nach oben

Journal of Materials Science

Erschienen in:

16.08.2021 | Energy materials

Nitrogen-doped biomass-derived porous carbon spheres for supercapacitors with ultrafast charge/discharge rate up to 2.5 V s⁻¹

verfasst von: Jingting Bu, Zhipeng Zhou, Xiaomin Wu, Chenying Zhang, Zhen Li

Erschienen in: Journal of Materials Science | Ausgabe 31/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Biomass-derived carbon materials are often applied in green energy storage systems like supercapacitors due to the abundance, facile access, low cost and nontoxicity. In this work, biomass-derived porous carbon spheres (PCSs) have been prepared by the carbonization and etching of sodium alginate (SA). Using polyacrylic acid (PAA) as a template, N-doped graphene quantum dots (N-GQDs) are grown evenly on the surface of the PCSs, which drastically improves the pseudocapacitive activity and electrical conductivity. The prepared N-GQD/PCS/PAA electrode has a remarkable specific capacitance of 419.3 F g⁻¹ at 1 A g⁻¹. The symmetric supercapacitor assembled with N-GQD/PCS/PAA electrode exhibits a great specific capacitance of 337.5 F g⁻¹ at 0.5 A g⁻¹. Particularly, the device displays an ultrafast charge/discharge rate of 2.5 V s⁻¹, demonstrating excellent rate capability and structural stability. The supercapacitor based on N-GQD/PCS/PAA possesses high energy density of 11.72 W h kg⁻¹ and excellent cycle stability. A high mass loading (9.18 mg cm⁻²) with the energy density of 8.54 W h kg⁻¹ is also investigated to realize the practical application for the device. In general, a novel biomass-derived carbon electrode modified with highly electrochemical active N-doped graphene quantum dots has been constructed to provide an effective way for high performance energy storage.

Vorheriger Artikel Utilization of impurities and carbon defects in natural microcrystalline graphite to prepare silicon-graphite composite anode for high-performance lithium-ion batteries

Nächster Artikel Boosting hydrogen production via urea electrolysis on an amorphous nickel phosphide/graphene hybrid structure

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Chai D, Gómez-García CJ, Li B, Pang H, Ma H, Wang X, Tan L (2019) Polyoxometalate-based metal-organic frameworks for boosting electrochemical capacitor performance. Chem Eng J 373:587–597. https://doi.org/10.1016/j.cej.2019.05.084CrossRef

Jeyaranjan A, Sakthivel TS, Neal CJ, Seal S (2019) Scalable ternary hierarchical microspheres composed of PANI/ rGO/CeO₂ for high performance supercapacitor applications. Carbon 151:192–202. https://doi.org/10.1016/j.carbon.2019.05.043CrossRef

Pawar SA, Kim D, Lee R, Kang S-W, Patil DS, Kim TW, Shin JC (2019) Efficient supercapacitor based on polymorphic structure of 1T′-Mo₆Te₆ nanoplates and few-atomic-layered 2H-MoTe₂: A layer by layer study on nickel foam. Chem Eng J 371:182–192. https://doi.org/10.1016/j.cej.2019.04.009CrossRef

Wei J, Luo C, Li H, Lv W, Liang J, Deng Y, Huang Z, Wang C, Kang F, Yang Q-H (2019) Direct assembly of micron-size porous graphene spheres with a high density as supercapacitor materials. Carbon 149:492–498. https://doi.org/10.1016/j.carbon.2019.04.071CrossRef

Lv S, Ma L, Shen X, Tong H (2020) Recent design and control of carbon materials for supercapacitors. J Mater Sci 56(3):1919–1942. https://doi.org/10.1007/s10853-020-05351-6CrossRef

Zhai T, Sun S, Liu X, Liang C, Wang G, Xia H (2018) Achieving insertion-like capacity at ultrahigh rate via tunable surface pseudocapacitance. Adv Mater 30(12):e1706640. https://doi.org/10.1002/adma.201706640CrossRef

Zhao H, Liu L, Fang Y, Vellacheri R, Lei Y (2018) Nickel nanopore arrays as promising current collectors for constructing solid-state supercapacitors with ultrahigh rate performance. Front Chem Sci Eng 12(3):339–345. https://doi.org/10.1007/s11705-018-1699-6CrossRef

Zhong Y, Shi T, Huang Y, Cheng S, Liao G, Tang Z (2018) One-step synthesis of porous carbon derived from starch for all-carbon binder-free high-rate supercapacitor. Electrochim Acta 269:676–685. https://doi.org/10.1016/j.electacta.2018.03.012CrossRef

Liu Z, Wu ZS, Yang S, Dong R, Feng X, Mullen K (2016) Ultraflexible in-plane micro-supercapacitors by direct printing of solution-processable electrochemically exfoliated graphene. Adv Mater 28(11):2217–2222. https://doi.org/10.1002/adma.201505304CrossRef

10.

Sun G, Zhang X, Lin R, Chen B, Zheng L, Huang X, Huang L, Huang W, Zhang H, Chen P (2016) Weavable, high-performance, solid-state supercapacitors based on hybrid fibers made of sandwiched structure of MWCNT/rGO/MWCNT. Adv Electron Mater 2(7):1600102. https://doi.org/10.1002/aelm.201600102CrossRef

11.

Lv Q, Chi K, Zhang Y, Xiao F, Xiao J, Wang S, Loh KP (2017) Ultrafast charge/discharge solid-state thin-film supercapacitors via regulating the microstructure of transition-metal-oxide. J Mater Chem A 5(6):2759–2767. https://doi.org/10.1039/c6ta09849eCrossRef

12.

Wang K, Song Y, Yan R, Zhao N, Tian X, Li X, Guo Q, Liu Z (2017) High capacitive performance of hollow activated carbon fibers derived from willow catkins. Appl Surf Sci 394:569–577. https://doi.org/10.1016/j.apsusc.2016.10.161CrossRef

13.

Xu M, Yu Q, Liu Z, Lv J, Lian S, Hu B, Mai L, Zhou L (2018) Tailoring porous carbon spheres for supercapacitors. Nanoscale 10(46):21604–21616. https://doi.org/10.1039/c8nr07560cCrossRef

14.

Wang D, Lu Z, Xu L (2020) Microstructure design of porous nanocarbons for ultrahigh-energy and power density supercapacitors in ionic liquid electrolyte. J Mater Sci 55(17):7477–7491. https://doi.org/10.1007/s10853-020-04538-1CrossRef

15.

Song M, Zhou Y, Ren X, Wan J, Du Y, Wu G, Ma F (2019) Biowaste-based porous carbon for supercapacitor: The influence of preparation processes on structure and performance. J Colloid Interface Sci 535:276–286. https://doi.org/10.1016/j.jcis.2018.09.055CrossRef

16.

Wang Q, Zhang Y, Jiang H, Meng C (2019) In-situ grown manganese silicate from biomass-derived heteroatom-doped porous carbon for supercapacitors with high performance. J Colloid Interf Sci 534:142–155. https://doi.org/10.1016/j.jcis.2018.09.026CrossRef

17.

Gao K, Niu Q, Tang Q, Guo Y, Wang L (2017) Graphene-like 2D porous carbon nanosheets derived from cornstalk pith for energy storage materials. J Electron Mater 47(1):337–346. https://doi.org/10.1007/s11664-017-5771-7CrossRef

18.

Thakur AK, Choudhary RB, Majumder M, Gupta G (2017) In-situ integration of waste coconut shell derived activated carbon/polypyrrole/rare earth metal oxide (Eu₂O₃): a novel step towards ultrahigh volumetric capacitance. Electrochim Acta 251:532–545. https://doi.org/10.1016/j.electacta.2017.08.159CrossRef

19.

Zhang Q, Han K, Li S, Li M, Li J, Ren K (2018) Synthesis of garlic skin-derived 3D hierarchical porous carbon for high-performance supercapacitors. Nanoscale 10(5):2427–2437. https://doi.org/10.1039/c7nr07158bCrossRef

20.

He D, Zhao W, Li P, Liu Z, Wu H, Liu L, Han K, Liu L, Wan Q, Butt FK, Qu X (2019) Bifunctional biomass-derived 3D nitrogen-doped porous carbon for oxygen reduction reaction and solid-state supercapacitor. Appl Surf Sci 465:303–312. https://doi.org/10.1016/j.apsusc.2018.09.185CrossRef

21.

Ye Z, Wang F, Jia C, Mu K, Yu M, Lv Y, Shao Z (2017) Nitrogen and oxygen-codoped carbon nanospheres for excellent specific capacitance and cyclic stability supercapacitor electrodes. Chem Eng J 330:1166–1173. https://doi.org/10.1016/j.cej.2017.08.070CrossRef

22.

Cui Y, Wang H, Xu X, Lv Y, Shi J, Liu W, Chen S, Wang X (2018) Nitrogen-doped porous carbons derived from a natural polysaccharide for multiple energy storage devices. Sustain Energ Fuels 2(2):381–391. https://doi.org/10.1039/c7se00443eCrossRef

23.

Raymundo-Piñero E, Leroux F, Béguin F (2006) A high-performance carbon for supercapacitors obtained by carbonization of a seaweed biopolymer. Adv Mater 18(14):1877–1882. https://doi.org/10.1002/adma.200501905CrossRef

24.

Bai Q, Xiong Q, Li C, Shen Y, Uyama H (2018) Hierarchical porous carbons from a sodium alginate/bacterial cellulose composite for high-performance supercapacitor electrodes. Appl Surf Sci 455:795–807. https://doi.org/10.1016/j.apsusc.2018.05.006CrossRef

25.

Huang H, Zeng X, Li W, Wang H, Wang Q, Yang Y (2014) Reinforced conducting hydrogels prepared from the in situ polymerization of aniline in an aqueous solution of sodium alginate. J Mater Chem A 2(39):16516–16522. https://doi.org/10.1039/c4ta03332aCrossRef

26.

Li J, Sun K, Leng C, Jiang J (2018) Zipping assembly of an Fe₃O₄/carbon nanosheet composite as a high-performance supercapacitor electrode material. RSC Adv 8(65):37417–37423. https://doi.org/10.1039/c8ra06970kCrossRef

27.

Wang N, Liu Q, Kang D, Gu J, Zhang W, Zhang D (2016) Facile self-cross-linking synthesis of 3D nanoporous Co₃O₄/carbon hybrid electrode materials for supercapacitors. ACS Appl Mater Interf 8(25):16035–16044. https://doi.org/10.1021/acsami.6b03527CrossRef

28.

Xuan C, Peng Z, Wang J, Lei W, Xia K, Wu Z, Xiao W, Wang D (2017) Biomass derived nitrogen doped carbon with porous architecture as efficient electrode materials for supercapacitors. Chinese Chem Lett 28(12):2227–2230. https://doi.org/10.1016/j.cclet.2017.09.009CrossRef

29.

Jia H, Cai Y, Lin J, Liang H, Qi J, Cao J, Feng J, Fei W (2018) Heterostructural graphene quantum dot/MnO₂ nanosheets toward high-potential window electrodes for high-performance supercapacitors. Adv Sci (Weinh) 5(5):1700887. https://doi.org/10.1002/advs.201700887CrossRef

30.

Zhang Q, Wang N, Zhao P, Yao M, Hu W (2018) N-doped mesoporous carbon integrated on carbon cloth for flexible supercapacitors with remarkable performance. J Mater Sci 53(20):14573–14585. https://doi.org/10.1007/s10853-018-2654-0CrossRef

31.

Dong X, Xu Y, Wang S, Zhao J, Ren B, Zhang L, Liu Z (2018) Design of high specific surface area N-doped carbon aerogels via a microwave reduction method. J Mater Sci 54(2):1580–1592. https://doi.org/10.1007/s10853-018-2909-9CrossRef

32.

Li Z, Bu F, Wei J, Yao W, Wang L, Chen Z, Pan D, Wu M (2018) Boosting the energy storage densities of supercapacitors by incorporating N-doped graphene quantum dots into cubic porous carbon. Nanoscale 10(48):22871–22883. https://doi.org/10.1039/c8nr06986gCrossRef

33.

Kongkaew S, Kanatharana P, Thavarungkul P, Limbut W (2017) A preparation of homogeneous distribution of palladium nanoparticle on poly (acrylic acid)-functionalized graphene oxide modified electrode for formalin oxidation. Electrochim Acta 247:229–240. https://doi.org/10.1016/j.electacta.2017.06.131CrossRef

34.

Guo Y, Zhou X, Tang Q, Bao H, Wang G, Saha P (2016) A self-healable and easily recyclable supramolecular hydrogel electrolyte for flexible supercapacitors. J Mater Chem A 4(22):8769–8776. https://doi.org/10.1039/c6ta01441kCrossRef

35.

Ye Z, Wang F, Jia C, Shao Z (2018) Biomass-based O, N-codoped activated carbon aerogels with ultramicropores for supercapacitors. J Mater Sci 53(17):12374–12387. https://doi.org/10.1007/s10853-018-2487-xCrossRef

36.

Wang L, Wang Y, Xu T, Liao H, Yao C, Liu Y, Li Z, Chen Z, Pan D, Sun L, Wu M (2014) Gram-scale synthesis of single-crystalline graphene quantum dots with superior optical properties. Nat Commun 5:5357. https://doi.org/10.1038/ncomms6357CrossRef

37.

Iamprasertkun P, Krittayavathananon A, Sawangphruk M (2016) N-doped reduced graphene oxide aerogel coated on carboxyl-modified carbon fiber paper for high-performance ionic-liquid supercapacitors. Carbon 102:455–461. https://doi.org/10.1016/j.carbon.2015.12.092CrossRef

38.

Wang N, Zhao P, Liang K, Yao M, Yang Y, Hu W (2017) CVD-grown polypyrrole nanofilms on highly mesoporous structure MnO₂ for high performance asymmetric supercapacitors. Chem Eng J 307:105–112. https://doi.org/10.1016/j.cej.2016.08.074CrossRef

39.

Cao F, Zhao M, Yu Y, Chen B, Huang Y, Yang J, Cao X, Lu Q, Zhang X, Zhang Z, Tan C, Zhang H (2016) Synthesis of two-dimensional CoS_1.097/nitrogen-doped carbon nanocomposites using metal-organic framework nanosheets as precursors for supercapacitor application. J Am Chem Soc 138(22):6924–6927. https://doi.org/10.1021/jacs.6b02540CrossRef

40.

Lai F, Miao YE, Zuo L, Lu H, Huang Y, Liu T (2016) Biomass-derived nitrogen-doped carbon nanofiber network: a facile template for decoration of ultrathin nickel-cobalt layered double hydroxide nanosheets as high-performance asymmetric supercapacitor electrode. Small 12(24):3235–3244. https://doi.org/10.1002/smll.201600412CrossRef

41.

de Oliveira HP, Sydlik SA, Swager TM (2013) Supercapacitors from free-standing polypyrrole/graphene nanocomposites. J Phys Chem C 117(20):10270–10276. https://doi.org/10.1021/jp400344uCrossRef

42.

Li Z, Liu X, Wang L, Bu F, Wei J, Pan D, Wu M (2018) Hierarchical 3D all-carbon composite structure modified with n-doped graphene quantum dots for high-performance flexible supercapacitors. Small 14(39):1801498. https://doi.org/10.1002/smll.201801498CrossRef

43.

Li Z, Wei J, Ren J, Wu X, Wang L, Pan D, Wu M (2019) Hierarchical construction of high-performance all-carbon flexible fiber supercapacitors with graphene hydrogel and nitrogen-doped graphene quantum dots. Carbon 154:410–419. https://doi.org/10.1016/j.carbon.2019.08.040CrossRef

44.

Zhang C, Liu X, Li Z, Zhang C, Chen Z, Pan D, Wu M (2021) Nitrogen-doped accordion-like soft carbon anodes with exposed hierarchical pores for advanced potassium-ion hybrid capacitors. Adv Func Mater 31(23):2101470. https://doi.org/10.1002/adfm.202101470CrossRef

45.

Liu J, Wang J, Xu C, Jiang H, Li C, Zhang L, Lin J, Shen Z (2018) Advanced energy storage devices: basic principles, analytical methods, and rational materials design. Adv Sci 5(1):1700322. https://doi.org/10.1002/advs.201700322CrossRef

46.

Hu J, Wang H, Gao Q, Guo H (2010) Porous carbons prepared by using metal–organic framework as the precursor for supercapacitors. Carbon 48(12):3599–3606. https://doi.org/10.1016/j.carbon.2010.06.008CrossRef

47.

Kwak M-J, Ramadoss A, Yoon K-Y, Park J, Thiyagarajan P, Jang J-H (2017) Single-step synthesis of N-doped three-dimensional graphitic foams for high-performance supercapacitors. ACS Sust Chem Eng 5(8):6950–6957. https://doi.org/10.1021/acssuschemeng.7b01132CrossRef

Titel: Nitrogen-doped biomass-derived porous carbon spheres for supercapacitors with ultrafast charge/discharge rate up to 2.5 V s−1
verfasst von: Jingting Bu
Zhipeng Zhou
Xiaomin Wu
Chenying Zhang
Zhen Li
Publikationsdatum: 16.08.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 31/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-06389-w

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 31/2021

Evaluation of water structures in cotton cloth by fractal analysis with broadband dielectric spectroscopy

Effect of Er dopant on the corrosion resistance of YSZ in CMAS melt: experimental and first-principles study

Thermal shock exfoliated and siloxane cross-linked graphene framework for high performance epoxy-based thermally conductive composites

Facile fabrication of recyclable and macroscopic D-g-C3N4/sodium alginates/non-woven fabric immobilized photocatalysts with enhanced photocatalytic activity and antibacterial performance

Boosting hydrogen production via urea electrolysis on an amorphous nickel phosphide/graphene hybrid structure

Structural health monitoring of irradiated high-density polyethylene samples with electrical resistance tomography

Premium Partner

Marktübersichten