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Journal of Nanoparticle Research

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01.02.2018 | Research Paper

Hierarchical rutile TiO₂ microspheres assembled by nanorods with nanocavities and their lithium-ion storage properties

verfasst von: Lin Chen, Sudong Yang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 2/2018

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Abstract

Unique hierarchical rutile TiO₂ microspheres assembled by nanorods with nanocavities were successfully synthesized through mesoscale assembly in the tetrabutyl titanate-hydrochloric acid system followed by subsequently calcinating in air. In contrast to the classical mechanism of atom-/molecule-mediated growth of a single crystal, the particle-mediated growth and assembly mechanism was summarized as nonclassical crystallization. The particle-based crystallization pathways lead to single crystals with nanocavities via mesoscopic transformation and anti-nucleation process. The electrochemical properties were investigated by constant current discharge-charge tests and electrochemical impedance techniques. This microsphere-shaped rutile TiO₂ with nanocavities exhibits excellent rate capacities (151 mAh g⁻¹ at 2 C) and better cyclic performance than that of rutile TiO₂ mesocrystals precursor at high rate.

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Titel: Hierarchical rutile TiO2 microspheres assembled by nanorods with nanocavities and their lithium-ion storage properties
verfasst von: Lin Chen
Sudong Yang
Publikationsdatum: 01.02.2018
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 2/2018
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-017-4112-3

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