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Erschienen in: Journal of Materials Science 3/2017

01.02.2017 | Original Paper

High formability of glass plus fcc-Al phases in rapidly solidified Al-based multicomponent alloy

verfasst von: F. F. Han, A. Inoue, Y. Han, F. L. Kong, S. L. Zhu, E. Shalaan, F. Al-Marzouki

Erschienen in: Journal of Materials Science | Ausgabe 3/2017

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Abstract

A multicomponent Al84Y9Ni4Co1.5Fe0.5Pd1 alloy was found to keep a mixed glassy + Al phases in the relatively large ribbon thickness range up to about 200 μm for the melt-spun ribbon and in the diameter range up to about 1100 μm for the wedge-shaped cone rod prepared by injection copper mold casting. The glassy phase in the Al-based alloy has a unique crystallization process of glass transition, followed by supercooled liquid region, fcc-Al + glass, and then Al + Al3Y + Al9 (Co, Fe)2 + unknown phase. It is also noticed that the primary precipitation phase from supercooled liquid is composed of an Al phase instead of coexistent Al + compound phases, being different from the crystallization mode from supercooled liquid for ordinary Al-based glassy alloys. In addition, it is noticed that the mixed Al and glassy phases are extended in a wide heating temperature range of 588–703 K, which is favorable for the development of high-strength nanostructure Al-based bulk alloys obtained by warm extrusion of mixed Al + amorphous phases. The Vickers hardness is about 415 for the glassy phase and increases significantly to about 580 for the mixed Al and glassy phases. The knowledge of forming Al + glassy phases with high hardness in the wide solidification and annealing conditions through high stability up to complete crystallization for the multicomponent alloy is promising for future development of a high-strength Al-based bulk alloy.

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Literatur
1.
Zurück zum Zitat Davis JR (1993) Aluminum and aluminum alloys, ASM international Davis JR (1993) Aluminum and aluminum alloys, ASM international
2.
Zurück zum Zitat Malek P, Janecek M, Smola B, Bartuska P, Plestil J (2000) Structure and properties of rapidly solidified Al–Zr–Ti alloys. J Mater Sci 35:2625–2633CrossRef Malek P, Janecek M, Smola B, Bartuska P, Plestil J (2000) Structure and properties of rapidly solidified Al–Zr–Ti alloys. J Mater Sci 35:2625–2633CrossRef
3.
Zurück zum Zitat Inoue A, Kimura H (2000) High-strength aluminum alloys containing nanoquasicrystalline particles. Mat Sci Eng 286:1–10CrossRef Inoue A, Kimura H (2000) High-strength aluminum alloys containing nanoquasicrystalline particles. Mat Sci Eng 286:1–10CrossRef
4.
Zurück zum Zitat Zhu M, Yang GC, YaoLJ Cheng SL, Zhou YH (2010) Microstructure and mechanical properties of Al-base composites by addition of Al–Ni–Co decagonal quasicrystalline particles through a mechanical stirring route. J Mater Sci 45:3727–3734CrossRef Zhu M, Yang GC, YaoLJ Cheng SL, Zhou YH (2010) Microstructure and mechanical properties of Al-base composites by addition of Al–Ni–Co decagonal quasicrystalline particles through a mechanical stirring route. J Mater Sci 45:3727–3734CrossRef
5.
Zurück zum Zitat Taketani K, Uoya A, Ohtera K, Uehara T, Higashi K, Inoue A (1994) Readily superplastic forging at high strain rates in an aluminium-based alloy produced from nanocrystalline powders. J Mater Sci 29:6513–6517CrossRef Taketani K, Uoya A, Ohtera K, Uehara T, Higashi K, Inoue A (1994) Readily superplastic forging at high strain rates in an aluminium-based alloy produced from nanocrystalline powders. J Mater Sci 29:6513–6517CrossRef
6.
Zurück zum Zitat Tokuoka T, Kaji T, Nishioka T, Ikegaya A (2006) Development of high-strength, heat-resistant aluminum alloy made by powder forging process. SEI Technical Review 61:70–76 Tokuoka T, Kaji T, Nishioka T, Ikegaya A (2006) Development of high-strength, heat-resistant aluminum alloy made by powder forging process. SEI Technical Review 61:70–76
7.
Zurück zum Zitat Inoue A, Yamamoto M, Kimura HM, Masumoto T (1987) Ductile aluminium-base amorphous alloys with two separate phases. J Mater Sci Lett 6:194–196CrossRef Inoue A, Yamamoto M, Kimura HM, Masumoto T (1987) Ductile aluminium-base amorphous alloys with two separate phases. J Mater Sci Lett 6:194–196CrossRef
8.
Zurück zum Zitat He Y, Poon SJ, Shiflet GJ (1988) Synthesis and properties of metallic glasses that contain aluminum. Science 241:1640–1642CrossRef He Y, Poon SJ, Shiflet GJ (1988) Synthesis and properties of metallic glasses that contain aluminum. Science 241:1640–1642CrossRef
9.
Zurück zum Zitat Inoue A (1998) Amorphous, nanoquasicrystalline and nanocrystalline alloys in Al-based systems. Prog Mater Sci 43:365–520CrossRef Inoue A (1998) Amorphous, nanoquasicrystalline and nanocrystalline alloys in Al-based systems. Prog Mater Sci 43:365–520CrossRef
10.
Zurück zum Zitat Scudino S, Surreddi KB, Sager S, Sakaliyskaet M, Kim JS, Loser W, Eckert J (2008) Production and mechanical properties of metallic glass-reinforced Al-based metal matrix composites. J Mater Sci 43:4518–4526CrossRef Scudino S, Surreddi KB, Sager S, Sakaliyskaet M, Kim JS, Loser W, Eckert J (2008) Production and mechanical properties of metallic glass-reinforced Al-based metal matrix composites. J Mater Sci 43:4518–4526CrossRef
11.
Zurück zum Zitat Nieh TG, Wadsworth J (1991) High-strain-rate superplasticity in aluminum matrix composites. Mat Sci Eng 147:129–142CrossRef Nieh TG, Wadsworth J (1991) High-strain-rate superplasticity in aluminum matrix composites. Mat Sci Eng 147:129–142CrossRef
12.
Zurück zum Zitat Inoue A, Kimura H, Amiya K (2002) Developments of aluminum- and magnesium-based nanophase high-strength alloys by use of melt quenching-induced metastable phase. Mater Trans 43:2006–2016CrossRef Inoue A, Kimura H, Amiya K (2002) Developments of aluminum- and magnesium-based nanophase high-strength alloys by use of melt quenching-induced metastable phase. Mater Trans 43:2006–2016CrossRef
13.
Zurück zum Zitat Gordillo MA, Cernatescu I, Aindow TT, Watson TJ, Aindow M (2014) Phase stability in a powder-processed Al–Mn–Ce alloy. J Mater Sci 49:3742–3754CrossRef Gordillo MA, Cernatescu I, Aindow TT, Watson TJ, Aindow M (2014) Phase stability in a powder-processed Al–Mn–Ce alloy. J Mater Sci 49:3742–3754CrossRef
14.
Zurück zum Zitat Calin M, Grahl H, Adam M, Eckert J, Schultzl L (2004) Synthesis and thermal stability of ball-milled and melt-quenched amorphous and nanostructured Al–Ni–Nd–Co alloys. J Mater Sci 39:5295–5298CrossRef Calin M, Grahl H, Adam M, Eckert J, Schultzl L (2004) Synthesis and thermal stability of ball-milled and melt-quenched amorphous and nanostructured Al–Ni–Nd–Co alloys. J Mater Sci 39:5295–5298CrossRef
15.
Zurück zum Zitat Inoue A, Sobu S, Louzguine DV, Kimura H, Sasamori K (2004) Ultrahigh strength Al-based amorphous alloys containing Sc. J Mater Res 19:1539–1543CrossRef Inoue A, Sobu S, Louzguine DV, Kimura H, Sasamori K (2004) Ultrahigh strength Al-based amorphous alloys containing Sc. J Mater Res 19:1539–1543CrossRef
16.
Zurück zum Zitat Inoue A, Horio Y, Kim Y, Masumoto T (1992) Elevated-temperature strength of an Al88Ni9Ce2Fe1 amorphous alloy containing nanoscale fcc-Al particles. Mater Trans, JIM 33:669–674CrossRef Inoue A, Horio Y, Kim Y, Masumoto T (1992) Elevated-temperature strength of an Al88Ni9Ce2Fe1 amorphous alloy containing nanoscale fcc-Al particles. Mater Trans, JIM 33:669–674CrossRef
17.
Zurück zum Zitat Zhuo L, Pang S, Wang H, Zhang T (2009) Ductile bulk aluminum-based alloy with good glass-forming ability and high strength. Chin Phys Lett 26:066402CrossRef Zhuo L, Pang S, Wang H, Zhang T (2009) Ductile bulk aluminum-based alloy with good glass-forming ability and high strength. Chin Phys Lett 26:066402CrossRef
18.
Zurück zum Zitat Wu NC, Zuo L, Wang JQ, Ma E (2016) Designing aluminum-rich bulk metallic glasses via electronic-structure-guided microalloying. Acta Mater 108:143–151CrossRef Wu NC, Zuo L, Wang JQ, Ma E (2016) Designing aluminum-rich bulk metallic glasses via electronic-structure-guided microalloying. Acta Mater 108:143–151CrossRef
19.
Zurück zum Zitat Inoue A, Matsumoto N, Masumoto T (1990) Al–Ni–Y–Co amorphous alloys with high mechanical strengths, wide supercooled liquid region and large glass-forming capacity. Mater Trans, JIM 31:493–500CrossRef Inoue A, Matsumoto N, Masumoto T (1990) Al–Ni–Y–Co amorphous alloys with high mechanical strengths, wide supercooled liquid region and large glass-forming capacity. Mater Trans, JIM 31:493–500CrossRef
20.
Zurück zum Zitat Takeuchi A, Inoue A (2005) Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater Trans 46:2817–2829CrossRef Takeuchi A, Inoue A (2005) Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater Trans 46:2817–2829CrossRef
21.
Zurück zum Zitat Louzguine DV, Inoue A (2002) Influence of a supercooled liquid on crystallization behaviour of Al–Y–Ni–Co metallic glass. Mater Lett 54:75–80CrossRef Louzguine DV, Inoue A (2002) Influence of a supercooled liquid on crystallization behaviour of Al–Y–Ni–Co metallic glass. Mater Lett 54:75–80CrossRef
22.
Zurück zum Zitat Bassim N, Kiminami CS, Kaufman MJ, Oliveira MF, Perdigao MNRV, Botta Filho WJ (2001) Crystallization behavior of amorphous Al84Y9Ni5Co2 alloy. Mater Sci Eng 304:332–337CrossRef Bassim N, Kiminami CS, Kaufman MJ, Oliveira MF, Perdigao MNRV, Botta Filho WJ (2001) Crystallization behavior of amorphous Al84Y9Ni5Co2 alloy. Mater Sci Eng 304:332–337CrossRef
23.
Zurück zum Zitat Nitsche H, Sommer F, Mittemeijer EJ (2005) The Al nano-crystallization process in amorphous Al85Y8Ni5Co2. J Non-Cryst Solids 351:3760–3771CrossRef Nitsche H, Sommer F, Mittemeijer EJ (2005) The Al nano-crystallization process in amorphous Al85Y8Ni5Co2. J Non-Cryst Solids 351:3760–3771CrossRef
24.
Zurück zum Zitat Louzguine D, Inoue A (2002) Crystallization behaviour of Al-based metallic glasses below and above the glass-transition temperature. J Non-Cryst Solids 311:281–293CrossRef Louzguine D, Inoue A (2002) Crystallization behaviour of Al-based metallic glasses below and above the glass-transition temperature. J Non-Cryst Solids 311:281–293CrossRef
25.
Zurück zum Zitat Inoue A, Ohtera K, Tsai A-P, Masumoto T (1988) Aluminum-based amorphous alloys with tensile strength above 980 MPa (100 kg/mm2). Jpn J Appl Phys 27:L479CrossRef Inoue A, Ohtera K, Tsai A-P, Masumoto T (1988) Aluminum-based amorphous alloys with tensile strength above 980 MPa (100 kg/mm2). Jpn J Appl Phys 27:L479CrossRef
26.
Zurück zum Zitat Louzguine DV, Inoue A (2001) Full or particle replacement of Y by rare-earth and some other elements in the Al85Y8Ni5Co2 alloy. J Light Met 1:105–109CrossRef Louzguine DV, Inoue A (2001) Full or particle replacement of Y by rare-earth and some other elements in the Al85Y8Ni5Co2 alloy. J Light Met 1:105–109CrossRef
27.
Zurück zum Zitat Kim HY, Inoue A, Masumoto T (1991) Ultrahigh mechanical strengths of Al88Y2Ni10−xMx (M = Mn, Fe or Co) amorphous alloys containing nanoscale fcc-Al particles. Mater Trans, JIM 32:599–608CrossRef Kim HY, Inoue A, Masumoto T (1991) Ultrahigh mechanical strengths of Al88Y2Ni10−xMx (M = Mn, Fe or Co) amorphous alloys containing nanoscale fcc-Al particles. Mater Trans, JIM 32:599–608CrossRef
28.
Zurück zum Zitat Inoue A, Nakazato K, Kawamura Y, Tsai A, Masumoto T (1994) Effect of Cu or Ag on the formation of coexistent nanoscale Al particles in Al–Ni–M–Ce (M = Cu or Ag) amorphous alloys. Mater Trans, JIM 35:95–102CrossRef Inoue A, Nakazato K, Kawamura Y, Tsai A, Masumoto T (1994) Effect of Cu or Ag on the formation of coexistent nanoscale Al particles in Al–Ni–M–Ce (M = Cu or Ag) amorphous alloys. Mater Trans, JIM 35:95–102CrossRef
29.
Zurück zum Zitat Inoue A (2000) Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater 48:279–306CrossRef Inoue A (2000) Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater 48:279–306CrossRef
30.
Zurück zum Zitat Xie YQ, Peng K, Liu XB (2004) Influences of xTi/xAl on atomic states, lattice constants and potential-energy planes of ordered FCC TiAl-type alloys. Phys B 344:5–20CrossRef Xie YQ, Peng K, Liu XB (2004) Influences of xTi/xAl on atomic states, lattice constants and potential-energy planes of ordered FCC TiAl-type alloys. Phys B 344:5–20CrossRef
31.
Zurück zum Zitat Inoue A, Ohtera K, Masumoto T (1988) New amorphous Al–Y, Al–La and Al–Ce alloys prepared by melt spinning. Jpn J Appl Phys 27:736–739CrossRef Inoue A, Ohtera K, Masumoto T (1988) New amorphous Al–Y, Al–La and Al–Ce alloys prepared by melt spinning. Jpn J Appl Phys 27:736–739CrossRef
32.
Zurück zum Zitat Louzguine DV, Inoue A (2002) Investigation of structure and properties of the Al–Y–Ni–Co–Cu metallic glasses. J Mater Res 17:1014–1018CrossRef Louzguine DV, Inoue A (2002) Investigation of structure and properties of the Al–Y–Ni–Co–Cu metallic glasses. J Mater Res 17:1014–1018CrossRef
33.
Zurück zum Zitat Yang H, Dong P, Wang J, Li Y (2007) Glass formability and structural stability of Al-based alloy systems. Mat Sci Eng A-Struct 449:273–276CrossRef Yang H, Dong P, Wang J, Li Y (2007) Glass formability and structural stability of Al-based alloy systems. Mat Sci Eng A-Struct 449:273–276CrossRef
34.
Zurück zum Zitat Wang JQ, Liu YH, Imhoff S, Chen N, Louzguine-Luzgin DV, Takeuchi A, Chen MW, Kato H, Perepezko JH, Inoue A (2012) Enhance the thermal stability and glass forming ability of Al-based metallic glass by Ca minor-alloying. Intermetallics 29:35–40CrossRef Wang JQ, Liu YH, Imhoff S, Chen N, Louzguine-Luzgin DV, Takeuchi A, Chen MW, Kato H, Perepezko JH, Inoue A (2012) Enhance the thermal stability and glass forming ability of Al-based metallic glass by Ca minor-alloying. Intermetallics 29:35–40CrossRef
35.
Zurück zum Zitat Hirata A, Hirotsu Y, Amiya K, Nishiyama N, Inoue A (2009) Fe23B6-type quasicrystal-like structures without icosahedral atomic arrangement in an Fe-based metallic glass. Phys Rev B 80:140201CrossRef Hirata A, Hirotsu Y, Amiya K, Nishiyama N, Inoue A (2009) Fe23B6-type quasicrystal-like structures without icosahedral atomic arrangement in an Fe-based metallic glass. Phys Rev B 80:140201CrossRef
36.
Zurück zum Zitat Saida J, Yamada R, Wakeda M (2013) Recovery of less relaxed state in Zr–Al–Ni–Cu bulk metallic glass annealed above glass transition temperature. Appl Phys Lett 103:221910CrossRef Saida J, Yamada R, Wakeda M (2013) Recovery of less relaxed state in Zr–Al–Ni–Cu bulk metallic glass annealed above glass transition temperature. Appl Phys Lett 103:221910CrossRef
37.
Zurück zum Zitat Hirata A, Hirotsu Y, Amiya K, Inoue A (2010) Quasicrystal-like structure and its crystalline approximant in an Fe48Cr15Mo14C15B6Tm2 bulk metallic glass. J Alloy Compd 504:186–189CrossRef Hirata A, Hirotsu Y, Amiya K, Inoue A (2010) Quasicrystal-like structure and its crystalline approximant in an Fe48Cr15Mo14C15B6Tm2 bulk metallic glass. J Alloy Compd 504:186–189CrossRef
38.
Zurück zum Zitat Louzguine DV, Bazlov AI, Ketov SV, Greer AL, Inoue A (2015) Crystal growth limitation as a critical factor for formation of Fe-based metallic glasses. Acta Mater 82:396–402CrossRef Louzguine DV, Bazlov AI, Ketov SV, Greer AL, Inoue A (2015) Crystal growth limitation as a critical factor for formation of Fe-based metallic glasses. Acta Mater 82:396–402CrossRef
39.
Zurück zum Zitat Bassim N, Kiminami CS, Kaufman MJ (2000) Phases formed during crystallization of amorphous Al84Y9Ni5Co2 alloy. J Non-Cryst Solids 273:271–276CrossRef Bassim N, Kiminami CS, Kaufman MJ (2000) Phases formed during crystallization of amorphous Al84Y9Ni5Co2 alloy. J Non-Cryst Solids 273:271–276CrossRef
40.
Zurück zum Zitat Inoue A, Kong FL, Zhu SL, Liu CT (2015) Development and applications of highly functional Al-based materials by use of metastable phases. Mater Res 18:1414–1425CrossRef Inoue A, Kong FL, Zhu SL, Liu CT (2015) Development and applications of highly functional Al-based materials by use of metastable phases. Mater Res 18:1414–1425CrossRef
Metadaten
Titel
High formability of glass plus fcc-Al phases in rapidly solidified Al-based multicomponent alloy
verfasst von
F. F. Han
A. Inoue
Y. Han
F. L. Kong
S. L. Zhu
E. Shalaan
F. Al-Marzouki
Publikationsdatum
01.02.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 3/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0394-6

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