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Journal of Materials Science
Erschienen in: Journal of Materials Science 9/2017

11.01.2017 | Original Paper

High-strength, thermally stable nylon 6,6 composite nanofiber separators for lithium-ion batteries

verfasst von: Meltem Yanilmaz, Jiadeng Zhu, Yao Lu, Yeqian Ge, Xiangwu Zhang

Erschienen in: Journal of Materials Science | Ausgabe 9/2017

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Abstract

Electrospun nylon 6,6 composite nanofiber membranes containing TiO2 or SiO2 nanoparticles were fabricated, and their physical and electrochemical properties were assessed for use as high-strength, thermally stable separators for lithium-ion batteries. Experimental results demonstrated that TiO2/nylon 6,6 and SiO2/nylon 6,6 nanofiber membranes not only displayed good mechanical strength and excellent thermal stability, but also showed improved electrochemical properties compared to commercial polypropylene membrane separator. Larger liquid electrolyte uptake, higher ionic conductivity, higher electrochemical oxidation limit, and lower interfacial resistance with lithium were obtained for TiO2/nylon 6,6 and SiO2/nylon 6,6 nanofiber membranes. Among all membranes studied, SiO2/nylon 6,6 nanofiber membranes showed the highest ionic conductivity and lowest interfacial resistance with lithium owing to their highest porosity and well-dispersed nanoparticles. In addition, Li/LiCoO2 and Li/LiFePO4 cells containing these composite nanofiber membranes demonstrated high cell capacities, good cycling performance, and superior C-rate performance at room temperature.
Vorheriger Artikel Effect of dopant segregation and negative differential mobility on multi-quantum well activation energy
Nächster Artikel The influence of H2O2 on the properties of CeO2-ZrO2 mixed oxides

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Literatur
1.
Li Y, Xu G, Yao Y, Xue L, Yanilmaz M, Lee H, Zhang X (2014) Coaxial electrospun Si/C–C core–shell composite nanofibers as binder-free anodes for lithium-ion batteries. Solid State Ion 258:67–73CrossRef
2.
Dirican M, Yanilmaz M, Fu K, Lu Y, Kizil H, Zhang X (2014) Carbon-enhanced electrodeposited SnO2/carbon nanofiber composites as anode for lithium-ion batteries. J Power Sources 264:240–247CrossRef
3.
Lee H, Yanilmaz M, Toprakci O, Fu K, Zhang X (2014) A review of recent developments in membrane separators for rechargeable lithium-ion batteries. Energy Environ Sci 7(12):3857–3886CrossRef
4.
Yanilmaz M, Chen C, Zhang X (2013) Fabrication and characterization of SiO2/PVDF composite nanofiber-coated PP nonwoven separators for lithium-ion batteries. J Polym Sci Polym Phys 51(23):1719–1726CrossRef
5.
Yanilmaz M, Lu Y, Li Y, Zhang X (2015) SiO2/polyacrylonitrile membranes via centrifugal spinning as a separator for Li-ion batteries. J Power Sources 273:1114–1119CrossRef
6.
Yanilmaz M, Lu Y, Dirican M, Fu K, Zhang X (2014) Nanoparticle-on-nanofiber hybrid membrane separators for lithium-ion batteries via combining electrospraying and electrospinning techniques. J Membr Sci 456:57–65CrossRef
7.
Yanilmaz M, Sarac AS (2014) A review: effect of conductive polymers on the conductivities of electrospun mats. Text Res J 84(12):1325–1342CrossRef
8.
Yanilmaz M, Kalaoglu F, Karakas H, Sarac AS (2012) Preparation and characterization of electrospun polyurethane–polypyrrole nanofibers and films. J Appl Polym Sci 125(5):4100–4108CrossRef
9.
Ding Y, Zhang P, Long Z, Jiang Y, Xu F, Di W (2009) The ionic conductivity and mechanical property of electrospun P (VdF-HFP)/PMMA membranes for lithium ion batteries. J Membr Sci 329(1):56–59CrossRef
10.
Gao K, Hu X, Dai C, Yi T (2006) Crystal structures of electrospun PVDF membranes and its separator application for rechargeable lithium metal cells. Mater Sci Eng 131(1):100–105CrossRef
11.
Yang C, Li Z, Li W, Liu H, Xiao Q, Lei G, Ding Y (2015) Batwing-like polymer membrane consisting of PMMA-grafted electrospun PVdF–SiO2 nanocomposite fibers for lithium-ion batteries. J Membr Sci 495:341–350CrossRef
12.
Zhai Y, Xiao K, Yu J, Ding B (2015) Fabrication of hierarchical structured SiO2/polyetherimide-polyurethane nanofibrous separators with high performance for lithium ion batteries. Electrochim Acta 154:219–226CrossRef
13.
Chen W, Liu Y, Ma Y, Yang W (2015) Improved performance of lithium ion battery separator enabled by co-electrospinnig polyimide/poly (vinylidene fluoride-co-hexafluoropropylene) and the incorporation of TiO2-(2-hydroxyethyl methacrylate). J Power Sources 273:1127–1135CrossRef
14.
Liu H, Xu J, Guo B, He X (2014) Effect of Al2O3/SiO2 composite ceramic layers on performance of polypropylene separator for lithium-ion batteries. Ceram Int 40(9):14105–14110CrossRef
15.
Raja M, Angulakshmi N, Thomas S, Kumar TP, Stephan AM (2014) Thin, flexible and thermally stable ceramic membranes as separator for lithium-ion batteries. J Membr Sci 471:103–109CrossRef
16.
Shayapat J, Chung OH, Park JS (2015) Electrospun polyimide-composite separator for lithium-ion batteries. Electrochim Acta 170:110–121CrossRef
17.
Rusu G, Rusu E, Zaltariov M-F (2016) Anionic nylon 612/TiO2 composite materials: synthesis, characterization and properties. J Inorg Organomet Polym Mater. doi:10.​1007/​s10904-016-0466-8
18.
Zheng L-Y, Lau K-T, Zhao L-X, Zhang Y-Q, Hui D (2009) Mechanical and thermal properties of nano-Al2O3/nylon 6 composites. Chem Eng Commun 197(3):343–351CrossRef
19.
Raghavan P, Zhao X, Kim J-K, Manuel J, Chauhan GS, Ahn J-H, Nah C (2008) Ionic conductivity and electrochemical properties of nanocomposite polymer electrolytes based on electrospun poly(vinylidene fluoride-co-hexafluoropropylene) with nano-sized ceramic fillers. Electrochim Acta 54(2):228–234CrossRef
20.
Huang X (2011) Separator technologies for lithium-ion batteries. J Solid State Electron 15(4):649–662CrossRef
21.
Huang X, Hitt J (2013) Lithium ion battery separators: development and performance characterization of a composite membrane. J Membr Sci 425:163–168CrossRef
22.
Yanilmaz M, Zhang X (2015) Polymethylmethacrylate/polyacrylonitrile membranes via centrifugal spinning as separator in Li-ion batteries. Polymers 7(4):629–643CrossRef
23.
Liu Q, Xia M, Chen J, Tao Y, Wang Y, Liu K, Li M, Wang W, Wang D (2015) High performance hybrid Al2O3/poly (vinyl alcohol-co-ethylene) nanofibrous membrane for lithium-ion battery separator. Electrochim Acta 176:949–955CrossRef
24.
Peng K, Wang B, Li Y, Ji C (2015) Magnetron sputtering deposition of TiO2 particles on polypropylene separators for lithium-ion batteries. RSC Adv 5(99):81468–81473CrossRef
25.
Zhang F, Ma X, Cao C, Li J, Zhu Y (2014) Poly(vinylidene fluoride)/SiO2 composite membranes prepared by electrospinning and their excellent properties for nonwoven separators for lithium-ion batteries. J Power Sources 251:423–431CrossRef
26.
Yanilmaz M, Lu Y, Li Y, Zhang X (2015) SiO2/polyacrylonitrile membranes via centrifugal spinning as a separator for Li-ion batteries. J Power Sources 273:1114–1119CrossRef
27.
Zhang X-W, Li Y, Khan SA, Fedkiw PS (2004) Inhibition of lithium dendrites by fumed silica-based composite electrolytes. J Electrochem Soc 151(8):A1257–A1263CrossRef
Metadaten
Titel
High-strength, thermally stable nylon 6,6 composite nanofiber separators for lithium-ion batteries
verfasst von
Meltem Yanilmaz
Jiadeng Zhu
Yao Lu
Yeqian Ge
Xiangwu Zhang
Publikationsdatum
11.01.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 9/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-0764-8

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