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07.09.2021 | Ceramics

Glass structure of industrial ground granulated blast furnace slags (GGBS) investigated by time-resolved Raman and NMR spectroscopies

verfasst von: Simon Blotevogel, Valérie Montouillout, Aurélien Canizares, Patrick Simon, Erwan Chesneau, Abel Danezan, Thomas Wattez, Andreas Ehrenberg, Mathilde Poirier, Cédric Patapy, Martin Cyr

Erschienen in: Journal of Materials Science | Ausgabe 31/2021

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Abstract

Ground granulated blast furnace slags (GGBS) are glassy by-products from iron production that are commonly used as supplementary cementitious materials in blended cements. The glass structure of seven industrial GGBS was investigated by Raman and nuclear magnetic resonance spectroscopies. The complex composition of the slags induced multiple analytical challenges. Under usual continuous excitation, the Raman signal was masked by strong luminescence, so that analysis was carried out on a time-resolved Raman (TRR) device. TRR allowed to eliminate luminescence and resulted in exploitable spectra that showed variations in line with theoretical NBO/T values. The analysis of ²⁷Al and ²⁹Si NMR spectra was complicated by the presence of paramagnetic nuclei and the wide variety of environments. Nevertheless, ²⁷Al NMR showed that Al was present as a network former, mainly in fourfold coordination and careful analyses of ²⁹Si NMR spectra allowed the comparison of glass network polymerization of industrial GGBS in line with the theoretical NBO/T based on their composition.

Vorheriger Artikel Formation and elimination mechanism of thermal blistering in Al2O3/Si system

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Titel: Glass structure of industrial ground granulated blast furnace slags (GGBS) investigated by time-resolved Raman and NMR spectroscopies
verfasst von: Simon Blotevogel
Valérie Montouillout
Aurélien Canizares
Patrick Simon
Erwan Chesneau
Abel Danezan
Thomas Wattez
Andreas Ehrenberg
Mathilde Poirier
Cédric Patapy
Martin Cyr
Publikationsdatum: 07.09.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 31/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-06446-4

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