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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2016

01.03.2016 | Original Paper

Green synthesis of zirconia nanoparticles using the modified Pechini method and characterization of its optical and electrical properties

verfasst von: Ali Majedi, Alireza Abbasi, Fatemeh Davar

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2016

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Abstract

Zirconia nanoparticles with the cubic phase were prepared from zirconium acetate and lemon juice as the precursors. Then, the effect of sucrose addition on improving the particle size and the agglomeration of product was investigated. The particle size of as-synthesized nanoparticles was obtained using FESEM. The results showed that the as-obtained product with the mix of lemon juice (20 mL) and sucrose had a better morphology with the mean particle size of about 21 nm. These nanoparticles were selected and further characterized by EDS, AAS, XRD, UV–Vis, and PL spectroscopy. The EDS and AAS revealed the presence of Mg and Ca in the sample introduced from lemon juice. Also, XRD confirmed the formation of the cubic-phase zirconia. The synthesized cubic ZrO2 nanoparticles exhibited a broad photoluminescence in the UV–Vis region. Then, a pellet from these nanoparticles was prepared and the electrical property of this sample was measured in the temperature range of 450–750 °C using four-probe techniques. The results revealed that these zirconia nanoparticles could have a potential application as an electrolyte material in the intermediate-temperature solid oxide fuel cells.

Graphical Abstract

Vorheriger Artikel Effect of fuel-to-oxidant ratio on phase constituents, microstructure and magnetic properties of NiFe2O4-based composite nanopowder synthesized by sol–gel auto-combustion method
Nächster Artikel Study of the growth of hydrophilic iron oxide nanoparticles obtained via the non-aqueous sol–gel method

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Metadaten
Titel
Green synthesis of zirconia nanoparticles using the modified Pechini method and characterization of its optical and electrical properties
verfasst von
Ali Majedi
Alireza Abbasi
Fatemeh Davar
Publikationsdatum
01.03.2016
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2016
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-015-3881-3

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