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Journal of Sol-Gel Science and Technology

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20.05.2016 | Original Paper: Sol-gel and hybrid materials for optical, photonic and optoelectronic applications

Heavily Yb-doped silicate glass thick films

verfasst von: Tiago V. Ribeiro, Luís F. Santos, M. Clara Gonçalves, Rui M. Almeida

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2017

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Abstract

A series of Yb-doped glass films has been prepared by sol–gel processing within the SiO₂–Al₂O₃–P₂O₅–Yb₂O₃ system with doping levels up to 30 mol% Yb on a cation basis, with a thickness up to ~36 μm. The refractive indices at 633 nm, measured by spectroscopic ellipsometry, varied between 1.457 and 1.577, depending on the composition. Infrared (IR) and Raman spectroscopies were used to establish the main structural features of the different compositions, which included the presence of mixed Si–O–Al bonds evidenced by a IR peak at 940 cm⁻¹, as well as P=O bonds revealed by a Raman peak at 1326 cm⁻¹. The photoluminescence spectrum of Yb³⁺ ions was dominated by peaks at 987 and 1020 nm, with a lifetime between ~0.5–1.0 ms.

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Vorheriger Artikel Ethanol–water co-condensation into hydrophobic mesoporous thin films: example of a photonic ethanol vapor sensor in humid environment

Nächster Artikel Multifunctional organic–inorganic hybrids based on cellulose acetate and 3-glycidoxypropyltrimethoxysilane

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Titel: Heavily Yb-doped silicate glass thick films
verfasst von: Tiago V. Ribeiro
Luís F. Santos
M. Clara Gonçalves
Rui M. Almeida
Publikationsdatum: 20.05.2016
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 1/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-016-4071-7

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