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Erschienen in:
In Situ Chemical Oxidation: Technology Description and Status Kapitel lesen Erstes Kapitel lesen

2011 | OriginalPaper | Buchkapitel

2. Fundamentals of ISCO Using Hydrogen Peroxide

verfasst von : Benjamin G. Petri, Richard J. Watts, Amy L. Teel, Scott G. Huling, Richard A. Brown

Erschienen in: In Situ Chemical Oxidation for Groundwater Remediation

Verlag: Springer New York

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Scope

Chemistry and use of hydrogen peroxide for in situ chemical oxidation (ISCO) of subsurface contaminants, including free radical and other reaction mechanisms, catalysts, and reactive transport.

Key Concepts

  • Hydrogen peroxide reaction chemistry is complex, but potentially capable of degrading a wide range of organic contaminants depending on conditions.
  • Ferrous [Fe(II)] and ferric [Fe(III)] iron, iron and manganese soil minerals, and other metals in solution may catalyze hydrogen peroxide to form free radicals. These catalysts may be naturally present in the matrix, or added during ISCO to augment the reaction.
  • pH has a strong effect on hydrogen peroxide chemistry and effectiveness. pH impacts catalyst solubility and reactivity towards hydrogen peroxide, as well as the radicals formed and the degradation of target contaminants. Some hydrogen peroxide applications include the injection of amendments (acids or alkalis) to modify pH to an optimal range.
  • Radicals known to play significant roles in hydrogen peroxide chemistry include the hydroxyl radical (OH⋅), superoxide radical (O2⋅−), and perhydroxyl radical (HO2⋅).
  • Different radicals dominate the reaction under different chemistry conditions, and are controlled by parameters such as concentration of the oxidant, catalyst, organic or inorganic solutes, and pH. This can affect performance as some contaminants may only degrade under specific chemistry conditions.
  • Carbonate, bicarbonate, chloride, other inorganic ions, and hydrogen peroxide itself are reactive with radicals and may affect reaction efficiency and effectiveness.
  • The lifetime of hydrogen peroxide in the subsurface is short, generally hours to days.
  • The reactive transport of hydrogen peroxide in the subsurface is limited, primarily because of its fast reaction rate.

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Vorheriges Kapitel In Situ Chemical Oxidation: Technology Description and Status
Nächstes Kapitel Fundamentals of ISCO Using Permanganate
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Metadaten
Titel
Fundamentals of ISCO Using Hydrogen Peroxide
verfasst von
Benjamin G. Petri
Richard J. Watts
Amy L. Teel
Scott G. Huling
Richard A. Brown
Copyright-Jahr
2011
Verlag
Springer New York
Buch
In Situ Chemical Oxidation for Groundwater Remediation

Print ISBN: 978-1-4419-7825-7

Electronic ISBN: 978-1-4419-7826-4

Copyright-Jahr: 2011

DOI
https://doi.org/10.1007/978-1-4419-7826-4_2