chem 19:410–418. doi:10.1016/j.proche.2016.03.032 CrossRef

32.

Salam LA, Matthews RD, Robertson H (2000) Pyrolysis of polyvinyl butyral (PVB) binder in thermoelectric green tapes. J Eur Ceram Soc 20:1375–1383. doi:10.1016/S0955-2219(99)00236-8 CrossRef

33.

Koysuren O, Karaman M, Dinc H (2012) Preparation and characterization of polyvinyl borate/polyvinyl alcohol (PVB/PVA) blend nanofibers. J Appl Polym Sci 124:2736–2741. doi:10.1002/app.35035 CrossRef

34.

Cheng Y-L, Chen F (2017) Preparation and characterization of photocured poly (ε-caprolactone) diacrylate/poly (ethylene glycol) diacrylate/chitosan for photopolymerization-type 3D printing tissue engineering scaffold application. Mater Sci Eng, C 81:66–73. doi:10.1016/j.msec.2017.07.025 CrossRef

35.

Fawzy YHA, Radwan RM (2007) Conduction mechanism in electron beam-irradiated unplasticized PVC/PVA copolymer films under high electric field. Phys B Condens Matter 395:79–83. doi:10.1016/j.physb.2007.02.059 CrossRef

36.

Mandelkern L (1964) Crystallization of polymers, 38th edn. McGraw-Hill, New York

37.

Nouh S (1999) The effect of UV radiation on the thermal degradation of cellulose triacetate. Radiat Meas 30:753–757. doi:10.1016/S1350-4487(99)00234-6 CrossRef

38.

Qin X-X, Cheng Z-L (2016) Application of ionic liquids as a catalyst in the synthesis of polyvinyl butyral (PVB) polymer. Chinese Chem Lett 27:145–148. doi:10.1016/j.cclet.2015.07.012 CrossRef

39.

Wang Y-J, Kim D (2007) PEGDA/PVdF/F127 gel type polymer electrolyte membranes for lithium secondary batteries. J Power Sources 166:202–210. doi:10.1016/j.jpowsour.2007.01.016 CrossRef

40.

Mohammadian-Kohol M, Asgari M, Shakur HR (2016) A detailed investigation of the gamma-ray radiation effects on the optical properties of polyvinyl butyral film. Opt Int J Light Electron Opt 127:7459–7468. doi:10.1016/j.ijleo.2016.05.076 CrossRef

41.

Don T-M, Chen C-C, Lee C-K et al (2005) Preparation and antibacterial test of chitosan/PAA/PEGDA bi-layer composite membranes. J Biomater Sci Polym Ed 16:1503–1519CrossRefPubMed

42.

Kang G, Cao Y, Zhao H, Yuan Q (2008) Preparation and characterization of crosslinked poly(ethylene glycol) diacrylate membranes with excellent antifouling and solvent-resistant properties. J Memb Sci 318:227–232. doi:10.1016/j.memsci.2008.02.045 CrossRef

43.

Ju H, McCloskey BD, Sagle AC et al (2009) Preparation and characterization of crosslinked poly(ethylene glycol) diacrylate hydrogels as fouling-resistant membrane coating materials. J Memb Sci 330:180–188. doi:10.1016/j.memsci.2008.12.054 CrossRef

44.

Hajian M, Reisi MR, Koohmareh GA, Zanjani Jam AR (2012) Preparation and characterization of Polyvinylbutyral/Graphene Nanocomposite. J Polym Res 19:9966. doi:10.1007/s10965-012-9966-6 CrossRef

45.

Rahman MT, Barikbin Z, Badruddoza AZM et al (2013) Monodisperse polymeric ionic liquid microgel beads with multiple chemically switchable functionalities. Langmuir 29:9535–9543. doi:10.1021/la401613w CrossRefPubMed

46.

Rydholm AE, Reddy SK, Anseth KS, Bowman CN (2006) Controlling Network Structure in Degradable Thiol − Acrylate Biomaterials to Tune Mass Loss Behavior. Biomacromol 7:2827–2836. doi:10.1021/bm0603793 CrossRef

47.

Niu G, Song L, Zhang H et al (2010) Application of thiol-ene photopolymerization for injectable intraocular lenses: a preliminary study. Polym Eng Sci 50:174–182. doi:10.1002/pen.21465 CrossRef

48.

El-kelesh NA, Mahmoud GA (2015) Synthesis and properties of treated waste cellulose and GMA grafted composite to remove different acid dyes from aqueous solutions. Cellul Chem Technol 49:881–889

49.

Fleischmann C, Lievenbrück M, Ritter H (2015) Polymers and dyes: developments and applications. Polymers (Basel) 7:717–746. doi:10.3390/polym7040717 CrossRef

50.

Saraya MEI, Nassar HS (2015) Removal of reactive blue7 dye from aqueous solution using solid waste 3:19–36

51.

Abou Taleb MF, El-Trass A, El-Sigeny S (2015) Synthesis of polyamidoamine dendrimer (PAMAM/CuS/AA) nanocomposite and its application in the removal of Isma acid fast yellow G Dye. Polym Adv Technol 26:994–1002. doi:10.1002/pat.3517 CrossRef

52.

Pandey S, Mishra SB (2013) Chromatographic resolution of racemic??-amino acids: chiral stationary phase derived from modified xanthan gum. Carbohydr Polym 92:2201–2205. doi:10.1016/j.carbpol.2012.11.102 CrossRefPubMed

53.

Singh V, Singh SK, Pandey S, Sanghi R (2010) Adsorption behavior of potato starch-silica nanobiocomposite. Adv Mater Lett 1:40–47. doi:10.5185/amlett.2010.4107 CrossRef

54.

Tan IAW, Ahmad AL, Hameed BH (2008) Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: equilibrium, kinetic and thermodynamic studies. J Hazard Mater 154:337–346. doi:10.1016/j.jhazmat.2007.10.031 CrossRefPubMed

55.

Konicki W, Aleksandrzak M, Mijowska E (2017) Equilibrium, kinetic and thermodynamic studies on adsorption of cationic dyes from aqueous solutions using graphene oxide. Chem Eng Res Des. doi:10.1016/j.cherd.2017.03.036 CrossRef

Titel: Free radical polymerization of polyvinyl butyral/polyethylene glycol diacrylate copolymer for removing organic dyes from waste water
verfasst von: Salah Lotfy
Manal Fawzy Abou Taleb
Publikationsdatum: 22.09.2017
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 7/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-017-2185-x

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 7/2018

Difluoroboranyl derivatives as efficient panchromatic photoinitiators in radical polymerization reactions

Hydrogen effects in TiCl4/MgCl2/THF catalysts with second Lewis acid addition on ethylene polymerization behaviors

Band structure and optical properties of polyaniline polymer material

Improved electrical heating properties for polymer nanocomposites by electron beam irradiation

Investigation and fine-tuning of optoelectrical features of tertiary aminophenyl-activated poly(1,3,4-oxadiazole) conjugated system

Synthesis and CO2 permeation properties of novel sulfonium-substituted poly(diphenylacetylene)s

Premium Partner

Marktübersichten