Skip to main content
Erschienen in: Journal of Electroceramics 4/2018

18.04.2018

High dielectric response of cobalt aluminate mullite (CAM) nanocomposite over cobalt aluminate mullite polymer (CAMP) nanocomposite in PVDF matrix

verfasst von: Biplab Kumar Paul, Debasis Roy, Smarajit Manna, Papiya Nandy, Sukhen Das

Erschienen in: Journal of Electroceramics | Ausgabe 4/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this communication we have compared the dielectric behavior of cobalt aluminate mullite (CAM) nanocomposite and cobalt aluminate mullite polymer (CAMP) nanocomposite with different molar concentration of Co +2 ions. The study of dielectric property of the CAM samples as well as that of the CAMP samples at room temperature shows that at all concentrations the dielectric constant is higher than pure mullite and there is a critical concentration of Co +2, where maximum enhancement of dielectric property occurs. This paper demonstrates that the loading of a conductive component into a highly insulating matrix is an effective way to fabricate composites with high permittivity as well as a charge storage material. We have designed a device using CAM as the electrode material and CAMP as the separator to compare it with a commercial Li-polymer ion mobile battery. We observed that the charge storage ability of the composite system is better than the commercial Li-polymer ion mobile battery. Our device persists for more than 24 h while the maximum voltage recorded by the device is 0.885 V, whereas the maximum voltage recorded by the conventional commercial Li-polymer ion mobile battery is 0.566 V.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat L. Zhang, Z.-Y. Cheng, Development of polymer-based 0-3 composites with high dielectric constant. J. Adv. Dielectr. 1, 389 (2011)CrossRef L. Zhang, Z.-Y. Cheng, Development of polymer-based 0-3 composites with high dielectric constant. J. Adv. Dielectr. 1, 389 (2011)CrossRef
2.
Zurück zum Zitat Z.M. Dang, J.K. Yuan, J.W. Zha, T. Zhou, S.T. Li, G.H. Hu, Fundamentals, processes and applications ofhigh-permittivitypolymer-matrixcomposites. Prog. Mater. Sci. 57, 660 (2012)CrossRef Z.M. Dang, J.K. Yuan, J.W. Zha, T. Zhou, S.T. Li, G.H. Hu, Fundamentals, processes and applications ofhigh-permittivitypolymer-matrixcomposites. Prog. Mater. Sci. 57, 660 (2012)CrossRef
3.
Zurück zum Zitat C.W. Nan, Y. Shen, J. Ma, Physical properties of composites near percolation. Annu. Rev. Mater. Res. 40, 131 (2010)CrossRef C.W. Nan, Y. Shen, J. Ma, Physical properties of composites near percolation. Annu. Rev. Mater. Res. 40, 131 (2010)CrossRef
4.
Zurück zum Zitat L. Zhang, W. Wang, X.G. Wang, P. Bass, Z.-Y. Cheng, Metal-polymer nanocomposites with high percolation threshold and high dielectric constant. Appl. Phys. Lett. 103, 232903 (2013)CrossRef L. Zhang, W. Wang, X.G. Wang, P. Bass, Z.-Y. Cheng, Metal-polymer nanocomposites with high percolation threshold and high dielectric constant. Appl. Phys. Lett. 103, 232903 (2013)CrossRef
5.
Zurück zum Zitat Z.M. Dang, B. Peng, D. Xie, S.H. Yao, M.J. Jiang, J.B. Bai, High dielectric permittivity silver/polyimide composite films with excellent thermal stability. Appl. Phys. Lett. 92, 112910 (2008)CrossRef Z.M. Dang, B. Peng, D. Xie, S.H. Yao, M.J. Jiang, J.B. Bai, High dielectric permittivity silver/polyimide composite films with excellent thermal stability. Appl. Phys. Lett. 92, 112910 (2008)CrossRef
6.
Zurück zum Zitat J.W. Xu, K.S. Moon, C. Tison, C.P. Wong, A novel aluminum-filled composite dielectric for embedded passive applications. IEEE Trans. Adv. Packag. 29, 295 (2006)CrossRef J.W. Xu, K.S. Moon, C. Tison, C.P. Wong, A novel aluminum-filled composite dielectric for embedded passive applications. IEEE Trans. Adv. Packag. 29, 295 (2006)CrossRef
7.
Zurück zum Zitat M. Panda, V. Srinivas, A.K. Thakur, On the question of percolation threshold in polyvinylidene fluoride/nanocrystalline nickel composites. Appl. Phys. Lett. 92, 132905 (2008)CrossRef M. Panda, V. Srinivas, A.K. Thakur, On the question of percolation threshold in polyvinylidene fluoride/nanocrystalline nickel composites. Appl. Phys. Lett. 92, 132905 (2008)CrossRef
8.
Zurück zum Zitat L. Zhang, P. Bass, Z.-Y. Cheng, Revisiting the percolation phenomena in dielectric composites with conducting fillers. Appl. Phys. Lett. 105, 042905 (2014)CrossRef L. Zhang, P. Bass, Z.-Y. Cheng, Revisiting the percolation phenomena in dielectric composites with conducting fillers. Appl. Phys. Lett. 105, 042905 (2014)CrossRef
9.
Zurück zum Zitat Z.-M. Dang, Y.H. Lin, C.W. Nan, Novel ferroelectric polymer composites with high dielectric constants. Adv. Mater. 15, 1625 (2003)CrossRef Z.-M. Dang, Y.H. Lin, C.W. Nan, Novel ferroelectric polymer composites with high dielectric constants. Adv. Mater. 15, 1625 (2003)CrossRef
10.
Zurück zum Zitat D. Roy, B. Bagchi, S. Das, P. Nandy, Electrical and dielectric properties of sol-gel derived mullite doped with transition metals. Mater. Chem. Phys. 138, 375–383 (2013)CrossRef D. Roy, B. Bagchi, S. Das, P. Nandy, Electrical and dielectric properties of sol-gel derived mullite doped with transition metals. Mater. Chem. Phys. 138, 375–383 (2013)CrossRef
11.
Zurück zum Zitat V. Ramakrishnan, E. Goo, J.M. Roldan, E.A. Giess, Microstructure of mullite ceramics used for substrate and packaging applications. J. Mater. Sci. 27(22), 6127–6130 (1992)CrossRef V. Ramakrishnan, E. Goo, J.M. Roldan, E.A. Giess, Microstructure of mullite ceramics used for substrate and packaging applications. J. Mater. Sci. 27(22), 6127–6130 (1992)CrossRef
12.
Zurück zum Zitat V. Viswabaskaran, F.D. Gnanama, M. Balasubramanian, Mullite from clay–reactive alumina for insulating substrate application. Appl. Clay Sci. 25, 29–35 (2004)CrossRef V. Viswabaskaran, F.D. Gnanama, M. Balasubramanian, Mullite from clay–reactive alumina for insulating substrate application. Appl. Clay Sci. 25, 29–35 (2004)CrossRef
13.
Zurück zum Zitat N.L. Bowen, J.W. Greig, The system Al2O3-SiO2. J. Amer. Ceram. Soc. 7(238), 410 (1924) N.L. Bowen, J.W. Greig, The system Al2O3-SiO2. J. Amer. Ceram. Soc. 7(238), 410 (1924)
14.
Zurück zum Zitat Y. Konishi, M. Cakmak, Nanoparticle induced network self-assembly in polymer– carbon black composites. Polymer 47(15), 5371–5391 (2006)CrossRef Y. Konishi, M. Cakmak, Nanoparticle induced network self-assembly in polymer– carbon black composites. Polymer 47(15), 5371–5391 (2006)CrossRef
15.
Zurück zum Zitat O. Korostynska, K. Arshak, D. Morris, A. Arshak, E. Jafer, Radiation-induced changes in the electrical properties of carbon filled PVDF thick films. Mater. Sci. Eng. B 141(3), 115–120 (2007)CrossRef O. Korostynska, K. Arshak, D. Morris, A. Arshak, E. Jafer, Radiation-induced changes in the electrical properties of carbon filled PVDF thick films. Mater. Sci. Eng. B 141(3), 115–120 (2007)CrossRef
16.
Zurück zum Zitat Y.J. Li, M. Xu, J.Q. Feng, Z.M. Dang, Dielectric behavior of a metal–polymer composite with low percolation threshold. Appl. Phys. Lett. 89(7), 072902–007905 (2006)CrossRef Y.J. Li, M. Xu, J.Q. Feng, Z.M. Dang, Dielectric behavior of a metal–polymer composite with low percolation threshold. Appl. Phys. Lett. 89(7), 072902–007905 (2006)CrossRef
17.
Zurück zum Zitat H.P. Xu, Z.M. Dang, Electrical property and microstructure analysis of poly(vinylidene fluoride)-based composites with different conducting fillers. Chem. Phys. Lett. 438(4–6), 196–202 (2007)CrossRef H.P. Xu, Z.M. Dang, Electrical property and microstructure analysis of poly(vinylidene fluoride)-based composites with different conducting fillers. Chem. Phys. Lett. 438(4–6), 196–202 (2007)CrossRef
18.
Zurück zum Zitat J. Sun, Q.Z. Xue, Q.K. Guo, et al., Excellent dielectric properties of polyvinylidene fluoride composites based on sandwich structured MnO2/grapheme nanosheets/MnO2. Compos. A: Appl. Sci. Manuf. 67, 252–258 (2014)CrossRef J. Sun, Q.Z. Xue, Q.K. Guo, et al., Excellent dielectric properties of polyvinylidene fluoride composites based on sandwich structured MnO2/grapheme nanosheets/MnO2. Compos. A: Appl. Sci. Manuf. 67, 252–258 (2014)CrossRef
19.
Zurück zum Zitat D. Roy, B. Bagchi, A. Bhattacharya, S. Das, P. Nandy, A comparative study of densification of Sol-Gel- derived nano-mullite due to the influence of iron, nickel and copper ions. Int. J. Appl. Ceram. Technol. 11(6), 1054–1060 (2014)CrossRef D. Roy, B. Bagchi, A. Bhattacharya, S. Das, P. Nandy, A comparative study of densification of Sol-Gel- derived nano-mullite due to the influence of iron, nickel and copper ions. Int. J. Appl. Ceram. Technol. 11(6), 1054–1060 (2014)CrossRef
20.
Zurück zum Zitat K.C. Song, Preparation of mullite fibers from aluminum isopropoxide, aluminum nitrate, tetraethyl-orthosilicate solutions by sol–gel method. Mater. Lett. 35, 290–296 (1998)CrossRef K.C. Song, Preparation of mullite fibers from aluminum isopropoxide, aluminum nitrate, tetraethyl-orthosilicate solutions by sol–gel method. Mater. Lett. 35, 290–296 (1998)CrossRef
21.
Zurück zum Zitat J.P. Tkalcec, B.G. Eta, S. Kurajica, J. Schmauch, Cobalt incorporation in mullite. Am. Mineral. 92, 408–411 (2007)CrossRef J.P. Tkalcec, B.G. Eta, S. Kurajica, J. Schmauch, Cobalt incorporation in mullite. Am. Mineral. 92, 408–411 (2007)CrossRef
22.
Zurück zum Zitat W. Lv et al., Sonochemical synthesis of cobalt aluminate nanoparticles under various preparation parameters. Ultrason. Sonochem. 17, 793–801 (2010)CrossRef W. Lv et al., Sonochemical synthesis of cobalt aluminate nanoparticles under various preparation parameters. Ultrason. Sonochem. 17, 793–801 (2010)CrossRef
23.
Zurück zum Zitat R.R. Heikes, W.D. Johnston, Mechanism of conduction in Li-substituted transition metal oxides. J. Chem. Phys. 26, 582 (1957)CrossRef R.R. Heikes, W.D. Johnston, Mechanism of conduction in Li-substituted transition metal oxides. J. Chem. Phys. 26, 582 (1957)CrossRef
24.
26.
Zurück zum Zitat P. Thakur, A. Kool, B. Bagchi, S. Das, P. Nandy, Effect of in situ synthesized Fe2O3 and Co3O4 nanoparticles on electroactive b phase crystallization and dielectric properties of poly(vinylidene fluoride) thin films. (2015). https://doi.org/10.1039/c4cp04006f P. Thakur, A. Kool, B. Bagchi, S. Das, P. Nandy, Effect of in situ synthesized Fe2O3 and Co3O4 nanoparticles on electroactive b phase crystallization and dielectric properties of poly(vinylidene fluoride) thin films. (2015). https://​doi.​org/​10.​1039/​c4cp04006f
27.
Zurück zum Zitat B.K. Paul, D. Roy, S. Batabyal, A. Bhattacharya, P. Nandy, S. Das, A comparative study of strontium and titanium doped mullite in PVDF matrix and their phase behavior, microstructure and electrical properties. Mater. Chem. Phys. 187, 119–132 (2017)CrossRef B.K. Paul, D. Roy, S. Batabyal, A. Bhattacharya, P. Nandy, S. Das, A comparative study of strontium and titanium doped mullite in PVDF matrix and their phase behavior, microstructure and electrical properties. Mater. Chem. Phys. 187, 119–132 (2017)CrossRef
28.
Zurück zum Zitat D. Roy, B. Bagchi, S. Das, P. Nandy, Dielectric and magnetic properties of sol–gel derived mullite-iron nanocomposite. J. Electroceram. 28, 261–267 (2012)CrossRef D. Roy, B. Bagchi, S. Das, P. Nandy, Dielectric and magnetic properties of sol–gel derived mullite-iron nanocomposite. J. Electroceram. 28, 261–267 (2012)CrossRef
29.
Zurück zum Zitat K. Halder, B.K. Paul, A. Bhattacharya, P. Nandy, S. Das, High-K tungsten-mullite composite for electronic industrial application: Synthesis and study of its microstructure, phase behavior and electrical properties. J. Mater. Sci. Mater. Electron. (2015). https://doi.org/10.1007/s10854-014-2521-y K. Halder, B.K. Paul, A. Bhattacharya, P. Nandy, S. Das, High-K tungsten-mullite composite for electronic industrial application: Synthesis and study of its microstructure, phase behavior and electrical properties. J. Mater. Sci. Mater. Electron. (2015). https://​doi.​org/​10.​1007/​s10854-014-2521-y
30.
Zurück zum Zitat P. Thakur, A. Kool, B. Bagchi, S. Das, P. Nandy, Enhancement of β phase crystallization and dielectric behavior of kaolinite/halloysite modified poly(vinylidene fluoride) thin films. Appl. Clay Sci. 99, 149–159 (2014)CrossRef P. Thakur, A. Kool, B. Bagchi, S. Das, P. Nandy, Enhancement of β phase crystallization and dielectric behavior of kaolinite/halloysite modified poly(vinylidene fluoride) thin films. Appl. Clay Sci. 99, 149–159 (2014)CrossRef
31.
Zurück zum Zitat A. Kool, P. Thakur, B. Bagchi, N.A. Haque, S. Das, Mechanical, dielectric and photoluminescence properties of alumina–mullite composite derived from natural Ganges clay. Appl. Clay Sci. 114, 349–358 (2015)CrossRef A. Kool, P. Thakur, B. Bagchi, N.A. Haque, S. Das, Mechanical, dielectric and photoluminescence properties of alumina–mullite composite derived from natural Ganges clay. Appl. Clay Sci. 114, 349–358 (2015)CrossRef
32.
Zurück zum Zitat A. Kool, P. Thakur, B. Bagchi, N.A. Haque, S. Banerjee, S. Das, Sol–gel synthesis of transition-metal ion conjugated alumina-rich mullite nanocomposites with potential mechanical, dielectric and photoluminescence properties. RSC Adv. 5, 104299–104313 (2015)CrossRef A. Kool, P. Thakur, B. Bagchi, N.A. Haque, S. Banerjee, S. Das, Sol–gel synthesis of transition-metal ion conjugated alumina-rich mullite nanocomposites with potential mechanical, dielectric and photoluminescence properties. RSC Adv. 5, 104299–104313 (2015)CrossRef
33.
Zurück zum Zitat A. Kool, P. Thakur, B. Bagchi, N.A. Haque, S. Banerjee, S. Das, Physico-chemical property-driven dielectric behaviour and catalytic activity of nanocrystalline mullite synthesized from monophasic precursor gel. J. Sol-Gel Sci. Technol. 80(3), 769–782 (2016)CrossRef A. Kool, P. Thakur, B. Bagchi, N.A. Haque, S. Banerjee, S. Das, Physico-chemical property-driven dielectric behaviour and catalytic activity of nanocrystalline mullite synthesized from monophasic precursor gel. J. Sol-Gel Sci. Technol. 80(3), 769–782 (2016)CrossRef
34.
Zurück zum Zitat M.S. Sanad, M.M. Rashad, E.A. Abdel-Aal, M.F. El-Shahat, Synthesis and characterization of nanocrystalline mullite powders at low annealing temperature using a new technique. J. Eur. Ceram. Soc. 32, 4249–4255 (2012)CrossRef M.S. Sanad, M.M. Rashad, E.A. Abdel-Aal, M.F. El-Shahat, Synthesis and characterization of nanocrystalline mullite powders at low annealing temperature using a new technique. J. Eur. Ceram. Soc. 32, 4249–4255 (2012)CrossRef
Metadaten
Titel
High dielectric response of cobalt aluminate mullite (CAM) nanocomposite over cobalt aluminate mullite polymer (CAMP) nanocomposite in PVDF matrix
verfasst von
Biplab Kumar Paul
Debasis Roy
Smarajit Manna
Papiya Nandy
Sukhen Das
Publikationsdatum
18.04.2018
Verlag
Springer US
Erschienen in
Journal of Electroceramics / Ausgabe 4/2018
Print ISSN: 1385-3449
Elektronische ISSN: 1573-8663
DOI
https://doi.org/10.1007/s10832-018-0136-z

Weitere Artikel der Ausgabe 4/2018

Journal of Electroceramics 4/2018 Zur Ausgabe

Neuer Inhalt